Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8: A Supplement to Landolt-Börnstein II/31 Series 3662664593, 9783662664599

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R. T. Pardasani P. Pardasani

Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8 A Supplement to Landolt-Börnstein II/31 Series

MATERIALS.SPRINGER.COM

Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8

R. T. Pardasani • P. Pardasani

Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8 A Supplement to Landolt-Bo¨rnstein II/31 Series

With 1103 Figures and 501 Tables

R. T. Pardasani Ex-Department of Chemistry School of Chemical Sciences and Pharmacy Central University of Rajasthan Bandar Sindri, Ajmer, India

P. Pardasani Ex-Department of Chemistry University of Rajasthan Jaipur, India

ISBN 978-3-662-66459-9 ISBN 978-3-662-66460-5 (eBook) https://doi.org/10.1007/978-3-662-66460-5 © Springer-Verlag GmbH Germany, part of Springer Nature 2023 This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors, and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer-Verlag GmbH, DE part of Springer Nature. The registered company address is: Heidelberger Platz 3, 14197 Berlin, Germany

Preface

In continuation to our efforts to update the magnetic susceptibility data of paramagnetic compounds, a new volume is presented herewith covering literature from 2001 to 2010. Since most of the researches these days consult the literature online, a new pattern has been introduced. All the magnetic properties of each individual substance are listed as a single document which is self-explainable and allowing search in respect of substance name, synonyms, common vocabulary, and even structure. It is hoped that the new pattern will facilitate greater accessibility of magnetic data and enhance the use of Landolt-Börnstein. In this Volume, the Introduction Chapter has been thoroughly updated and recent trends in molecular magnetic materials with special reference to molecular nanomagnets and multifunctional magnetic materials as well as their theoretical aspects are summarized. The encouraging support of Michael Klinge, Sharon George, Antje Endemann and the whole production team from Springer is gratefully acknowledged. Jaipur March 2023

R. T. Pardasani Pushpa Pardasani Authors

v

Contents

Volume 8A Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Part I

1

V .................................................

13

Magnetic properties of dimeric vanadium(II) complex with bulky terphenyl thiolate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

15

Magnetic properties of vanadium(III) complex with anthranilate . . . . .

18

Magnetic properties of vanadium(III) complex with imidazol-4carboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

20

Magnetic properties of vanadium(III) chloro complex with trans-urocanic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

22

Magnetic properties of vanadium(III) complex with bulky terphenyl thiolate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

24

Magnetic properties of vanadium(III) 2-dimensional network (vanadyl chains linked by arydioxide) . . . . . . . . . . . . . . . . . . . . . . . . . .

26

Magnetic properties of oxovanadium(IV) complex of 2-acetylpyridine semicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

29

Magnetic properties of oxovanadium(IV) complex of 3-acetylpyridine semicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

31

Magnetic properties of oxovanadium(IV) complex of 4-acetylpyridine semicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

33

Magnetic properties of oxovanadium(IV) complex with imidazol-4-carboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

35

Magnetic properties of oxovanadium(IV) complex with anthranilate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

37 vii

viii

Contents

Magnetic properties of oxovanadium(IV) complex with dipyrido[3,2-a:20 ,30 -c]phenazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

39

Magnetic properties of mixed ligand complex of oxovanadium(IV) with N-salicylidene-S-methyldithiocarbazate and 1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

42

Magnetic properties of mixed ligand complex of oxovanadium(IV) with N-salicylidene-S-methyldithiocarbazate and dipyrido[3,2-d:20 , 30 -f]quinoxaline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

44

Magnetic properties of mixed ligand complex of oxovanadium(IV) with N-salicylidene-S-methyldithiocarbazate and dipyrido[3,2-a:20 , 30 -C]phenazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

47

Magnetic properties of oxovanadium(IV) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane-1,8-diamine . . . . .

50

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -dimethylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . .

53

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -isopropylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . .

56

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -trimethylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . .

59

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -tetra-methylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . . . .

62

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -penta-methylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . . . .

65

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -hexa-methylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . . . .

68

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -isopentylenebis(3,5-tBu2salicylaldimine) ligand . . . . . . . . . . . . . . .

71

Magnetic properties of dinuclear oxovanadium(IV) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

74

Magnetic properties of hetero-trimetallic, VO2Mn complex with macrocyclic oxamido vanadium(IV)-oxo ligand . . . . . . . . . . . . . . . . . . .

77

Magnetic properties of hetero-trimetallic, VO2Cu complex with macrocyclic oxamido vanadium(IV)-oxo ligand . . . . . . . . . . . . . . . . . . .

81

Contents

Part II

ix

Cr . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

85

Magnetic properties of chromium(III) chloro complex with 40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . .

87

Magnetic properties of chromium(III) azido complex with 40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . .

90

Magnetic properties of chromium(III) thiocyanato complex with 40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . .

92

Magnetic properties of chromium(III) complex with 1,8-N-bis (3-carboxy)- disalicylidene-3,6-diazaocatane-1,8-diamine as acetate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

95

Magnetic properties of chromium(III) complex with 1,8-N-bis (3-carboxy)- disalicylidene-3,6-diazaocatane-1,8-diamine as chloride salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

98

Magnetic properties of chromium(III) complex with oxalohydrazide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

101

Magnetic properties of dinuclear chromium(III) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

103

Magnetic properties of heterometallic ion-pair complex having copper(II) Schiff-base cation and diaminotetrathiocyanatochromate (III) anion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

106

Magnetic properties of heterometallic Cu(II)/Cr(III) complex with an open-chain Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

109

Part III

113

Mo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Magnetic properties of three-dimensional cyano-bridged heterobimetallic Ni(II)-Mo(IV) complex with macrocyclic ligand . . . . .

115

Magnetic properties of bimetallic oxide of Cu-Mo6 constructed from molybdenum oxo cluster having bis-N,N(methylphosphonic acid) amine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

118

Part IV

121

Mn . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Magnetic properties of manganese(II) complex with sulpiride drug . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

123

Magnetic properties of manganese(II) complex with 6-acetyl-1,3,7-trimethyllumazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

125

x

Contents

Magnetic properties of imidazole complex of manganese(II) benzenesulfonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

128

Magnetic properties of manganese(II) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl-4H-[1,3,4]thiadiazolo[2,3-c] [1,2,4]triazin-4-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

130

Magnetic properties of manganese(II) complex with pyrimidine derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

133

Magnetic properties of manganese(II) complex with pyrimidine derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

135

Magnetic properties of manganese(II) complex with 17-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

137

Magnetic properties of manganese(II) complex with 16-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

140

Magnetic properties of manganese(II) complex with 16-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

143

Magnetic properties of manganese(II) complex with 17-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

146

Magnetic properties of mixed ligand manganese(II) complex with N0 -(pyridine-3-carboxyl)-hydrazinecarbodithioic acid ethyl ester and 1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

148

Magnetic properties of manganese(II) complex with hexadentate Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

151

Magnetic properties of manganese(II) complex with mesogenic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

153

Magnetic properties of aqua-bridged binuclear manganese(II) . . . . . . .

155

Magnetic properties of dinuclear manganese(II) complex with thiophenedicarboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

158

0

Magnetic properties of bis-μ-η -carboxylate-bridged dinuclear manganese(II) complex containing a tetradentate tripodal ligand . . . . .

160

Magnetic properties of trinuclear manganese(II) complex with thiophenedicarboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

163

Magnetic properties of metallamacrocycle of manganese(II,III) with (z)-3-(salicylhydrazinocarbonyl)propenoic acid . . . . . . . . . . . . . . .

166

Contents

xi

Magnetic properties of manganese(II) complex with L-3-phenyl-2(3-phenyl-ureido)propionic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

169

Magnetic properties of manganese(II) diphosphonate . . . . . . . . . . . . . .

171

Magnetic properties of manganese(III) complex with sulphonatosubstituted Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

174

Magnetic properties of manganese(III) complex with 1,8-N-bis (3-carboxy)-disalicylidene-3,6-diazaocatane-1,8-diamine . . . . . . . . . . . .

178

Magnetic properties of 18-membered hexanuclear manganese(III) macrocycle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

181

Magnetic properties of polymeric manganese(III) carboxylate complex with salicylaldoxime . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

184

Magnetic properties of hexanuclear manganese(III) carboxylate complex with salicylaldoxime . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

187

Magnetic properties of manganese(III) complex with 2-(2-pyridylmethyleneamino)pyridine . . . . . . . . . . . . . . . . . . . . . . . . . .

190

Magnetic properties of manganese(II) coordination polymer with mixed pyrimidine-2-carboxylate and oxalate bridges . . . . . . . . . . . . . .

193

Part V

197

Re . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Magnetic properties of rhenium(III) complex of 1-(2-pyridylazo)2-naphthol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

199

Magnetic properties of rhenium(III) complex with 1-isoquinoline phenyl ketone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

203

Magnetic properties of hetero-trimetallic Gd-Re-Te three dimensional coordination polymer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

206

Magnetic properties of hetero-trimetallic Ho-Re-Te three dimensional coordination polymer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

209

Part VI

213

Fe . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand (as perchlorate salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

215

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as perchlorate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

218

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as perchlorate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

221

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as perchlorate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

224

xii

Contents

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as hexafluorophosphate salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

227

Magnetic properties of iron(II) complex with thiocyanate, tris-pyrazolylmethane and pyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . .

230

Magnetic properties of iron(II) complex with selenocyanate, tris-pyrazolylmethane and pyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . .

232

Magnetic properties of iron(II) complex with selenocyanate, tris-pyrazolylmethane and imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . .

234

Magnetic properties of dinuclear iron(II) complex with thiocyanate, tris-pyrazolylmethane and 4,40 -bipyridine . . . . . . . . . . . . . . . . . . . . . . .

237

Magnetic properties of dinuclear iron(II) complex with selenocyanate, tris-pyrazolylmethane and 4,40 -bipyridine . . . . . . . . . . . . . . . . . . . . . . .

240

Magnetic properties of ion-pair complex of bis(4-methylpyridine)iron (II) cation and dicyanoaurate(I) anion . . . . . . . . . . . . . . . . . . . . . . . . . .

243

Magnetic properties of cyanide-bridged Fe2Cu2 molecular square having bipyridine ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

246

Magnetic properties of iron(III) porphyrin radical diperchlorate complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

249

Magnetic properties of tosyl iron(III)-corrole radical cation . . . . . . . . .

252

Magnetic properties of chlorate iron(III)-corrole radical cation . . . . . .

255

Magnetic properties of iron(III) complex with sulpiride drug . . . . . . . .

258

Magnetic properties of iron(III) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin4-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

261

Magnetic properties of iron(III) complex with [1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane-1,8-diamine] as chloride salt . . . . . . . .

264

Magnetic properties of iron(III) complex with [1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane-1,8-diamine] as nitrate salt . . . . . . . . . .

267

Magnetic properties of iron(III) diperchlorate porphyrin radical complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

270

Magnetic properties of iron(III) diperchlorate porphyrin radical complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

273

Magnetic properties of iron(III) complex with 2-pyridinoformamide derived thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

276

Magnetic properties of iron(III) complex with 2-pyridinoformamide derived thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

278

Contents

Magnetic properties of iron(III) complex with N-salicylidenearginine

xiii

...

280

Magnetic properties of iron(III) complex with hyroxynaphthylidenearginine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

283

Magnetic properties of iron(III) complex with N-salicylidenelysine

...

286

Magnetic properties of iron(III) complex with 2,6,9-trisubstituted purine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

289

Magnetic properties of iron(III) complex with 2,6,9-trisubstituted purine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

292

Magnetic properties of iron(III) complex with 2,6,9-trisubstituted purine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

295

Magnetic properties of iron(III) complex with 2,6,9-trisubstituted purine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

298

Magnetic properties of iron(III) complex with 2,6,9-trisubstituted purine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

301

Magnetic properties of iron(III) complex with 2,6,9-trisubstituted purine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

304

Magnetic properties of iron(III) complex with 2-pyridinoformamide derived thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

307

Magnetic properties of dinuclear iron(III) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine . . . . . . . . .

309

Magnetic properties of dinuclear iron(III) complex incorporating N4O3 coordinating helptadentate ligand . . . . . . . . . . . . . . . . . . . . . . . .

312

Magnetic properties of bimetallic cyanide-bridged Ni-Fe complex based on nitroprusside anion and paramagnetic metal complex . . . . . .

316

Magnetic properties of bimetallic cyanide-bridged Mn-Fe complex based on nitroprusside anion and paramagnetic metal complex . . . . . .

318

Magnetic properties of bimetallic cyanide-bridged Mn-Fe complex based on nitroprusside anion and paramagnetic metal complex . . . . . .

321

Magnetic properties of chiral heptanuclear iron(III) cluster with N-(2-hydroxybenzyl)- L-histidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

324

Magnetic properties of bimetallic cyanide-bridged Ni-Fe complex based on nitroprusside anion and paramagnetic metal complex . . . . . .

327

Magnetic properties of metastable porphyrin-iron(IV) diperchlorate complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

329

Magnetic properties of metastable porphyrin-iron(IV) diperchlorate complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

331

xiv

Contents

Magnetic properties of corrole-iron(IV) chloro complex . . . . . . . . . . . .

334

...........

337

.............

340

..........

343

Magnetic properties of corrole-iron(IV) nitrato complex Magnetic properties of corrole-iron(IV) tosyl complex

Magnetic properties of corrole-iron(IV) chlorato complex Part VII

Ru . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

347

Magnetic properties of ruthenium(III) chloro complex with triphenylphosphine and methylamine-bis(p-crisolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

349

Magnetic properties of ruthenium(III) chloro complex with triphenylarsine and methylamine-bis(p-crisolate) tripodal ligand . . . . .

352

Magnetic properties of ruthenium(III) bromo complex with triphenylarsine and methylamine-bis(p-crisolate) tripodal ligand . . . . .

355

Magnetic properties of ruthenium(III) bromo complex with triphenylphosphine and methylamine-bis(p-crisolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

358

Magnetic properties of ruthenium(III) chloro complex with triphenylphosphine and cyclohexylamine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

361

Magnetic properties of ruthenium(III) chloro complex with triphenylarsine and cyclohexylamine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

364

Magnetic properties of ruthenium(III) bromo complex with triphenylarsine and cyclohexylamine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

367

Magnetic properties of ruthenium(III) bromo complex with triphenylphosphine and cyclohexylamine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

370

Magnetic properties of ruthenium(III) chloro complex with triphenylphosphine and 2-aminopyridine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

373

Magnetic properties of ruthenium(III) chloro complex with triphenylarsine and 2-aminopyridine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

376

Magnetic properties of ruthenium(III) bromo complex with triphenylarsine and 2-aminopyridine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

379

Contents

xv

Magnetic properties of ruthenium(III) bromo complex with triphenylphosphine and 2-aminopyridine-bis(p-cresolate) tripodal ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

382

Magnetic properties of ruthenium(III) Schiff-base complex containing triphenylphosphine co-ligand . . . . . . . . . . . . . . . . . . . . . . . .

385

Magnetic properties of ruthenium(III) Schiff-base complex containing triphenylarsine co-ligand . . . . . . . . . . . . . . . . . . . . . . . . . . .

388

Magnetic properties of mixed valent diruthenium(II, III) complex with ibuprofen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

391

Magnetic properties of mixed valent diruthenium(II, III) complex with aspirin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

393

Magnetic properties of mixed valent diruthenium(II, III) complex with naproxen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

395

Magnetic properties of mixed valent diruthenium(II, III) complex with indomethacin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

398

Part VIII

401

Co

............................................

Magnetic properties of cobalt(II) nitrato complex with methyl-2benzimidazolecarbamate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

403

Magnetic properties of cobalt(II) complex with furanyl-derived sulfonamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

406

Magnetic properties of cobalt(II) complex with furanyl-derived sulfonamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

409

Magnetic properties of cobalt(II) complex with mesogenic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

412

Magnetic properties of cobalt(II) complex with [18]-membered tetra-oxodithiatetraaza macrocyclic ligand . . . . . . . . . . . . . . . . . . . . . .

414

Magnetic properties of cobalt(II) complex with [20]-membered tetra-oxodithiatetraaza macrocyclic ligand . . . . . . . . . . . . . . . . . . . . . .

416

Magnetic properties of cobalt(II) complex with [18]-membered tetra-oxodithiatetraaza macrocyclic ligand . . . . . . . . . . . . . . . . . . . . . .

419

Magnetic properties of cobalt(II) complex with [20]-membered tetra-oxodithiatetraaza macrocyclic ligand . . . . . . . . . . . . . . . . . . . . . .

422

Magnetic properties of cobalt(II) complex with quinolone-2carboxylate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

425

Magnetic properties of cobalt(II) complex with sterically hindered o-aminophenol derivative . . . . . . . . . . . . . . . . . . . . . . . . . . . .

428

xvi

Contents

Magnetic properties of cobalt(II) complex with sterically hindered o-aminophenol derivative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

430

Magnetic properties of cobalt(II) chloro complex with 2-acetyl-2thiazoline hydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

433

Magnetic properties of cobalt(II) complex with spirocyclophosphazene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

435

Magnetic properties of cobalt(II) chloro complex with 2-chlorobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

438

Magnetic properties of cobalt(II) bromo complex with 2-chlorobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

441

Magnetic properties of cobalt(II) chloro complex with methyl-2-benzimidazolecarbamate . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

444

Magnetic properties of cobalt(II) bromo complex with methyl-2-benzimidazolecarbamate . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

447

Magnetic properties of cobalt(II) chloro complex with 2-guanidinobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

450

Magnetic properties of cobalt(II) bromo complex with 2-guanidinobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

452

Magnetic properties of cobalt(II) nitrato complex with 2-guanidinobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

455

Magnetic properties of cobalt(II) chloro complex with 2-phenylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

457

Magnetic properties of cobalt(II) bromo complex with 2-phenylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

460

Magnetic properties of cobalt(II) chloro complex with 2-methylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

463

Magnetic properties of cobalt(II) bromo complex with 2-methylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

466

Magnetic properties of cobalt(II) complex with 2-acetyl-γbutyrolactone thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

469

Magnetic properties of cobalt(II) chloro complex with 2-furancarbaldehyde thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . .

471

Magnetic properties of cobalt(II) chloro complex with 6-acetyl-1,3,7- trimethyllumazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

473

Magnetic properties of cobalt(II) perchlorato complex with 6-acetyl1,3,7-trimethyllumazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

476

Contents

xvii

Magnetic properties of cobalt(II) bromo complex with benzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

479

Magnetic properties of cobalt(II) nitrato complex with benzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

482

Magnetic properties of cobalt(II) chloro complex with 2-aminobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

485

Magnetic properties of cobalt(II) bromo complex with 2-aminobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

488

Magnetic properties of cobalt(II) nitrato complex with 2-aminobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

491

Magnetic properties of cobalt(II) chloro complex with albendazole . . .

494

Magnetic properties of cobalt(II) bromo complex with albendazole . . .

497

Magnetic properties of cobalt(II) nitrato complex with albendazole . . .

500

Magnetic properties of cobalt(II) chloro complex with tris(2-benzimidazolylmethyl)amine . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

503

Magnetic properties of cobalt(II) bromo complex with tris(2-benzimidazolylmethyl)amine . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

506

Magnetic properties of cobalt(II) nitrato complex with tris(2-benzimidazolylmethyl)amine . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

509

Magnetic properties of cobalt(II) chloro complex with benzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

511

Magnetic properties of cobalt(II) complex with Schiff-base derived from 2,6-diformyl-4-methylpheol and 5,6-diamino-1,3dimethyluracil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

514

Magnetic properties of cobalt(II) complex with 3-acetylcoumarinisonicotynoylhydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

516

Magnetic properties of imidazole complex of cobalt(II) benzenesulfonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

518

Magnetic properties of cobalt(II) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin4-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

520

Magnetic properties of cobalt(II) complex with ligand derived from reduced N,N0 -o-phenylenebis(salicylideneimine) . . . . . . . . . . . . . . . . . .

523

Magnetic properties of cobalt(II) complex with ligand derived from reduced N,N0 -o-phenylenebis(salicylideneimine) . . . . . . . . . . . . . . . . . .

526

xviii

Contents

Magnetic properties of cobalt(II) complex with ligand derived from reduced N,N0 -o-phenylenebis(salicylideneimine) . . . . . . . . . . . . . . . . . .

529

Magnetic properties of cobalt(II) complex with 1,8-N-bis (3-carboxy)-disalicylidene-3,6-diazaocatane-1,8-diamine . . . . . . . . . . . .

532

Magnetic properties of cobalt(II) complex with sulpiride drug . . . . . . .

535

Magnetic properties of dinuclear cobalt(II) complex with 28-membered [2+2] macrocyclic ligand derived from 1,4-bis(20 formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane (as perchlorate salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

537

Magnetic properties of dinuclear cobalt(II) complex with 28-membered [2+2] macrocyclic ligand derived from 1,4-bis (20 -formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane (as nitrate salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

540

Magnetic properties of binuclear cobalt(II) complex with binucleating Schiff-base ligand with a phenylene spaer . . . . . . . . . . . . . . . . . . . . . . .

543

Magnetic properties of dinuclear cobalt(II) complex with ‘end-off’ compartmental Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

546

Magnetic properties of dinuclear cobalt(II) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine . . . . . . . . .

549

Magnetic properties of diacetato and monohydroxamato bridged dinuclear cobalt(II) complex containing tetramethylethylenediamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

552

Magnetic properties of triacetato bridged dinuclear cobalt(II) urease complex containing tetramethylethylenediamine . . . . . . . . . . . . . . . . . .

556

Magnetic properties of diacetato-bridged, dinuclear cobalt(II) hydrolase complex containing tetramethylethylenediamine . . . . . . . . . .

559

Magnetic properties of heterometallic cobalt(II)-copper(II) complex formed by one pot reaction of 2,6-pyridinedicarboxylic acid and ethylenediamine with metal ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

562

Magnetic properties of ion-pair complex having chloro-tris {1-(3,5-dimethylpyrazolyl)methyl}aminecobalt(II) cation . . . . . . . . . . .

564

Magnetic properties of ion-pair complex having {tris[(2-benzimidazolylmethyl)amine]chlorocobalt(II)} cation and tetrachlorocobaltate(II) anion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

567

Magnetic properties of ion-pair complex having {tris[(2-benzimidazolyl-methyl)amine]bromocobalt(II)} cation and tetrabromocobaltate(II) anion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

569

Contents

xix

Magnetic properties of tetranuclear cobalt(II) cluster with pyridine alcoholate ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

572

Magnetic properties of oxalato-bridged cobalt(II) complex with 4-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

576

Magnetic properties of oxalato-bridged cobalt(II) complex with 3-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

578

Magnetic properties of oxalate-bridged cobalt(II) complex with 2-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

581

Magnetic properties of polymeric cobalt(II) complex with pyrazine and pivalic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

584

Magnetic properties of polymeric cobalt(II) complex with pyrimidine and pivalic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

587

Magnetic properties of cobalt(III) complex with N,N,-bis (2-aminothiophenol)-1,4-bis(carboxylidene phenoxy)butane . . . . . . . . .

590

Magnetic properties of cobalt(III)-cobalt(II) complex formed by one pot reaction of 2,6-pyridinedicarboxylic acid and ethylenediamine with metal ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

592

Part IX

595

Ni . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Magnetic properties of nickel(II) complex with 28-membered [2+2] macrocyclic ligand derived from 1,4-bis(20 -formylphenyl)-1,4dioxabutane and cis-1,2-diaminocyclohexane (as nitrate salt) . . . . . . . .

597

Magnetic properties of nickel(II) complex with imino nitroxide diradical . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

600

Magnetic properties of nickel(II) complex with sulpiride drug . . . . . . .

603

Magnetic properties of nickel(II) complex with 3-acetylcoumarinisonicotynoylhydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

605

Magnetic properties of imidazole complex of nickel(II) benzenesulfonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

608

Magnetic properties of nickel(II) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin4-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

611

Magnetic properties of nickel(II) complex with ligand derived from reduced N,N0 -o-phenylenebis(salicylideneimine) . . . . . . . . . . . . . . . . . .

614

Magnetic properties of nickel(II) complex with ligand derived from reduced N,N0 -o-phenylenebis(salicylideneimine) . . . . . . . . . . . . . . . . . .

617

xx

Contents

Magnetic properties of nickel(II) chloro complex with 2-acetyl-2thiazoline hydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

620

Magnetic properties of nickel(II) complex with N(4),N(4)-(butane1,4-diyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

622

Magnetic properties of nickel(II) complex with N(4),N(4)-(butane1,4-diyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

624

Magnetic properties of nickel(II) chloro complex with N(4),N(4)(butane-1,4-diyl)thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . .

626

Magnetic properties of mixed ligand nickel(II) complex with N-benzyl-N-methyldithiocarbamate and 1,10-phenanthroline . . . . . . . .

628

Magnetic properties of mixed ligand nickel(II) complex with N,N-dipentyl-dithiocarbamate and 1,10-phenanthroline . . . . . . . . . . . .

630

Magnetic properties of mixed ligand nickel(II) complex with 4-benzyl-piperazinedithiocarbamate and 1,10-phenanthroline . . . . . . .

632

Magnetic properties of mixed ligand nickel(II) complex with 4-benzyl-piperazinedithiocarbamate and 1,10-phenanthroline having thiocyanate counteranion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

634

Magnetic properties of mixed ligand nickel(II) complex with N,N-benzyl-methyldithiocarbamate and 2,20 -bipyridine . . . . . . . . . . . .

636

Magnetic properties of mixed ligand nickel(II) complex with N,N-dipentyl-dithiocarbamate and cyclam . . . . . . . . . . . . . . . . . . . . . . .

638

Magnetic properties of mixed ligand nickel(II) complex with N-benzyl-N-methyldithiocarbamate and cyclam . . . . . . . . . . . . . . . . . .

641

Magnetic properties of mixed ligand nickel(II) complex with N,N-dibenzyl-dithiocarbamate and cyclam . . . . . . . . . . . . . . . . . . . . . .

643

Magnetic properties of mixed ligand nickel(II) complex with N,N-dibenzyl-dithiocarbamate and 1,10-phenanthroline . . . . . . . . . . . .

646

Magnetic properties of nickel(II) aqua complex with antibacterial drug, flumequine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

648

Magnetic properties of mixed ligand nickel(II) complex with 4-benzylpyridine and antibacterial drug, flumequine . . . . . . . . . . . . . .

650

Magnetic properties of mixed ligand nickel(II) complex with pyridine and antibacterial drug, flumequine . . . . . . . . . . . . . . . . . . . . .

653

Magnetic properties of mixed ligand nickel(II) complex with 2,20 -bipyridine and antibacterial drug, flumequine . . . . . . . . . . . . . . . .

655

Contents

xxi

Magnetic properties of mixed ligand nickel(II) complex with 1,10-phenanthroline and antibacterial drug, flumequinato . . . . . . . . . .

658

Magnetic properties of nickel(II) complex with Schiff-base obtained from isatin and 5-methylthiocarbazate . . . . . . . . . . . . . . . . . . . . . . . . . .

661

Magnetic properties of nickel(II) complex with Schiff-base derived from 2,6-diformyl-4-methylpheol and 5,6-diamino-1,3dimethyluracil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

663

Magnetic properties of nickel(II) complex with 2-phenyl-2-(2-pyridyl) imidazolidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

665

Magnetic properties of nickel(II) azido complex with 2-phenyl-2(2-pyridyl)imidazolidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

668

Magnetic properties of nickel(II) complex with hexadentate Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

670

Magnetic properties of nickel(II) azido complex with 1-methyl-2(naphthyl-/-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

672

Magnetic properties of nickel(II) azido complex with 1-ethyl-2(naphthyl-/-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

675

Magnetic properties of nickel(II) azido complex with 1-methyl-2(naphthyl-β-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

678

Magnetic properties of nickel(II) azido complex with 1-ethyl-2(naphthyl-β-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

681

Magnetic properties of nickel(II) thiocyanato complex with 1-methyl-2-(naphthyl-/-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . .

684

Magnetic properties of nickel(II) thiocyanato complex with 1-methyl-2-(naphthyl-β-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . .

687

Magnetic properties of nickel(II) thiocyanato complex with 1-ethyl-2-(naphthyl-/-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . .

690

Magnetic properties of nickel(II) thiocyanato complex with 1-ethyl-2-(naphthyl-β-azo)imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . .

693

Magnetic properties of mixed ligand nickel(II) complex with 5-(3-pyridyl)-1,3,4-oxadiazol-2-thione and ethylenediamine as co-ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

696

Magnetic properties of nickel(II) complex with (2-methoxycarbonylmethylimino)-5-methyl-thiazol-3-yl)acetic acid

...

698

Magnetic properties of mixed ligand nickel(II) complex with hydrotris(3-phenyl-5-methylpyrazol-1-yl)borate, 3-phenyl-5methylpyrazole and sodium benzoate . . . . . . . . . . . . . . . . . . . . . . . . . . .

700

xxii

Contents

Magnetic properties of mixed ligand nickel(II) complex with hydrotris(3-phenyl-5-methylpyrazol-1-yl)borate, 3-phenyl-5methylpyrazole and sodium p-flourobenzoate . . . . . . . . . . . . . . . . . . . .

703

Magnetic properties of mixed ligand nickel(II) complex with hydrotris(3-phenyl-5-methylpyrazol-1-yl)borate, 3-phenyl-5methylpyrazole and sodium p-nitrobenzoate . . . . . . . . . . . . . . . . . . . . .

706

Magnetic properties of nickel(II) complex with azo-linked Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

709

Magnetic properties of nickel(II) complex with azo-linked Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

712

Magnetic properties of nickel(II) complex with azo-linked Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

715

Magnetic properties of nickel(II) complex formed by one pot reaction of 2,6-pyridinedicarboxylic acid and ethylenediamine with metal ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

718

Magnetic properties of dinuclear nickel(II) complex with tetra[(1-hydroxyiminomethylnaphthalen-2-yloxy)methyl)]ethene . . . . .

720

Magnetic properties of dinuclear nickel(II) complex with ‘end-off’ compartmental Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

723

Magnetic properties of binuclear nickel(II) complex with binucleating Schiff-base ligand with a phenylene spaer . . . . . . . . . . . . . . . . . . . . . . .

726

Magnetic properties of dinuclear nickel(II) complex with 28-membered [2+2] macrocyclic ligand derived from 1,4-bis (20 -formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane (as perchlorate salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

729

Magnetic properties of chloro bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

732

Magnetic properties of chloro bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

735

Magnetic properties of chloro bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

737

Magnetic properties of chloro bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

739

Magnetic properties of chloro dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

741

Contents

xxiii

Magnetic properties of azido bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

743

Magnetic properties of azido bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

746

Magnetic properties of azido bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

748

Magnetic properties of azido bridged dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

750

Magnetic properties of azido dinuclear nickel(II) complex with pyridylthioazophenol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

752

Magnetic properties of binuclear nickel(II) complex with 1,4,8-triaza-cycloundecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

754

Magnetic properties of unsymmetrical macrocyclic dicompartmetnal binuclear nickel(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

757

Magnetic properties of unsymmetrical macrocyclic dicompartmetnal binuclear nickel(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

760

Magnetic properties of unsymmetrical macrocyclic dicompartmetnal binuclear nickel(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

763

Magnetic properties of unsymmetrical macrocyclic dicompartmetnal binuclear nickel(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

766

Magnetic properties of unsymmetrical macrocyclic dicompartmetnal binuclear nickel(II) complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

769

Magnetic properties of [NiII 4 ] distorted cubane assembly . . . . . . . . . . . .

772

Magnetic properties of mixed ligand nickel(II) complex with tetraaza-macrocycle and isophthalic acid . . . . . . . . . . . . . . . . . . . . . . . .

775

Magnetic properties of mixed ligand nickel(II) complex with tetraaza-macrocycle and 1,3,5-cyclohexanetricarboxylic acid . . . . . . . .

778

Magnetic properties of nickel(II) complex with 1,5,9-triazacyclododecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

781

Magnetic properties of oxalato-bridged nickel(II) complex with 2-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

784

Magnetic properties of oxalato-bridged nickel(II) complex with 3-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

787

Magnetic properties of oxalato-bridged nickel(II) complex with 4-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

790

xxiv

Contents

Volume 8B Part X

Pt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

793

Magnetic properties of ion-pair complex having tetramethylethylenediaminecopper(II) cation and tetracyanoplatinate(II) anion . . . . . . . . .

795

Magnetic properties of tetra-n-butylammonium bis(benzene-1,2dithiolato-(2-)k2(S,S0 )platinate(III) . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

798

Part XI

801

Cu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Magnetic properties of copper(II) complex with clotrimazole . . . . . . . .

803

.......

805

Magnetic properties of copper(II) complex with Schiff-base obtained from isatin and 5-methylthiocarbazate . . . . . . . . . . . . . . . . . .

808

Magnetic properties of copper(II) complex with spirocyclophosphazene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

811

Magnetic properties of copper(II) complex with salicylideneanthranilic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

814

Magnetic properties of mixed ligand copper(II) complex with salicylideneanthranilic acid and 2-methyimidazole . . . . . . . . . . . . . . . .

816

Magnetic properties of mixed ligand copper(II) complex with salicylideneanthranilic acid and 2-ethylimidazole . . . . . . . . . . . . . . . . .

819

Magnetic properties of mixed ligand copper(II) complex with salicylideneanthranilic acid and benzimidazole . . . . . . . . . . . . . . . . . . .

822

Magnetic properties of mixed ligand copper(II) complex with salicylideneanthranilic acid and 2-methylbenzimidazole . . . . . . . . . . . .

824

Magnetic properties of copper(II) complex with N,N0 -ophenylenebis(3-ethoxysalicylaldimine) . . . . . . . . . . . . . . . . . . . . . . . . . .

826

Magnetic properties of 2-nitrobenzoatocopper(II) complex containing N,N-diethylnicotinamide(monomeric) . . . . . . . . . . . . . . . . . . . . . . . . . .

829

Magnetic properties of copper(II)-saccharinato complex with N-(2-aminoethyl)piperazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

832

Magnetic properties of mixed ligand copper(II) complex with azide and 2-phenyl-2-(2-pyridyl)imidazolidine (as perchlorate salt) . . .

835

Magnetic properties of mixed ligand copper(II) complex with aqua and 2-phenyl-2-(2-pyridyl)imidazolidine (as nitrate salt) . . . . . . .

837

Magnetic properties of copper(II) complex with ketoconazole

Contents

xxv

Magnetic properties of mixed ligand copper(II) complex with azide and 2-phenyl-2-(2-pyridyl)imidazolidine (as nitrate salt) . . . . . . .

839

Magnetic properties of mixed ligand copper(II) complex with acetonitrile and 2-phenyl-2-(2-pyridyl)imidazolidine . . . . . . . . . . . . . . .

841

Magnetic properties of copper(II) complex with pyrazine-2,3dicarboxylic acid and ethylenediamine . . . . . . . . . . . . . . . . . . . . . . . . .

843

Magnetic properties of copper(II) complex with pyrazine-2,3dicarboxylic acid and 2,2-dimethylpropane-1,3-diamine . . . . . . . . . . . .

846

Magnetic properties of copper(II) complex with 1,2,4-triazolo[1,5-a]-5,7-dimethylpyrimidine having ethylenediamine as auxiliary ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

849

Magnetic properties of copper(II) complex with 1,2,4-triazolo[1,5-a]-pyrimidine having ethylenediamine as auxiliary ligand . . . . . . .

852

Magnetic properties of copper(II) complex with 1,2,4-triazolo[1,5-a]-pyrimidine having 1,10-phenanthroline as auxiliary ligand (as nitrate salt] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

855

Magnetic properties of copper(II) complex with 1,2,4-triazolo[1,5-a]-5,7-dimethylpyrimidine having 1,10-phenanthroline as auxiliary ligand (as perchlorate salt] . . . . . . . . . . . . . . . . . . . . . . . . . . .

858

Magnetic properties of copper(II) complex with 1,2,4-triazolo[1,5-a]-pyrimidine having 1,10-phenanthroline as auxiliary ligand (as perchlorate salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

861

Magnetic properties of copper(II) complex with 1-(2-aminoethyl) biguanide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

864

Magnetic properties of copper(II) complex with (2-methoxycarbonylmethylimino)-5-methyl-thiazol-3-yl)-acetic acid and pyridine . . . . . . . .

866

Magnetic properties of mixed ligand copper(II) complex with ethylene-diamine as 5-(3-pyridyl)-1,3,4-oxadiazol-2-thione salt . . . . . . .

869

Magnetic properties of copper(II) nitrato complex with 2-hydroxymethyl-benzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

872

Magnetic properties of copper(II) complex with 2-hydroxymethylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

874

Magnetic properties of copper(II) complex with mesogenic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

876

Magnetic properties of copper(II) complex of Schiff-base derived from fururylamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

878

xxvi

Contents

Magnetic properties of copper(II) complex of Schiff-base derived from fururylamine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

880

Magnetic properties of imidazole complex of copper(II) benzenesulfonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

882

Magnetic properties of copper(II) thiocyanato complex with Schiff-base derived from 2,6-diformyl-4-methylpheol and 5,6-diamino1,3-dimethyluracil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

884

Magnetic properties of copper(II) nitrato complex with Schiff-base derived from 2,6-diformyl-4-methylpheol and 5,6-diamino1,3-dimethyluracil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

886

Magnetic properties of copper(II) perchlorato complex with Schiff-base derived from 2,6-diformyl-4-methylpheol and 5,6-diamino-1,3-dimethyluracil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

889

Magnetic properties of copper(II) complex with 6-acetyl-1,3,7trimethyllumazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

891

Magnetic properties of hetero-trihalide (ClBr2) mononuclear copper(II) complex with Schiff-base derived from diethylenetriamine and 2-furaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

894

Magnetic properties of homo-trihalide (BrBr2) mononuclear copper(II) complex with Schiff-base derived from diethylenetriamine and 2-furaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

896

Magnetic properties of hetero-trihalide (ClI2) mononuclear copper(II) complex with Schiff-base derived from diethylenetriamine and 2-furaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

898

Magnetic properties of hetero-trihalide (BrI2) mononuclear copper(II) complex with Schiff-base derived from diethylenetriamine and 2-furaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

900

Magnetic properties of hetero-trihalide (ClBr2) mononuclear copper (II) complex with Schiff-base derived from diethylenetriamine and 2-thiophenecarboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

902

Magnetic properties of homo-trihalide (ClI2) mononuclear copper(II) complex with Schiff-base derived from diethylenetriamine and 2-thiophenecarboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

904

Magnetic properties of hetero-trihalide (BrBr2) mononuclear copper(II) complex with Schiff-base derived from diethylenetriamine and 2-thiophenecarboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

906

Contents

xxvii

Magnetic properties of hetero-trihalide (BrI2) mononuclear copper (II) complex with Schiff-base derived from diethylenetriamine and 2-thiophenecarboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

908

Magnetic properties of hetero-trihalide (ClBr2) mononuclear copper (II) complex with Schiff-base derived from diethylenetriamine and pyrrole- 2-carboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

910

Magnetic properties of hetero-trihalide (ClI2) mononuclear copper (II) complex with Schiff-base derived from diethylenetriamine and pyrrole- 2-carboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

912

Magnetic properties of hetero-trihalide (BrI2) mononuclear copper (II) complex with Schiff-base derived from diethylenetriamine and pyrrole-2-carboxaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

914

Magnetic properties of copper(II) complex with 2-acetyl-γbutyrolactone thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

916

Magnetic properties of copper(II) chloro complex with 2-furancarbaldehyde thiosemicarbazone . . . . . . . . . . . . . . . . . . . . . . . .

918

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 2,20 -bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

920

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 4,40 -dimethylbipyridine . . . . . . . . . . . . . . . . . . . . . . .

922

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . .

924

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 4-methylphenanthroline . . . . . . . . . . . . . . . . . . . . . .

926

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 5-methylphenanthroline . . . . . . . . . . . . . . . . . . . . . .

928

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 4,7-dimethyl-1,10-phenanthroline . . . . . . . . . . . . . . .

930

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 5,6-dimethyl-1,10-phenanthroline . . . . . . . . . . . . . . .

932

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 3,4,7,8-tetramethyl-1,10-phenanthroline . . . . . . . . . .

934

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 5-phenyl-1,10-phenanthroline . . . . . . . . . . . . . . . . . .

937

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 4,7-diphenyl-1,10-phenanthroline . . . . . . . . . . . . . . .

939

xxviii

Contents

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 5-chloro-1,10-phenanthroline . . . . . . . . . . . . . . . . . .

941

Magnetic properties of mixed ligand copper(II) complex with acetylacetone and 5-nitro-1,10-phenanthroline . . . . . . . . . . . . . . . . . . .

943

Magnetic properties of mixed ligand copper(II) complex with glycine and 1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

945

Magnetic properties of mixed ligand copper(II) complex with glycine and 4-methyl-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . .

947

Magnetic properties of mixed ligand copper(II) complex with glycine and 5-methyl-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . .

949

Magnetic properties of mixed ligand copper(II) complex with glycine and 4,7-dimethyl-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . .

951

Magnetic properties of mixed ligand copper(II) complex with glycine and 5,6-dimethyl-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . .

953

Magnetic properties of mixed ligand copper(II) complex with glycine and 3,4,7,8-tetramethyl-1,10-phenanthroline . . . . . . . . . . . . . . .

955

Magnetic properties of mixed ligand copper(II) complex with glycine and 4,7-diphenyl-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . .

958

Magnetic properties of mixed ligand copper(II) complex with glycine and 5-chloro-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . .

960

Magnetic properties of mixed ligand copper(II) complex with glycine and 5-nitro-1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . .

963

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

965

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

968

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

971

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

974

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

977

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

980

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

983

Contents

xxix

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

986

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

989

Magnetic properties of copper(II) chlorocomplex with methyl-2benzimidazolecarbamate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

992

Magnetic properties of copper(II) bromocomplex with methyl-2benzimidazolecarbamate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

995

Magnetic properties of copper(II) nitrato complex with 2-methylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

997

Magnetic properties of copper(II) bromo complex with 2-phenylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

999

Magnetic properties of copper(II) chloro complex with 2-guanidinobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1002 Magnetic properties of copper(II) bromo complex with 2-guanidinobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1004 Magnetic properties of copper(II) nitrato complex with 2-guanidinobenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1006 Magnetic properties of copper(II) chloro complex with 2-phenylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1008 Magnetic properties of copper(II) chloro complex with 2-methylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1010 Magnetic properties of copper(II) bromo complex with 2-methylbenzimidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1012 Magnetic properties of copper(II) complex with 1,4-dihydroxy-9,10anthraquinone-2-sulphonate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1015 Magnetic properties of copper(II) complex of Schiff-base containing 2,4-disubstituted thiazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1017 Magnetic properties of copper(II) complex of Schiff-base containing 2,4-disubstituted thiazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1020 Magnetic properties of copper(II) nitrato complex with 2-methyl-4nitropyridine N-oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1023 Magnetic properties of copper(II) nitrato complex with 2,6-dimethyl-4nitropyridine N-oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1025 Magnetic properties of copper(II) nitrato complex with 2,3,6trimethyl-4-nitropyridine N-oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1027

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Magnetic properties of copper(II) complex with azo-linked Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1029 Magnetic properties of copper(II) complex with 15-membered diaza dioxa macrocyclic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1032 Magnetic properties of copper(II) complex with 16-membered diaza dioxa macrocyclic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1034 Magnetic properties of copper(II) complex with 15-membered diaza dioxa macrocyclic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1036 Magnetic properties of copper(II) complex with 15-membered diaza dioxa macrocyclic Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1039 Magnetic properties of copper(II) complex with N-cycloalkyl3,5-tBu2-salicylaldimine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1041 Magnetic properties of copper(II) complex with N-cyclohexyl3,5-tBu2-salicylaldimine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1043 Magnetic properties of copper(II) complex with N-cycloheptyl3,5-tBu2-salicylaldimine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1045 Magnetic properties of copper(II) complex with N-cyclooctyl3,5-tBu2-salicylaldimine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1047 Magnetic properties of copper(II) complex with N-(1-adamantyl)3,5-tBu2-salicylaldimine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1049 Magnetic properties of copper(II) complex with N-(2-adamantyl)3,5-tBu2-salicylaldimine ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1051 Magnetic properties of copper(II) complex with heterocyclic Schiff-base ligand derived from pyrazolone and semicarbazide . . . . . . 1054 Magnetic properties of copper(II) complex with heterocyclic Schiff-base ligand derived from pyrazolone and thiosemicarbazide . . . 1057 Magnetic properties of copper(II) complex with heterocyclic Schiff-base ligand derived from pyrazolone and semicarbazide . . . . . . 1060 Magnetic properties of copper(II) complex with heterocyclic Schiff-base ligand derived from pyrazolone and thiosemicarbazide . . . 1063 Magnetic properties of copper(II) complex with sulpiride drug . . . . . . 1066 Magnetic properties of copper(II) complex with 1,4,8,11-tetra (4-nitrobenzoyl)-1,4,8,11-tetraazacyclotetradecane . . . . . . . . . . . . . . . . 1068 Magnetic properties of copper(II) complex with 1,4,8,11-tetra (2-nitrobenzoyl)-1,4,8,11-tetraazacyclotetradecane . . . . . . . . . . . . . . . . 1071

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Magnetic properties of copper(II) complex with N-benzoylated 1,4,8,11-tetraazacyclotetradecane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1074 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1077 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1079 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1082 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1085 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1088 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1091 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1094 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1097 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1099 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1101 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1103 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1105 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1107 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1109 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1111 Magnetic properties of mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1113 Magnetic properties of copper(II) complex with 3-acetylcoumarinisonicotynoylhydrazone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1115

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Magnetic properties of copper(II) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl-4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin4-one . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1117 Magnetic properties of copper(II) complex with 1,8-N-bis(3-carboxy) disalicylidene-3,6-diazaocatane-1,8-diamine . . . . . . . . . . . . . . . . . . . . . . 1120 Magnetic properties of dimenic copper(II) complex with clotrimazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1122 Magnetic properties of dimeric copper(II) complex with ketoconazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1124 Magnetic properties of dinuclear copper(II) complex with Schiff-base derived from salicylaldehyde and β-alanine . . . . . . . . . . . . 1126 Magnetic properties of dinuclear copper(II) complex with pyridine-2-carbaldehyde thiosemicarbazone and trifluoroacetic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1129 Magnetic properties of dinuclear copper(II) complex with pyridine-2-carbaldehyde thiosemicarbazone and trifluoroacetic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1132 Magnetic properties of dinuclear copper(II) complex with (1,6)diazecine-based ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1135 Magnetic properties of μ-pyrazine bridged dinuclear copper(II) complex with pyridine-2-carbaldehyde thiosemicarbazone . . . . . . . . . . 1138 Magnetic properties of dinuclear copper(II) complex with pyridine2-carbaldehyde thiosemicarbazone and dicyanamide . . . . . . . . . . . . . . 1141 Magnetic properties of syn-anti acetate-bridged dinuclear copper(II) complex with 1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1145 Magnetic properties of mixed ligand dicopper complex with dibenzodioxa-tetraazamacrocycle and succinate . . . . . . . . . . . . . . . . . . 1148 Magnetic properties of mixed ligand dicopper complex with dibenzodioxa-tetraazamacrocycle and oxalate . . . . . . . . . . . . . . . . . . . . 1151 Magnetic properties of dinuclear copper(II) complex with deprotonated 2-(5-carboxy-1H-pyrazol-3-yl)-4,4,5,5-tetramethyl4, 5-dihydro-1H-imidazole . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1154 Magnetic properties of dinuclear copper(II) acetato complex with pyrazol-3-yl-substituted imino nitroxide . . . . . . . . . . . . . . . . . . . . . . . . 1157 Magnetic properties of dinuclear copper(II) complex with 5-carboxypyrazol-3-yl-substituted nitronyl nitroxide . . . . . . . . . . . . . . . . . . . . . . . 1160

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Magnetic properties of chloro bridged dinuclear copper(II) complex with 2-acetyl-2-thiazoline hydrazone . . . . . . . . . . . . . . . . . . . . 1163 Magnetic properties of hydroxo-bridged dinuclear copper(II) complex with saccharinate-N . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1167 Magnetic properties of hydroxo-bridged dinuclear copper(II) complex with saccharinate-O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1170 Magnetic properties of 2-nitrobenzoatocopper(II) complex containing N,N-dimethylformamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1173 Magnetic properties of dinuclear copper(II) complex with pyrazine and 2-phenyl-2-(2-pyridyl)imidazolidine (as perchlorate salt) . . . . . . . . 1176 Magnetic properties of dinuclear copper(II) complex with 28membered [2 + 2] macrocyclic ligand derived from 1,4-bis (20 -formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane (as nitrate salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1178 Magnetic properties of dinuclear copper(II) complex with pyrimidine derived Schiff-base ligand and 4,40 -bipyridine . . . . . . . . . . . . . . . . . . . . 1181 Magnetic properties of bis(μ-phenoxo) bridged dinuclear copper(II) complex with pyrimidine derived Schiff-base ligand . . . . . . . . . . . . . . . 1184 Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1187 Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1190 Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1193 Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1196 Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1199 Magnetic properties of dinuclear copper(II) complex with 1,2,4-triazolo-[1,5-a]pyrimidine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1202 Magnetic properties of dinuclear copper(II) hydrazido complex ligated by hydrotris-(pyrazolyl)borate . . . . . . . . . . . . . . . . . . . . . . . . . . 1205 Magnetic properties of amidocyanamide bridged dinuclear copper(II) complex with picolinic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1208 Magnetic properties of imidazolato-bridged homo-dinuclear copper (II) complex with macrocyclic ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . 1211

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Magnetic properties of macrocyclic unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy)-ethane and 1,8-diaminonaphthalene . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1214 Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformylphenol-1,2bis(aminoxy)-ethane and 1,2-diaminobenzene . . . . . . . . . . . . . . . . . . . . 1217 Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformylphenol-1,2bis(aminoxy)-ethane and 1,4-diaminobutane . . . . . . . . . . . . . . . . . . . . . 1220 Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformyl-4-methylphenol 1,2-bis(aminoxy)ethane and propylenediamine . . . . . . . . . . . . . . . . . . . 1223 Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformyl-4-methylphenol 1,2-bis(aminoxy)ethane and ethylenediamine . . . . . . . . . . . . . . . . . . . . . 1227 Magnetic properties of macrocyclic symmetrical binuclear copper(II) complex derived from mononuclear copper(II) complex having macrocyclic ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1230 Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . . . . . 1233 Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . . . . . 1236 Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . . . . . 1239 Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . . . . . 1242 Magnetic properties of dinuclear copper(II) complex having chloro and 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . 1245 Magnetic properties of dinuclear copper(II) complex having chloro and 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . 1248 Magnetic properties of dinuclear copper(II) complex having chloro and 6-(benzylamino)purine as bridging ligand . . . . . . . . . . . . . . . . . . . 1251 Magnetic properties of copper(II) complex with coumarin-derived Schiff-base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1254

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Magnetic properties of dinuclear copper(II) complex with ‘end-off’ compartmental Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1257 Magnetic properties of mixed ligand binuclear copper(II) complex with 1,10-phenanthroline and N,N,N0 ,N0 -tetrakis (2-pyridylmethyl)benzene-1,3-diamine . . . . . . . . . . . . . . . . . . . . . . . . . . 1260 Magnetic properties of chloro-bridged binuclear copper(II) complex with N,N,N0 ,N0 -tetrakis(2-pyridylmethyl)benzene-1,3-diamine . . . . . . . 1264 Magnetic properties of binuclear copper(II) complex with 1,2,4-triazole based ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1268 Magnetic properties of dinuclear copper(II) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine . . . . . . . . . 1271 Magnetic properties of dinuclear copper(II) complex with 1,10-phenanthroline as 4,6-dimethyl-1,2,3-triazolo[4,5-d]pyrimidin5,7-dionato salt . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1274 Magnetic properties of dinuclear mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . 1277 Magnetic properties of dinuclear mixed ligand copper(II) complex with diester and dinitrogen base ligands . . . . . . . . . . . . . . . . . . . . . . . . 1280 Magnetic properties of dinuclear copper(II) complex with tetra[(1-hydroxyiminomethylnaphthalen-2-yloxy)methyl)]ethene . . . . . 1282 Magnetic properties of binuclear copper(II) complex with binucleating Schiff-base ligand with a phenylene spaer . . . . . . . . . . . . . . . . . . . . . . . 1285 Magnetic properties of imidazolate-bridged hetero-dinuclear copper(II)-zinc(II) complex with macrocyclic ligand . . . . . . . . . . . . . . . 1288 Magnetic properties of copper(II) complex with pyrimidine derived Schiff-base ligand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1291 Magnetic properties of μ-hydroxo-μ-propionato bridged trinuclear copper(II) complex with N-(pyrid-2-ylmethyl) benzenesulfonylamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1294 Magnetic properties of μ-hydroxo-μ-propionato bridged trinuclear copper(II) complex with N-(pyrid-2-ylmethyl)p-toluenesulfonylamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1297 Magnetic properties of μ-hydroxo-μ-propionato bridged trinuclear copper(II) complex with N-(pyrid-2-ylmethyl) naphthalenesulfonylamide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1300

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Magnetic properties of trinuclear copper(II) complex with 1,5-bis(di-2-pyridylketone)carbohydrazone . . . . . . . . . . . . . . . . . . . . . . 1303 Magnetic properties of copper(II) complex formed by one pot reaction of 2,6-pyridinedicarboxylic acid and ethylenediamine with metal ion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1306 Magnetic properties of tetranuclear pyrophosphate bridged copper(II) complex with 2,20 -dipyridylamine . . . . . . . . . . . . . . . . . . . . . 1308 Magnetic properties of tetranuclear copper(II) acetato complex with pyrazol-3-yl-substituted nitronyl nitroxide . . . . . . . . . . . . . . . . . . . 1311 Magnetic properties of phenoxo-bridged tetranuclear copper(II) complex having 2-hydroxy-N-(2-pyridylmethyl)benzamide . . . . . . . . . . 1314 Magnetic properties of heterotetranuclear Cu3Mn complex with N,N0 -o-phenylene-bis(3-ethoxysalicylaldimine) . . . . . . . . . . . . . . . . . . . . 1316 Magnetic properties of heterotetranuclear Cu3Co complex with N,N0 -o-phenylene-bis(3-ethoxysalicylaldimine) . . . . . . . . . . . . . . . . . . . . 1319 Magnetic properties of ion-pair complex containing substituted pentadecanecopper(II) cation and hexacyanoferrate anion . . . . . . . . . . 1322 Magnetic properties of hexanuclear copper(II) carboxylate complex with 2,20 -bipyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1325 Magnetic properties of heptanuclear CuII 7 complex with N,N0 -o-phenylene-bis(3-ethoxysalicylaldimine) . . . . . . . . . . . . . . . . . . . . 1328 Magnetic properties of carbonato and hydroxide bridged octanuclear copper(II) complex with 1,10-phenanthroline . . . . . . . . . . . . . . . . . . . . 1331 Magnetic properties of paradodecatungstate derivative of trinuclear copper(II) azido complex with 2-pyrazine carboxylic acid . . . . . . . . . . 1334 Magnetic properties of anionic 4-terpyridone based copper(II) azide supramolecule containing dinuclear-mononuclear co-crystals . . . . . . . . 1337 Magnetic properties of copper(II) azido cluster with Schiff-base derived from 2,6-diformyl-4-methylphenol and tris(hydroxymethyl) aminomethane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1341 Magnetic properties of dicyanamide bridged polymeric copper(II) complex with di(2-pyridylmethyl)amine . . . . . . . . . . . . . . . . . . . . . . . . . 1344 Magnetic properties of copper(II) polymer with alternating μ1,3-squarato and binucleating polypyridylamine bridges . . . . . . . . . . . 1347 Magnetic properties of copper(II) complex with 5,6-diphenyl-3 (2-pyridyl)-1,2,4-triazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1350

Contents

xxxvii

Magnetic properties of copper(II) complex with vic-dioxime ligand containing 1,8-diamino-3,6-dioxaoctane group . . . . . . . . . . . . . . . . . . . 1354 Magnetic properties of 2-nitrobenzoatocopper(II) complex containing N,N-diethylnicotinamide (polymeric) . . . . . . . . . . . . . . . . . . . . . . . . . . . 1357 Magnetic properties of copper(II)-saccharinato complex with piperazine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1360 Magnetic properties of polymeric copper(II) complex with Schiff-base derived from salicylaldehyde and β-alanine . . . . . . . . . . . . . . . . . . . . . . 1363 Magnetic properties of copper(II) complex with vic-dioxime ligand containing 1,8-diamino-3,6-dioxaoctane group . . . . . . . . . . . . . . . . . . . 1366 Magnetic properties of oxalato-bridged copper(II) complex with 4-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1369 Magnetic properties of oxalato-bridged copper(II) complex with 3-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1372 Magnetic properties of oxalato-bridged copper(II) complex with 2-aminopyridine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1375 Magnetic properties of bimetallic oxide Cu-Mo4 containing p-xylene diphosphonic acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1378 Part XII

Gd . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1381

Magnetic properties of quaternary selenide of barium gadolinium and copper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1383 Magnetic properties of quaternary selenide of cesium gadolinium and zinc . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1385 Part XIII

Tb . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1387

Magnetic properties of bipyrimidine-bridged dinuclear terbium(III) complex containing bulky-β-diketonate terminal ligand . . . . . . . . . . . . 1389

Introduction

General Remarks Polynuclear metal complexes have continued to attract considerable attention because of their outstanding physical properties and complexity of structures. Thus in continuation to our work on “Magnetic Susceptibility Data” starting with a new Volume II/31/A titled “Magnetic Properties of Paramagnetic Compounds” in 2012 [1] and four supplement volumes [2], herein we present more new volumes titled “Magnetic Properties of Paramagnetic Compounds – Magnetic Susceptibility Data” covering literature for the period 2001–2010. With increasing demand for online study material, a new pattern is being introduced to facilitate the search of magnetic data in online mode. During the decade of 2001–2010, studies are mainly focused on two types of molecular magnetic material – molecular nanomagnets and multifunctional magnetic materials [3, 4]. The area of molecular nanomagnets has largely involved work on single-molecule magnets (SMMs). Most SMMs are polynuclear clusters of different structural types. Many groups have reported the synthesis of such material by exploiting molecular (bottom-up) or classical (top-bottom) approaches [3, 5]. It is revealed that for SMM behaviour, it is not the size of the cluster but the value of the ground state-spin S and the magnetic anisotropy D that matters the most. Hence, a prerequisite for a useful SMM is that it should have a large ground-state spin, large negative D and small E according to the following Hamiltonian [4, 6, 7]: ℋ ¼ DS 2Z þ E S2x  S2y where E ¼ energy of spin-levels The strength of the spin-orbit coupling is the main factor to determine the magnitude of anisotropy barrier rather than artificial optimization of D and S as suggested by Ruiz [8] and Peligkos [9] based on theoretical calculations.

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_1

1

2

Introduction

On the basis of above concepts, experimentally several groups have reported syntheses of SMMs of diverse structures [3, 4] but Mn12 complex, [Mn12O12(CH3COO)16(H2O)4].2CH3COOH.4H2O, first reported by Lis in 1980 [10] and its carboxylate derivatives remains one of the best choice that can function as SMM at the highest temperatures; others showing slow relaxation effects at lower temperatures. Next ferromagnetically coupled Mn19 aggregate has been reported that exhibited maximum spin ground state of 83/2, but it had very low anisotropy [6]. Another Mn10 cluster reported possessed rare T point group symmetry and high S ¼ 22 ground state spin [11]. The next break-through in the area of molecular nanomagnets was single-ion lanthanide SMM complexes [12]. Subsequently, Bogani [13] has reported a new rare-earth heteroleptic bis (phthalocyaninato)terbium(III) complex attached to single-walled carbon nanotubes (SWNTs) conjugate as promising unit in SMMs arena. The motivation for research in SMMs ranges from their application in magnetic storage of information, molecular electronics, quantum computing, magnetic drug delivery, contrast agents for MRI, etc [4]. Another related area which is fast-developing is that of single-chain magnets (SCMs) [14, 15] also called magnetic nanowires. Basically, these are one-dimensional equivalents of SMMs and have the properties of withstanding to higher temperature than SMMs for molecular paramagnets. One of the approach to design SCMs, illustrated by Miyasaka et al. [16], involved coupling of single-molecule magnets in one-direction. Later Tao [17] have argued that if SCMs could be crystallised into acentric or noncentric structures, it would be possible to obtain SCMs having nonlinear optical, ferroelastic and dielectric properties. Thus, this group has reported a novel MnIII 3 O complex which possessed, both magnetization relaxation and dielectric relaxation properties. Another noteworthy example is of vanadosilicate zeolite AM-6, first reported example of microporous material incorporating ferromagnetic chains [18]. Among magnetic nanoparticles, a new field of coordination nanoparticles (CNP) has also emerged during 2001–2010 decade particularly by Mann et al. [19] upon stability of nanocrystals of Prussian Blue Analogue (PBA). The light-induced magnetic behaviour was not examined until 2007 when Mallah [20] reported first example of photoinduced supermagnetism in trimetallic CNP, CuNiMo(CN)8. The field of organic molecule-based magnetic materials has also expanded rapidly and a library of about 40–50 ferromagnets have been well-documented [21]. Their ferromagnetic behaviour has also attracted widespread interest [22]. Among multifunctional magnetic materials, two categories of materials, viz switching magnetic materials and dual-function materials are being explored for advanced properties such as magnetic ordering combined with conductivity, superconductivity or ferroelectricity [3]. Examples of switching magnetic materials include spin-crossover compounds [23] and magnets based on PBA [24]. Dual-functional molecular materials displaying both conductive and magnetic properties are usually based on the use of charge-transfer salts [25]. A remarkable

Susceptibility Units

3

example being cationic conducting network based on tetrathiofulvalene (TTF) and anionic metal complexes serving as magnetic components [26]. Next Robertson and co-workers [27] have reported ferromagnetism in a heavy atom heterocyclic resonance-stabilized bisdithiazolyl radicals conductor. Due to their promising applications in magnets, molecular switches and memory devices, interest in spin-crossover (SCO) systems has grown significantly, especially those of Fe(II) [28]. Some important examples are iron(II)-iron(III) mixed valence supramolecular pseudo-dimer [29], heptanuclear mixed-valence iron complex [30] and a 2D polymer {FeII(4-methylpyridine)2[AuI(CN)2]2 [31] in which an unprecedented three-step SCO behaviour has been observed. Despite powerful medical diagnostic applications of MRI, its low sensitivity has been a constraint [32–34]. To overcome the problems, multifunctional magnetic nanocrystals are emerging in biomedical applications as reported by Cheon et al. [35, 36]. Thus clinically, iron-oxide based magnetic nano-particles such as supermagnetic iron oxide (SPIO) and related systems have been widely explored for signal enhancing purposes. Focus has also been shifted to in vivo magnetic resonance detection of cancer cell lines by using water-soluble magnetic iron-oxide (WSIO) nanocrystals [33]. Besides gold nanoparticles, have also been exploited by cellular studies because of their hypothermal properties [34, 37]. Recently, a new class of MRI contrast agents based on chemical exchange-dependent saturation transfer (CEST) has attracted considerable attention because the image contrast can be switched “on and off” as per desirability by controlling parameters like pH, temperature, etc [38, 39]. It is reported that, of the lanthanide ions, ytterbium allows for the highest paraCEST effect. Thus, Burdinski [40] has synthesized Yb complexes of hexa-acetamide ligands and studied their CEST properties.

Susceptibility Units The susceptibility data have again been mostly reported at room temperature and the studies down to 0.0 K have oftenly been reported in the form of figures (as curves of χ M vs. T or μeff vs. T or χ MT vs. T ). Throughout the volume the data have been reported in CGS units, commonly abbreviated as cgs or cgs-emu and represented as cm3mol1. The SI units wherever reported have been changed into the cgs units by the following conversion factor: χM SI m3 mol1 ¼ 4π  106 χM cgs cm3 mol1 The sign convention used throughout this volume is that negative value of J signifies antiferromagnetic coupling i.e. where the ground state has minimum multiplicity. All over the files ‘c’ after numbers stands for corrected value of magnetic moment and paramagnetic susceptibility after making diamagnetic corrections.

4

Introduction

Organization of Files With the objective to collate the enormous amount of information on magnetic susceptibility parameters of a very large number of a variety of skeletons and present it in a form that can readily be retrieved and used, a new pattern has been being introduced with effect from volumes 1 to 4 – supplement to LB-II/31 series [2] keeping in view that now a majority of research groups look at the scientific data electronically. All the magnetic properties of each individual substance are being documented as a single file and every single document is self-explainable. Each file is comprised of Title of the document listing searchable and common vocabulary as well as synonyms, Name of the substance according to IUPAC system and its abbreviated formula, CAS-number (wherever available), Gross formula, Properties – listing all properties reported using a standard SpringerMaterials term (see next section) and the Structure – a completely drawn structure of the molecule and/or ligand as well as a separate molefile of the compound is provided to allow even structure searches. The magnetic data have been presented in the form of table. It is followed by additional remarks such as susceptibility equations, exchange parameters, etc. and figures with captions showing curves of χ M vs. T or μeff vs. T or χ MT vs. T, wherever appropriate. Temperature and pH dependence, if reported, is indicated in the remarks column. As far as possible the reference is made to the original literature. The files are listed under their central metal ion or atom (transition metal, lanthanide or actinide). The transition elements are listed by the group in which they occur in the periodic table starting with Group IV (Ti, Zr, Hf) and proceeding until Group I (Cu, Ag, Au) followed by lanthanides and actinides.

SpringerMaterials Term All the properties and their symbols described in this volume are listed below using a standard vocabulary: a, b, c [Å] B BJ (x) c C Cm [emu K mol1] D, E [cm1] e g g||, g⊥ H [G]

lattice parameters magnetic induction Brillouin function concentration Curie constant molar Curie constant constants of spin Hamiltonian describing zero field splitting parameters electron charge spectroscopic splitting factor or Lande factor spectroscopic splitting factor parallel and perpendicular to the principal magnetic axis applied magnetic field (continued)

SpringerMaterials Term H HDVV J, J12, Jij J J k L M [G emu/cm3 ¼ G] m (M ) N Nα [emu mol1] pm (μB or μeff) S T [K] Tc To TIP t2g, eg V ZFS ZJ 0

α β δ ζnd [cm1] Θp [K] ΘN or TN [K] ΘC or TC [K] σ κ [emu/cm3] λ [cm1] μB or β χA χ g [emu/g] χ M [emu/mol] χp χs χ ||, χ ⊥ [emu/mol] χ MT [cm3 K/mol]

5 Hamiltonian Heisenberg-Dirac-van Vleck model exchange integral Exchange energy, value quoted as J/k in [K], J/hc in [cm1] or J/T in multiples of k total angular momentum Boltzmann constant total orbital angular momentum magnetic moment per unit volume ¼ magnetization electron mass molecular weight Avogadro number temperature-independent paramagnetism (TIP) per mole effective magnetic moment per molecule in Bohr magnetons total spin angular momentum temperature (in degrees Kelvin) critical temperature of phase transition effective spin-exchange temperature temperature-independent paramagnetism subshells of d electrons in octahedral field molecular volume zero-field splitting Z is the number of nearest neighbor J 0 is exchange integral for the magnetic interaction between nearest neighbor chains TIP per molecule Bohr magneton percentage monomeric impurity spin-orbit coupling constant for single d electron paramagnetic Curie constant (Weiss constant) Néel temperature ferromagnetic Curie temperature spontaneous magnetic moment volume susceptibility spin-orbit coupling constant for the ground state Bohr magneton magnetic susceptibility per gram-atom (average atomic susceptibility) magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) Pauli susceptibility spin susceptibility principal molar susceptibilities parallel and perpendicular to the principal magnetic axis product of molar magnetic susceptibility with temperature

6

Introduction

Experimental Methods for Determination of Magnetic Susceptibility Various methods/instruments used for the precise measurement of the magnetic susceptibility are listed below: Abbreviation a.c. Evans Faraday Gouy Johnson Matthey NMR Pend. SQUID Tors. VSM

Description of method alternate current mutual inductance bridge method Evans balance Faraday method Gouy method or Pascal method Johnson Matthey balance nuclear magnetic resonance method pendulum magnetometer superconducting quantum interference device torsional balance with electromagnetic compensation Vibrating-sample magnetometer

Ref. [41] [42] [43–46] [47–51] [52, 53] [54] [55] [56] [57, 58] [59, 60]

Theoretical Aspects of Paramagnetic Susceptibility A detailed theoretical analysis of magnetic susceptibility has been described in the First Volume of II/31A Series [1]. Major new developments are summarized below: The susceptibility data for mixed-valent manganese-rods like SMM complex [Mn12O14(OH)2(C6H5COO)12 (thmne)4(C5H5N)2]{H3thme ¼ 1,1,1-tris(hydroxyme thyl)ethane)} with S ¼ 7 ground state were fitted to a model that assumed only the ground state to be populated [61]. ℋ ¼ D S2Z þ gμB μθ Sz H 2

ð1Þ

where D ¼ axial anisotropy, μθ ¼ vacuum permeability, μB ¼ Bohr magneton, Sz ¼ easy-axis spin operator, Hz ¼ applied field The magnetic data showed the complex to be a SMM. The magnetic susceptibility of unidimentional chains of antiferromagnetically coupled [Mn4] complexes have been interpreted by using Chain model [62] with ST ¼ 9 and confirm SMM behaviour:

Theoretical Aspects of Paramagnetic Susceptibility

xM T ¼ xk þ 2x⊥ T=3 ¼ C ð1  xÞ exp 4JS 2T =kB T þ x=2 þ 2x⊥ T =3

7

ð2Þ

where x ¼ amount of defaults of missing links C ¼ Currie constant of the constitutive unit of the chain xǁ & x⊥ ¼ parallel and perpendicular susceptibility The magnetic properties of dimeric SCM MnIII quadridentate Schiff-base compound [Mn2(salph)2(H2O)2] (ClO4)2 {salph2 ¼ N,N 0 -(propane)bis(salicylideneiminate)} have been stimulated by considering the following spin Hamiltonian [15]: ℋ ¼ 2J ðSMn1 :SMn2 Þ þ DMn S2Z,Mn1 þ S2Z,Mn2

ð3Þ

where J ¼ MnIII-MnIII intradimer magnetic interaction DMn ¼ zero-field splitting parameter of a single MnIII ion Sz,Mn ¼ z component of the SMn operators On the basis of exchange interaction, slow relaxation of the magnetization at low temperature, M versus H data, hysteresis effects and finite-size effects, it is suggested that the magnetic properties of this complex could be regarded as intermediate between SMM and single-chain magnet (SCM). For single-chain magnet (SCM) (NEt)4[Mn2(5-MeOsalen)2Fe(CN)6] (5-MeOsalen2 ¼ N,N 0 -ethylenebis(5-methoxysalicylideneiminate) made of MnIIIFeIII-MnIII trinuclear SMM with an ST ¼ 9/2 spin ground state, magnetic susceptibility was calculated based on a Heinseberg trinuclear model with spin system (SMnSFe-SMn ¼ 2, ½, 2) and assuming JMn-Mn to be smaller than JMn-Fe and external magnetic field (H ) along the z axis (Hz) [16]: ℋ ¼ 2J MnFe ðS Mn1 S Fe þ S Mn1A SFe Þ þ gav μB STz H z

ð4Þ

where ST ¼ total spin operator of trimer with ST ¼ SMn1 + SFe + SMn1A STZ ¼ Z component of the ST operator gav ¼ Lande factor assuming gav ¼ gMn ¼ gFe In order to accurately calculate the magnetic susceptibility, interchain intertrimer interaction factor J 0 was introduced: x¼

xtrimer 0 1  Ng2zJ2 μ2 xtrimer

ð5Þ

B

The detailed analysis of SCM behaviour is consistent with magnetic parameters independently estimated (J 0 and DT) and allow the determination of the average

8

Introduction

chain length. It illustrates a new strategy to design SCM by coupling ferromagnetically single-molecule magnets in one direction. The magnetic susceptibility of oxalate (ox) based Fe(II) SCM [Fe(II)(ox) (btz)]n(btz ¼ benzotriazole) has been described by Keene, Price and Decurtins [63] and the data have been modelled from the equation of Drillion et al. [64]: xM ¼

2Ng 2 μ2B : exp ð4J=kB T Þ kB T

ð6Þ

It is noted that the complex shows the Dzyaloshinskii-Moriya (D-M) interaction [65] which leads to spin canting through antisymmetric spin-exchange. A similar spin canting arising from D-M interaction [65] has also been observed in trimeric Co(II) magnetic coordination polymer, [Co3(OH)2(pa)2(ina)2] {pa ¼ 3-(1H-benzimidazol-2-yl)propanoic carboxylate; ina ¼ isonicotinate} [66]. The magnetic data of this new 2D polymer were evaluated by theoretical expression of a trimer model possessing antiferromagnetic interactions: ℋex ¼ 2J ðS1 S2 þ S2 S3 Þ

ð7Þ

Then, EðS0 , S13 Þ ¼ J ðS0 ðS0 þ 1Þ  S13 ðS13 þ 1Þ  S2 ðS2 þ 1ÞÞ where S13 ¼ S1 þ S3 ; S03 ¼ S13 þ S2 ; 0

x0 ¼

Nβ2 g2 ΣS0 ðS0 þ 1Þð2S0 þ 1ÞeEðS Þ=kT 0 3kT Σð2S0 þ 1ÞeEðS Þ=kT xM ¼

x0 1

2zJ 0 x0 =Nβ2 g2

ð8Þ ð9Þ

where J ¼ intratrimer exchange interaction J 0 ¼ intertrimer exchange interaction z ¼ number of nearest neighbours of the trimer A comparison of the stimulating methods to understand the behaviour of an S ¼ ½ ferromagnetically-coupled sheet and an S ¼ ½ tetranuclear butterfly cluster {[Cu4(μ3-OH)2(μ-tla)6].4H2O}/ (tla ¼ tetrazole-1-acetate) has been described by Keene et al. [67] based on Hamiltonian: ℋ ¼ 2J 1 ðSA :SB Þ  2J 2 ðSA :SC þ SA :SD þ SB :SC þ SB :SD Þ using vector coupling, it is then possible to evaluate magnetic susceptibility:

ð10Þ

References

9

x M ¼ ð 1  pÞ

2Ng2 μ2B A Ng 2 μ2B SðS þ 1Þ þP : 3kB T kB T B

ð11Þ

where A ¼ exp(3/2J1/kBT ) + exp(1/2J1/kBT ) + exp((1/2J1 + 4J2)kBT) + 5exp(1/2J1  2J2/kBT ) B ¼ 4exp(3/2J1/kBT ) + exp(1/2J1/kBT ) + exp((1/2J1 + 4J2)kBT ) + 3exp((1/2J1 + 2J2)/kBT ) + 5exp((1/2J1  2J2)/kBT ) p ¼ percentage paramagnetic impurity A molecular field approximation approach has been applied to evaluate the magnetic data of [2  2 + 1  3] heptanuclear Cu7III inclusion compound derived from N,N 0 -o-phenylenebis(3-ethoxysalicylaldimine) assuming very weak Cu—O—H— Cu interaction and same volume of μCu of all Cu(II) centres [68]: xM ¼

1

x1M 0 1 2zJ xM =Nβ2 g2

ð12Þ

where x1M ¼

1:5995xD T þ 3μ2Cu 7:997 T

xD ¼

Nβ2 g2 2e2J=kT kT 1 þ 3e2J=kT

with

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11

36. H.-T. Song, J.-S. Choi, Y.-M. Huh, S.J. Kim, Y.-W. Jun, J.-S. Suh, J. Cheon, J. Am. Chem. Soc. 127, 992 (2005) 37. D.P. O’Neal, L.R. Hirch, N.J. Halas, J.D. Payne, J.L. West, Cancer Lett. 209, 171 (2004) 38. S. Aime, S. Geninatti Crich, E. Gianolio, G.B. Giovenzana, L. Tei, E. Terreno, Coord. Chem. Rev. 250, 1562 (2006) 39. S. Aime, D. Delli Castelli, E. Terreno, Angew. Chem. Int. Ed. 44, 5513 (2005) 40. D. Burdinski. J. Lub, J.A. Pikkemaat, D.M. Jalon, S. Martial, C.D.P. Ochoa, Dalton Trans. 4138 (2008) 41. A. Van der Bilt, K.O. Joung, R.L. Carlin, L. De Jongh, J. Phys. Rev. B 22, 1259 (1980) 42. D.F. Evans, G.V. Fazakerley, R.F. Philips, J. Chem. Soc. A 1931 (1971) 43. M. Faraday, Exp. Res. Lond. 7, 27 (1855) 44. L.F. Bates, Modern Magnetism, 3rd edn. (Cambridge University Press, London, 1951) 45. J. Josephsen, E. Pedersen, Inorg. Chem. 16, 2534 (1977) 46. E. Pedersen, Acta Chem. Scand. 26, 333 (1972) 47. L.G. Gouy, Compt. Rend. 109, 935 (1889) 48. S.S. Bhatnagar, K.N. Mathur, Physical Principles and Applications of Magnetochemistry (McMillan, London, 1935) 49. P.W. Selwood, Magnetochemistry, 2nd edn. (Interscience, New York, 1951) 50. R.S. Nyholm, Quart. Rev. 377 (1953) 51. L.N. Mulay, Magnetic Susceptibility (Interscience, New York, 1966) 52. A.R. Wills, P.G. Edwards, J. Chem. Soc. Dalton Trans. 1253 (1989) 53. L.-Y. Chung, E.C. Constable, M.S. Khan, J. Lewis, Inorg. Chim. Acta 185, 93 (1991) 54. D.F. Evans, J. Chem. Soc. 2003 (1959) 55. J.C. Bernier, P. Poix, Actual. Chim. 2, 7 (1978) 56. J.S. Philo, W.M. Fairbank, Rev. Sci. Instrum. 48, 1529 (1977) 57. F.E. Mabbs, D.J. Marchin, Magnetism and Transition Metal Complexes (Chapman and Hall, London, 1975) 58. M. Suzuki, T. Sugisawa, A. Uehara, Bull. Chem. Soc. Jpn. 63, 1115 (1990) 59. D.B. Brown, V.H. Crawford, J.W. Hall, W.E. Hatfield, J. Phys. Chem. 81, 1303 (1977) 60. J.S. Haynes, K.W. Oliver, S.J. Rettig, R.C. Thompson, J. Trotter, Can. J. Chem. 62, 891 (1984) 61. G. Rajaraman, M. Murugesu, E.C. Sanudo, M. Soler, W. Wernsdorfer, M. Helliwell, C. Muryn, J. Raftery, S.J. Teat, G. Chirstou, E. Brechin, J. Am. Chem. Soc. 126, 15445 (2004) 62. L. Lecren, O. Roubeau, Y-G. Li, X.F. Le Goff, H. Miyasaka. F. Richard. W. Wernsdorfer, C. Coulon, R. Clerac, Dalton Trans. 755 (2008) 63. T.D. Keene, I. Zimmermann, A. Neels, O. Sereda, J. Hauser, M. Bonin, M.B. Hursthouse, D.J. Prie, S. Decurtins, Dalton Trans. 39, 4937 (2010) 64. A. Maignan, V. Hardy, S. Hebert, M. Drillon, M.R. Lees, O. Petrenko, D. Mc, K. Paul, D. Khomskii, J. Mater. Chem. 14, 231 (2004) 65. I. J. Dzyaloshinskii, J. Phys. Chem. Solids 4, 241 (1958); T. Moriya, Phys Rev. 120, 91 (1960) 66. M-X. Yao, M-H. Zeng, H-H. Zou, Y-L. Zhou, H. Liang, Dalton Trans. 2428 (2008) 67. T.D. Keene, Y.-H. Deng, F.G. Li, Y.-F. Ding, B. Wu, S.-X. Liu, C. Ambrus, O. Waldmann, S. Decurtins, X.-J. Yang, Inorg. Chim. Acta 362, 2265 (2009) 68. M. Nayak, S. Hazra, P. Lemoine, R. Koner, C.R. Lucas, S. Mohanta, Polyhedron 27, 1201 (2008)

Part I V

Magnetic properties of dimeric vanadium(II) complex with bulky terphenyl thiolate

Substance Vanadium(II) complex with bulky terphenyl thiolate; [V(μ-L)I]2

Gross Formula C60H74I2S2V2

Properties Molar magnetic moment

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15

Magnetic properties of dimeric vanadium(II) complex with bulky. . .

16

Structure [V(μ-L)I]2;

HL ¼ terphenyl thiol

SH

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.61/V

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Evans

Remarks in C6D6 solution

Reference

17

Additional Remark (i) d3 electronic configuration, little coupling between vanadium(II) ions

Symbols and Abbreviations Short form T χg χM Evans pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) Evans balance effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference A.D. Sutton, J.C. Fettinger, B.D. Rekken, P.P. Power, Polyhedron 27, 2337 (2008)

Magnetic properties of vanadium(III) complex with anthranilate

Substance Tris(anthranilato]vanadium(III); [V(anc)3]

Gross Formula C21H9N3O6V

Properties Molar magnetic moment and product of molar magnetic susceptibility with temperature

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18

Reference

19

Structure ancNa ¼ sodium anthranilate

[V(anc)3];

O

NH2

O H2N O

H2 N

O NaO

V O NH2

O

O

Data T [K] –

χg [106 emu/g] –

χ MT [cm3 K mol1] 0.556

pm or μeff [μB] 2.02 2.17 (corr)

ΘP [K] –

Method JohnsonMatthey

Remarks d2 V(III) complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference C.C. McLauchlan, J.D. Hooker, M.A. Jones, Z. Dymon, E.A. Backhus, B.A. Greiner, N.A. Dorner, M.A. Youkhana, L.M. Manus, J. Inorg. Biochem. 104, 274 (2010)

Magnetic properties of vanadium(III) complex with imidazol-4-carboxylate

Substance [Tris(imidazol-4-carboxylato)]vanadium(III) monohydrate; [V(imc)3].H2O

Gross Formula C12H11N6O7V

Properties Molar magnetic moment and product of molar magnetic susceptibility with temperature

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_4

20

Reference

21

Structure imcNa ¼ sodium imidazol-4-carboxylate NH

[V(imc)3].H2O; O O

HN

N

N

HN N

NaO

V O

O

O

O

N

O

NH

Data T [K] –

χg [106 emu/g] –

χ MT [cm3 K mol1] 0.908

pm or μeff [μB] 2.71 2.76 (corr.)

ΘP [K] –

Method JohnsonMatthey

Remarks d2 V(III) complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference C.C. McLauchlan, J.D. Hooker, M.A. Jones, Z. Dymon, E.A. Backhus, B.A. Greiner, N.A. Dorner, M.A. Youkhana, L.M. Manus, J. Inorg. Biochem. 104, 274 (2010)

Magnetic properties of vanadium(III) chloro complex with trans-urocanic acid

Substance Vanadium(III) chloro complex with trans-urocanic acid; [V(thf)(ua)2Cl]

Gross Formula C10H9ClN2O3V

Properties Molar magnetic moment

Structure [V(thf)(ua)2Cl];

ua ¼ trans-urocanic acid; COOH N N H

thf ¼ tetrahydrofuran

O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_5

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Reference

23

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.72

ΘP [K] –

Method Evans

Remarks d2 electronic structure

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Evans

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Evans balance

Reference H. Podsiadly, Polyhedron 27, 1563 (2008)

Magnetic properties of vanadium(III) complex with bulky terphenyl thiolate

Substance Vanadium(III) complex with bulky terphenyl thiolate; [V(L)2I]

Gross Formula C60H74IS2V

Properties Molar magnetic moment

Structure [V(L)2I];

HL ¼ terphenyl thiol

SH

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_6

24

Reference

25

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.64

ΘP [K] –

Method Evans

Remarks in C6D6 solution

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) d2 electronic configuration, little orbital contribution

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Evans

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Evans balance

Reference A.D. Sutton, J.C. Fettinger, B.D. Rekken, P.P. Power, Polyhedron 27, 2337 (2008)

Magnetic properties of vanadium(III) 2-dimensional network (vanadyl chains linked by arydioxide)

Substance Vanadium(III) 2-dimensional network (vanadyl chains linked by arydioxide); [mer-V(μ2,6 –OC10H6O)1.5(L)3]

Gross Formula C57H54N3O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_7

26

Data

27

Structure [mer-V(μ2,6 –OC10H6O)1.5(L)3];

L ¼ 5-(3-phenylpropyl)pyridine; N

HOC10H6OH ¼ 2,6-dihydroxynaphthalene

OH

HO

Data T [K] 273-10

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.67

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.86

Method SQUID

Remarks 2D net structure, VO3N3 core is roughly octahedral

28

Magnetic properties of vanadium(III) 2-dimensional network (vanadyl. . .

Additional Remark (i) weak antiferromagnetic interactions indicated

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference J.M. Tanski, P.-T. Wolczanski, Inorg. Chem. 40, 346 (2001)

Magnetic properties of oxovanadium(IV) complex of 2-acetylpyridine semicarbazone

Substance Oxovanadium(IV) complex of 2-acetylpyridine semicarbazone; [VO(HL)(acac)2]

Gross Formula C18H24N4O6V

Properties Molar magnetic moment

Structure [VO(HL)(acac)2];

HL ¼ 2-acetylpyridine semicarbazone;

CH3

N HN H2N

Hacac ¼ acetylacetone O O

N

O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_8

29

30

Magnetic properties of oxovanadium(IV) complex of 2-acetylpyridine semicarbazone

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.87

ΘP [K] –

Method Johnson Matthey

Remarks octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference A.M.B. Bastos, J.G. da Silva, P.I.d.S. Maia, V.M. Deflon, A.A. Batista, A.V.M. Ferreira, L.M. Botion, E. Niquet, H. Beraldo, Polyhedron 27, 1787 (2008)

Magnetic properties of oxovanadium(IV) complex of 3-acetylpyridine semicarbazone

Substance Oxovanadium(IV) complex of 3-acetylpyridine semicarbazone; [VO(HL)(acac)2]

Gross Formula C18H24N4O6V

Properties Molar magnetic moment

Structure [VO(HL)(acac)2];

HL ¼ 3-acetylpyridine semicarbazone; N

O

O

CH3 HN

H2N

Hacac ¼ acetylacetone

N

O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_9

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32

Magnetic properties of oxovanadium(IV) complex of 3-acetylpyridine semicarbazone

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.13

ΘP [K] –

Method Johnson Matthey

Remarks octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference A.M.B. Bastos, J.G. da Silva, P.I.d.S. Maia, V.M. Deflon, A.A. Batista, A.V.M. Ferreira, L.M. Botion, E. Niquet, H. Beraldo, Polyhedron 27, 1787 (2008)

Magnetic properties of oxovanadium(IV) complex of 4-acetylpyridine semicarbazone

Substance Oxovanadium(IV) complex of 4-acetylpyridine semicarbazone; [VO(L)(acac)(H2O)].0.5H2O

Gross Formula C13H19N4O5.5V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_10

33

34

Magnetic properties of oxovanadium(IV) complex of 4-acetylpyridine semicarbazone

Structure [VO(L)(acac)(H2O)].0.5H2O;

HL ¼ 4-acetylpyridine semicarbazone; N CH3 N

HN

H2N O Hacac ¼ acetylacetone O

O

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.89

ΘP [K] –

Method Johnson Matthey

Remarks octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference A.M.B. Bastos, J.G. da Silva, P.I.d.S. Maia, V.M. Deflon, A.A. Batista, A.V.M. Ferreira, L.M. Botion, E. Niquet, H. Beraldo, Polyhedron 27, 1787 (2008)

Magnetic properties of oxovanadium(IV) complex with imidazol-4-carboxylate

Substance Aqua-bis(imidazol-4-carboxylato)oxovanadium(IV); [V(imc)3(H2O)]

Gross Formula C8H8N4O6V

Properties Molar magnetic moment and product of molar magnetic susceptibility with temperature

Structure [V(imc)3(H2O)];

imcNa ¼ sodium imidazol-4-carboxylate NH N NaO

O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_11

35

36

Magnetic properties of oxovanadium(IV) complex with imidazol-4-carboxylate

Data T [K] –

χg [106 emu/g] –

χ MT [cm3 K mol1] 0.139

pm or μeff [μB] 1.13 1.27 (corr.)

ΘP [K] –

Method JohnsonMatthey

Remarks octahedral V(IV) centre

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference C.C. McLauchlan, J.D. Hooker, M.A. Jones, Z. Dymon, E.A. Backhus, B.A. Greiner, N.A. Dorner, M.A. Youkhana, L.M. Manus, J. Inorg. Biochem. 104, 274 (2010)

Magnetic properties of oxovanadium(IV) complex with anthranilate

Substance Oxovanadium(IV) complex with anthranilate; [V(anc)2]1.25H2O

Gross Formula C14H8.5N2O6.25V

Properties Molar magnetic moment and product of molar magnetic susceptibility with temperature

Structure [V(anc)2]1.25H2O;

ancNa ¼ sodium anthranilate NH2 O NaO

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_12

37

38

Magnetic properties of oxovanadium(IV) complex with anthranilate

Data T [K] ––

χg [106 emu/g] –

χ MT [cm3 K mol1] 0.357

pm or μeff [μB] 1.70 1.77 (corr.)

ΘP [K] –

Method JohnsonMatthey

Remarks d1 V(IV) species

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference C.C. McLauchlan, J.D. Hooker, M.A. Jones, Z. Dymon, E.A. Backhus, B.A. Greiner, N.A. Dorner, M.A. Youkhana, L.M. Manus, J. Inorg. Biochem. 104, 274 (2010)

Magnetic properties of oxovanadium(IV) complex with dipyrido[3,2-a:20 ,30 -c] phenazine

Substance Oxovanadium(IV) complex with dipyrido[3,2-a:20 ,30 -c]phenazine; [VO(SO4)(H2O)2(dppz)].2H2O

Gross Formula C18H18N4O9SV

Properties Molar magnetic moment and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_13

39

Magnetic properties of oxovanadium(IV) complex. . .

40

Structure dppz ¼ dipyrido[3,2-a:20 ,30 -c] phenazine

[VO(SO4)(H2O)2(dppz)].2H2O; O O4S H2O N

V OH2 N

.2H2O

N

N

N

N

N

N

Data T [K] 300–4

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.63

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Curie-Weiss law obeyed (300-4 K), with: C ¼ 0.348 cm3 K mol–1 θ ¼ –1.333 K (ii) weak antiferromagnetic interactions indicated

ΘP [K] 1.333

Method Faraday

Remarks octahedral

Reference

41

Symbols and Abbreviations Short form T Faraday θ C χg χM pm μeff ΘP

Full form temperature Faraday method Curie constant Curie temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference J. Benitez, L. Guggeri, I. Tomaz, J.C. Pessoa, V. Moreno, J. Lorenzo, F.X. Aviles, B. Garat, D. Gambino, J. Inorg. Biochem. 103, 1386 (2009)

Magnetic properties of mixed ligand complex of oxovanadium(IV) with N-salicylidene-S-methyldithiocarbazate and 1,10-phenanthroline

Substance 1,10-Phenanthroline(N-salicylidene-S-methyldithiocarbazato)oxovanadium(IV); [VO(L)(phen)]

Gross Formula C21H16N4O2S2V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_14

42

Reference

43

Structure [VO(L)(phen)];

O N

V

N H 3C

N

O

N

H2L ¼ N-salicylidene-S-methyldithiocarbazone OH SH N CH3 N S phen ¼ 1,10-phenanthroline

S S

N

N

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.63

ΘP [K] –

Method Gouy

Remarks octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Gouy

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Gouy method or Pascal method

Reference P.K. Sasmal, A.K. Patra, A.R. Chakravarty, J. Inorg. Biochem. 102, 1463 (2008)

Magnetic properties of mixed ligand complex of oxovanadium(IV) with N-salicylidene-S-methyldithiocarbazate and dipyrido[3,2-d:20 ,30 -f]quinoxaline

Substance [Dipyrido[3,2-d:20 ,30 -f]quinoxaline]-N-salicylidene-S-methyldithiocarbazato) oxovanadium(IV); [VO(L)(dpq)]

Gross Formula C23H16N6O2S2V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_15

44

Data

45

Structure [VO(L)(dqp)]; N O N

O

N

V

N

CH3

dqp ¼ dipyrido[3,2-d:20 ,30 -f]quinoxaline

S

N H3C

N

H2L ¼ N-salicylideneS-methyldithiocarbazone OH SH N N S

S

N

N

N

N

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.65

ΘP [K] –

Method Gouy

Remarks octahedral

46

Magnetic properties of mixed ligand complex of oxovanadium(IV). . .

Symbols and Abbreviations Short form T χg χM pm Gouy μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Gouy method or Pascal method effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference P.K. Sasmal, A.K. Patra, A.R. Chakravarty, J. Inorg. Biochem. 102, 1463 (2008)

Magnetic properties of mixed ligand complex of oxovanadium(IV) with N-salicylidene-S-methyldithiocarbazate and dipyrido[3,2-a:20 ,30 -C]phenazine

Substance [Dipyrido[3,2-a:30 ,20 -C]phenazine]-N-salicylidene-S-methyldithiocarbazato) oxovanadium(IV); [VO(L)(dppz)]

Gross Formula C27H18N6O2S2V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_16

47

Magnetic properties of mixed ligand complex of oxovanadium(IV). . .

48

Structure [VO(L)(dppz)]; N O N N

N

O

N

V

N S

H3C S H2L ¼ N-salicylideneS-methyldithiocarbazone OH SH N N S

dqpz ¼ dipyrido[3,2-a:30 ,20 -C] phenazine

CH3

N

N

N

N

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.60

ΘP [K] –

Method Gouy

Remarks octahedral

Reference

49

Symbols and Abbreviations Short form T χg χM pm μeff Gouy ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Gouy method or Pascal method paramagnetic Curie constant (Weiss constant)

Reference P.K. Sasmal, A.K. Patra, A.R. Chakravarty, J. Inorg. Biochem. 102, 1463 (2008)

Magnetic properties of oxovanadium(IV) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6diazaocatane-1,8-diamine

Substance Oxovanadium(IV) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane1,8-diamine; [VO(H4L)]SO4

Gross Formula C22H26N4O11SV

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_17

50

Data

51

Structure [VO(H4L)]SO4; O

COOH OH C

HOOC HO

V N

NH NH

SO4 N

C H

H

H4L ¼ 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane-1,8-diamine HOOC

COOH HO

OH C

N

NH NH

N

C H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.73

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks presence of one unpaired electron indicated

Magnetic properties of oxovanadium(IV) complex. . .

52

Additional Remark (i) no significant interactions between neighboring V(IV) ions

Symbols and Abbreviations Short form T χg χM pm Gouy μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Gouy method or Pascal method effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Sarkar, K. Dey, Spectrochim. Acta A 77, 740 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 dimethylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -dimethylenebis(3,5-tert-butylsalicylaldimine) ligand; [VO(L)]

Gross Formula C32H48N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_18

53

Magnetic properties of oxovanadium(IV) complex with. . .

54

Structure [VO(L)]; HC

N

O V

O

N

CH

O

H2L ¼ N,N0 -dimethylenebis(3,5-di-tert-butyl-salicylaldimine HC

N OH

N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.74

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

Reference

55

Additional Remark (i) no interaction between the metal centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 isopropylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -isopropylenebis(3,5-di-tert-butyl-salicylaldimine) ligand; [VO(L)]

Gross Formula C34H48N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_19

56

Data

57

Structure [VO(L)]; CH3 HC

O

N

V O

N

CH

O

H2L ¼ N,N0 -isopropylenebis(3,5-di-tert-butyl-salicylaldimine) CH3 HC

N OH

N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.70

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

58

Magnetic properties of oxovanadium(IV) complex with. . .

Additional Remark (i) no interaction between the metal centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 trimethylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -trimethylenebis(3,5-di-tert-butylsalicylaldimine) ligand; [VO(L)]

Gross Formula C33H48N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_20

59

Magnetic properties of oxovanadium(IV) complex with. . .

60

Structure [VO(L)]; HC

N

O

N

CH

V O

O

H2L ¼ N,N0 -trimethylenebis(3,5-di-tert-butylsalicylaldimine) HC

N OH

N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.67

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

Reference

61

Additional Remark (i) no interaction between the metal centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -tetramethylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -tetramethylenebis(3,5-di-tertbutylsalicylaldimine) ligand; [VO(L)]

Gross Formula C34H50N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_21

62

Data

63

Structure [VO(L)]; HC

O

N

V O

N

CH

O

H2L ¼ N,N0 -tetramethylenebis(3,5-di-tert-butylsalicylaldimine) HC

N OH

N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.68

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

64

Magnetic properties of oxovanadium(IV) complex with. . .

Additional Remark (i) no interaction between the metal centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -pentamethylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -pentamethylenebis(3,5-di-tert-butylsalicylaldimine) ligand; [VO(L)]

Gross Formula C35H52N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_22

65

Magnetic properties of oxovanadium(IV) complex with. . .

66

Structure [VO(L)]; (CH2)5 HC

N

O

N

CH

V O

O

H2L ¼ N,N0 -pentamethylenebis(3,5-di-tert-butylsalicylaldimine) (CH2)5 HC

N OH

N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.71

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

Reference

67

Additional Remark (i) no interaction between the metal centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 -hexamethylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -hexamethylenebis(3,5-di-tert-butylsalicylaldimine) ligand; [VO(L)]

Gross Formula C36H54N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_23

68

Data

69

Structure [VO(L)]; (CH2)6 HC

N

O

N

CH

V O

O

H2L ¼ N,N0 -hexamethylenebis(3,5-di-tert-butylsalicylaldimine) (CH2)6 HC

N OH

N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.73

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

70

Magnetic properties of oxovanadium(IV) complex with. . .

Additional Remark (i) no interaction between the metal centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of oxovanadium(IV) complex with bulky N,N0 isopentylenebis(3,5-tBu2salicylaldimine) ligand

Substance Oxovanadium(IV) complex with N,N0 -isopentylenebis(3,5-di-tert-butylsalicylaldimine) ligand; [VO(L)]

Gross Formula C35H52N2O3V

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_24

71

Magnetic properties of oxovanadium(IV) complex with. . .

72

Structure [VO(L)]; CH3

H3C HC

N

O V

O

N

CH

O

H2L ¼ N,N0 -isopentylenebis(3,5-di-tert-butylsalicylaldimine) H3C HC

N OH

CH3 N

CH

HO

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.85

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks magnetically dilute mononuclear complex

Reference

73

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Kasumov, F. Koksal, M. Aslanoglu, Y. Yerli, Spectrochim. Acta A 77, 630 (2010)

Magnetic properties of dinuclear oxovanadium(IV) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine

Substance Dinuclear oxovanadium(IV) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine; [(VO)2(L)]SO4

Gross Formula C18H30N8O8SV2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_25

74

Data

75

Structure [(VO)2(L)]SO4; CH3

CH3 N

N

O

O HN

V

O

O

SO4

NH

V N H2

N H2

H2L ¼ Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine CH3 CH3 N

N HN

OH

OH

NH N H2

N H2

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.17/mol 1.41/V

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks square-pyramidal

76

Magnetic properties of dinuclear oxovanadium(IV) complex with Schiff-base. . .

Symbols and Abbreviations Short form T χg χM pm μeff Gouy ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Gouy method or Pascal method paramagnetic Curie constant (Weiss constant)

Reference A.A.A. Emara, Spectrochim. Acta A 77, 117 (2010)

Magnetic properties of hetero-trimetallic, VO2Mn complex with macrocyclic oxamido vanadium(IV)-oxo ligand

Substance Hetero-trimetallic, VO2Mn complex with macrocyclic oxamido vanadium(IV)oxo ligand; [Mn(VOL)2(CH3OH)2](ClO4)2.5CH3OH

Gross Formula C67H72Cl2MnN8O21V2

Properties Molar magnetic moment, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_26

77

Magnetic properties of hetero-trimetallic, VO2Mn complex with macrocyclic. . .

78

Structure [Mn(VOL)2(CH3OH)2](ClO4)2.5CH3OH;

H2L ¼ 2,3-dioxo-5,6:13,14-dibenzo-7,12-diphenyl-1,4,8,11tetra-azacyclotetradeca-7,12-diene O O

NH N

HN N

Data T [K] 300 2.0

χg [106 emu/g] –

χM pm or μeff [106 emu/mol] [μB] – 6.03 5.37

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.03

Method SQUID

Remarks trinuclear, V-1 and V-1A adopt a square-pyramidal geometry and Mn(II) is in a distorted octahedral coordination sphere

Symbols and Abbreviations

79

Additional Remarks (i) plots of χ M versus T and μeff versus T are shown in Fig. 1 (ii) weak antiferromagnetic interactions indicated (iii) fitting of χ M data leds to: J ¼ 0.27 cm1 θ ¼ 0.03 K g ¼ 1.97

Fig. 1 [Mn(VOL)2(CH3OH)2](ClO4)2.5CH3OH. Temperature dependence of χ M (○) and μeff (Δ). The solid line shows the fitting values

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g θ

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie constant

80

Magnetic properties of hetero-trimetallic, VO2Mn complex with macrocyclic. . .

Reference Y.-H. Zhang, M. Yu, Q.-L. Wang, G.-F. Xu, M. Hu, G.-M. Yang, D.-Z. Liao, Polyhedron 27, 3371 (2008)

Magnetic properties of hetero-trimetallic, VO2Cu complex with macrocyclic oxamido vanadium(IV)-oxo ligand

Substance Hetero-trimetallic, VO2Cu complex with macrocyclic oxamido vanadium(IV)oxo ligand; [Cu(VOL)2(H2O)2](ClO4)2.1.5H2O

Gross Formula C60H51Cl2CuN8O17.5V2

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_27

81

Magnetic properties of hetero-rimetallic, VO2Cu complex with macrocyclic. . .

82

Structure [Cu(VOL)2(H2O)2](ClO4)2.1.5H2O;

H2L ¼ 2,3-dioxo-5,6:13,14-dibenzo-7,12-diphenyl-1,4,8,11tetra-azacyclotetradeca-7,12-diene O O

NH N

HN N

Data T [K] RT

χg [106 emu/g] –

χM pm or μeff [106 emu/mol] [μB] – 3.11

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks trinuclear, V-1 and V-1A adopt a squarepyramidal geometry and Cu(II) is in a distorted octahedral coordination sphere

Additional Remarks

83

Additional Remarks (i) plots of χ M versus T and μeff versus T are shown in Fig. 1 (ii) magnetic behavior indicated ferromagnetic coupling between paramagnetic metals (iii) least-squares fitting of experimental data led to: J ¼ 9.09 cm1 zJ 0 ¼ 5.0  103 cm1 (interdimer exchange interaction parameter) g ¼ 2.00

Fig. 1 [Cu(VOL)2(H2O)2](ClO4)2.1.5H2O. Temperature dependence of χ M (○) and μeff (Δ). The solid line shows the fitting values

84

Magnetic properties of hetero-rimetallic, VO2Cu complex with macrocyclic. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ 0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

Reference Y.-H. Zhang, M. Yu, Q.-L. Wang, G.-F. Xu, M. Hu, G.-M. Yang, D.-Z. Liao, Polyhedron 27, 3371 (2008)

Part II Cr

Magnetic properties of chromium(III) chloro complex with 40 -(2-pyridyl)2,20 -60 ,200 -terpyridine

Substance Trichloro[40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine]chromium(III) mono(dimethylformamidate); [Cr(L)Cl3].dmf

Gross Formula C23H21Cl3CrN5O

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_28

87

88

Magnetic properties of chromium(III) chloro complex. . .

Structure L ¼ 40 -(2-pyridyl)-2,20 -60 ,200 terpyridine;

[Cr(L)Cl3].dmf;

N

N N

N

dmf ¼ dimethylformamide H3C O N

H3C

C

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.90

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method VSM

Remarks distorted octahedral geometry

Reference

89

Symbols and Abbreviations Short form T χg χM pm μeff VSM ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment vibrating-sample magnetometer paramagnetic Curie constant (Weiss constant)

Reference S.K. Padhi, D. Saha, R. Sahu, J. Subramanian, V. Manivannan, Polyhedron 27, 1714 (2008)

Magnetic properties of chromium(III) azido complex with 40 -(2-pyridyl)-2,20 -60 ,200 terpyridine

Substance Triazido[40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine]chromium(III) monoacetonitrilate; [Cr(L)(N3)3].CH3CN

Gross Formula C22H17CrN14

Properties Molar magnetic moment

Structure [Cr(L)(N3)3].CH3CN;

L ¼ 40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine N

N N

N

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_29

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Reference

91

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.72

ΘP [K] –

Method VSM

Remarks distorted octahedral geometry

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff VSM ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment vibrating-sample magnetometer paramagnetic Curie constant (Weiss constant)

Reference S.K. Padhi, D. Saha, R. Sahu, J. Subramanian, V. Manivannan, Polyhedron 27, 1714 (2008)

Magnetic properties of chromium(III) thiocyanato complex with 40 -(2-pyridyl)2,20 -60 ,200 -terpyridine

Substance [40 -(2-Pyridyl)-2,20 -60 ,200 -terpyridine]trithiocyanatochromium(III) mono(dimethylformamidate); [Cr(L)(NCS3)].dmf

Gross Formula C26H21CrN8OS3

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_30

92

Data

93

Structure [Cr(L)(NCS3)].dmf;

L ¼ 40 -(2-pyridyl)-2,20 -60 ,200 -terpyridine; N

N N N dmf ¼ dimethylformamide H3C O

N

C

H3C

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.73

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method VSM

Remarks distorted octahedral geometry

94

Magnetic properties of chromium(III) thiocyanato complex. . .

Symbols and Abbreviations Short form T χg χM pm μeff VSM ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment vibrating-sample magnetometer paramagnetic Curie constant (Weiss constant)

Reference S.K. Padhi, D. Saha, R. Sahu, J. Subramanian, V. Manivannan, Polyhedron 27, 1714 (2008)

Magnetic properties of chromium(III) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane1,8-diamine as acetate salt

Substance Chromium(III) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane1,8-diamine as acetate salt; [Cr(H2L)]OAc.2H2O

Gross Formula C24H31CrN4O10

Properties Molar magnetic moment

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96

Magnetic properties of chromium(III) complex. . .

Structure [Cr(H2L)]OAc.2H2O; H C N HOOC

NH

O Cr O

HOOC

OAc.2H2O NH

N C H

H4L ¼ 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane-1,8-diamine HOOC

COOH HO

OH C

N

NH NH

N

C H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.82

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks pseudo-octahedral

Reference

97

Symbols and Abbreviations Short form T χg χM pm μeff Gouy ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Gouy method or Pascal method paramagnetic Curie constant (Weiss constant)

Reference S. Sarkar, K. Dey, Spectrochim. Acta A 77, 740 (2010)

Magnetic properties of chromium(III) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane1,8-diamine as chloride salt

Substance Chromium(III) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane1,8-diamine as chloride salt; [Cr(H2L)]Cl.2H2O

Gross Formula C22H28ClCrN4O8

Properties Molar magnetic moment

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Data

99

Structure [Cr(H2L)]Cl.2H2O; H C N HOOC

NH

O Cr O

HOOC

Cl.2H2O NH

N C H

H4L ¼ 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane-1,8-diamine HOOC

COOH HO

OH C

N

NH NH

N

C H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.88

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks pseudo-octahedral

100

Magnetic properties of chromium(III) complex. . .

Symbols and Abbreviations Short form T χg χM pm μeff Gouy ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Gouy method or Pascal method paramagnetic Curie constant (Weiss constant)

Reference S. Sarkar, K. Dey, Spectrochim. Acta A 77, 740 (2010)

Magnetic properties of chromium(III) complex with oxalohydrazide

Substance Chromium(III) complex with oxalohydrazide; [Cr(L)(H2O)3Cl].H2O

Gross Formula C2H12ClCrN4O6

Properties Molar magnetic moment

Structure [Cr(L)(H2O)3Cl].H2O;

H2L ¼ oxalohydrazide O H2N

N

H

H

O N

NH2

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102

Magnetic properties of chromium(III) complex with oxalohydrazide

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 4.9

ΘP [K] –

Method Johnson Matthey

Remarks octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference A.A. Et-Asmy, O.A. El-Gammal, H.A. Radwan, Spectrochim. Acta A 76, 496 (2010)

Magnetic properties of dinuclear chromium(III) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine

Substance Dinuclear chromium(III) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine; [Cr2(L)(NO3)4].3H2O

Gross Formula C18H36Cr2N10O17

Properties Molar magnetic moment

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Magnetic properties of dinuclear chromium(III) complex with Schiff-base. . .

104

Structure [Cr2(L)(NO3)4].3H2O; CH3

CH3 N

N HN Cr N H2

O

O ONO2

O2NO

NH Cr N H2

O2NO

ONO2

.3H2O

H2L ¼ Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine CH3 CH3 N

N HN

OH

NH

OH

N H2

N H2

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.47/mol 3.87/Cr

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks octahedral

Reference

105

Symbols and Abbreviations Short form T χg χM pm μeff Gouy ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Gouy method or Pascal method paramagnetic Curie constant (Weiss constant)

Reference A.A.A. Emara, Spectrochim. Acta A 77, 117 (2010)

Magnetic properties of heterometallic ion-pair complex having copper(II) Schiff-base cation and diaminotetrathiocyanatochromate(III) anion

Substance [N-(2-{[(1E)-3-amino-1,3-dimethylbutylidene]amino}ethyl)-N-(2-aminoethyl)ethane-1,2-diamine]copper(II) diaminotetrathiocyanatochromate(III) thiocyanate hexadimethylformamidate; [Cu(trenac)][Cr(NCS)4(NH3]2]NCS.6dmso

Gross Formula C29H70CrCuN12O6S11

Properties Molar magnetic moment and Weiss constant

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Data

107

Structure [Cu(trenac)][Cr(NCS)4(NH3]2]NCS.6dmso;

trenac ¼ open chain Schiff-base ligand N-(2-{[(1E)3-amino1,3- dimethylbutylidene] amino}ethyl)N-(2-aminoethyl)ethane1,2-diamine

N

NH2 NH2

N

NH2 dmso ¼ dimethylsulphoxide O H3C

S

CH3

Data T [K] RT 2.0

χg [106 emu/g] –

χM pm or μeff [106 emu/mol] [μB] – 4.37 3.89

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.41

Method SQUID

Remarks square-pyramidal geometry around Cu(II) while Cr(III) has octahedral geometry

108

Magnetic properties of heterometallic ion-pair complex having copper(II). . .

Additional Remarks (i) decrease of μeff with temperature may be due to zero-field splitting effect of Cr(III) ions and/or weak antiferromagnetic interactions between paramagnetic centres (ii) Curie-Weiss law obeyed, with: C ¼ 2.41 cm3 K mol1 θ ¼ 0.41 K

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Curie constant Curie temperature

Reference V.M. Nikitina, O.V. Nesterova, V.N. Kokozay, V.V. Dyakonenko, O.V. Shishkin, J. Jezierska, Inorg. Chem. Commun. 12, 101 (2009)

Magnetic properties of heterometallic Cu(II)/Cr(III) complex with an open-chain Schiff-base ligand

Substance Heterometallic Cu(II)-Cr(III) complex with 4,6,6-trimethyl-3,7-diazanon-3-ene-1,9diamine; {[Cu(enac)]2Cr(NCS)4(NH3)2}[Cr(NCS)4(NH3)2]3.4CH3COCH3

Gross Formula C48H96Cr4Cu2N32O4S16

Properties Molar magnetic moment, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_36

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110

Magnetic properties of heterometallic Cu(II)/Cr(III) complex with an open-chain. . .

Structure {[Cu(enac)]2Cr(NCS)4(NH3)2}[Cr(NCS)4(NH3)2]3.4CH3COCH3;

enac ¼ 4,6,6-trimethyl-3,7-diazanon-3-ene-1,9-diamine

N

HN

NH2 H2N

Data T [K] RT

χM pm or μeff ΘP χg [106 emu/g] [106 emu/mol] [μB] [K] Method – – 8.02 2.03 SQUID

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Remarks supramolecular assembly

Additional Remarks

111

Additional Remarks (i) temperature dependence of μeff and χ M–1 is shown in Fig. 1 (ii) Curie-Weiss law observed, with: C ¼ 8.10 cm3 K mol–1 θ ¼ 2.03 K (iii) weak antiferromagnetic interactions suggested, with: J ¼ 0.9 cm–1 θ ¼ 2.9 K gCr ¼ 1.94

Fig. 1 {[Cu(enac)]2Cr(NCS)4(NH3)2}[Cr(NCS)4(NH3)2]3.4CH3COCH3. Temperature dependence of μeff and χ M–1 (inset). The solid line shows the Currie-Weiss fit

112

Magnetic properties of heterometallic Cu(II)/Cr(III) complex with an open-chain. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID χ M1 g θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device inverse molar susceptibility Lande factor Curie constant Curie temperature

Reference V.M. Nikitina, O.V. Nesterova, V.N. Kokozay, E.A. Goreshnik, J. Jezierska, Polyhedron 27, 2426 (2008)

Part III Mo

Magnetic properties of three-dimensional cyano-bridged heterobimetallic Ni(II)-Mo(IV) complex with macrocyclic ligand

Substance Cyano-bridged heterobimetallic Ni(II)-Mo(IV) complex with macrocyclic ligand; {[Ni(L)]2[Mo(CN)8]}.12H2O

Gross Formula C40H88MoN16Ni2O12

Properties Molar magnetic moment, product of molar magnetic susceptibility with temperature and Weiss constant

Structure {[Ni(L)]2[Mo(CN)8]}.12H2O;

L ¼ macrocyclic ligand 5,7,7,12,14,14hexamethyl-1,4,8,11tetra-azacyclotetradecane Me Me Me NH HN Me Me

NH

HN Me

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Magnetic properties of three-dimensional cyano-bridged. . .

116

Data T [K] RT 6.0 1.8

χg [106 emu/g] –

χ MT [cm3 K mol1] 2.46 2.10 1.55

pm or μeff [μB] 4.4 4.1 3.5

ΘP [K] Method 3.2 –

Remarks cyano-bridged bimetallic assembly, elongated octahedral geometry around Ni(II) while Mn(II) centre adopts a distorted squareantiprismatic geometry

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) plot of χ MT and χ M1 is shown in Fig. 1 (ii) weak antiferromagnetic indicated with: θ ¼ 3.2 K

Fig. 1 {[Ni(L)]2[Mo(CN)18]}.12H2O. Temperature dependence of χ MT and χ M1

Reference

117

Symbols and Abbreviations Short form T χg χM pm μeff ΘP χ M1 θ

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) inverse molar susceptibility Curie constant

Reference H. Zhou, Y.-Y. Chen, A.-H. Yuan, X.-P. Shen, Inorg. Chem. Commun. 11, 363 (2008)

Magnetic properties of bimetallic oxide of Cu-Mo6 constructed from molybdenum oxo cluster having bis-N,N(methylphosphonic acid)amine

Substance Bimetallic oxide of Cu-Mo6 constructed from molybdenum oxo cluster having bis-N,N(methylphosphonic acid)amine; {[Cu(terpy)]2[Mo6O17(H2O)(L)2]}.H2O

Gross Formula C34H45Cu2Mo6N8O35P4

Properties Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_38

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Data

119

Structure {[Cu(terpy)]2[Mo6O17(H2O)(L)2]}.H2O;

terpy ¼ 2,20 :60 ,200 -terpydine;

N N

N

H4L ¼ bis[N,N(methylphosphonic acid) amine] OH OH O O P P N HO OH H

Data T [K] 300–2

χM pm or μeff ΘP χg [106 emu/g] [106 emu/mol] [μB] [K] Method – – – 0.35 –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Remarks 3D structure is constructed from [Mo6O17(H2O)(L)2]-4 clusters linked through [Cu(terpy)]+2 subunits

120

Magnetic properties of bimetallic oxide of Cu-Mo6 constructed from. . .

Additional Remarks (i) temperature dependence of χ M and μeff is shown in Fig. 1 (ii) Curie-Weiss law obeyed, with: θ ¼ 0.35 K g ¼ 2.07

Fig. 1 {[Cu(terpy)]2[Mo6O17(H2O)(L)2]}.H2O. Temperature dependence of χ M and μeff. The line through the susceptibility data points is the best-fit values

Symbols and Abbreviations Short form T χg χM pm μeff ΘP g θ

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Lande factor Curie constant

Reference Y.-H.J. Chaung, H. Liu, C.J. O’Conner, J. Zubieta, Inorg. Chem. Commun. 11, 1205 (2008)

Part IV Mn

Magnetic properties of manganese(II) complex with sulpiride drug

Substance Manganese(II) complex with sulpiride drug; [MnCl2(spr)2(H2O)2].2H2O

Gross Formula C30H52Cl2MnN6O12S2

Properties Molar magnetic moment

Structure [MnCl2(spr)2(H2O)2].2H2O;

spr ¼ sulpiride O

O

Cl

OH2

Mn H2O

Cl

O

H 2N .2H2O

S

O

O

C2H5 N H

OCH3

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124

Magnetic properties of manganese(II) complex with sulpiride drug

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.25

ΘP [K] –

Method Faraday

Remarks distorted octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Faraday

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Faraday method

Reference G.G. Mohamed, M.H. Soliman, Spectrochim. Acta A 76, 341 (2010)

Magnetic properties of manganese(II) complex with 6-acetyl-1,3,7trimethyllumazine

Substance Diacetato(6-acetyl-1,3,7-trimethylumazine)manganese(II) dihydrate; [Mn(OAc)2(L)].2H2O

Gross Formula C22H28MnN6O9

Properties Molar magnetic moment and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_40

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126

Magnetic properties of manganese(II) complex with 6-acetyl. . .

Structure L ¼ benzoylhydrazone of 6-acetyl1,3,7-trimethyllumazine

[Mn(OAc)2(L)].2H2O;

O N

O H3C

N

N

O

N

N

N

H

CH3 CH3

CH3

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 6.06

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) Curie-Weiss law obeyed, with: C ¼ 6.419 cm3 K mol–1 θ ¼ 10 K

ΘP [K] 10

Method SQUID

Remarks octahedral

Reference

127

Symbols and Abbreviations Short form T χg SQUID θ C χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) superconducting quantum interference device Curie constant Curie temperature magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S.B. Jimenez-Pulido, F.M. Linares-Ordonez, J.M. Martinez-Martos, M.N. Moreno-Carretero, M. Quiros-Olozabal, M.J. Ramirez-Exposito, J. Inorg. Biochem. 102, 1677 (2008)

Magnetic properties of imidazole complex of manganese(II) benzenesulfonate

Substance Triaquatriimidazolemanganese(II) dibenzenesulfonate; [Mn(imH)3(H2O)3](bs)2

Gross Formula C21H28MnN6O9S2

Properties Molar magnetic moment

Structure [Mn(imH)3(H2O)3](bs)2;

imH ¼ imidazole;

N

bs ¼ benzenesulfonate O S

N H

O

O

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Reference

129

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.92

ΘP [K] –

Method Gouy

Remarks high-spin, octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Gouy

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Gouy method or Pascal method

Reference T.Y. Yazicular, E.Y. Gurkan, I. Ucar, C. Kazak, Trans. Met. Chem. 34, 669 (2009)

Magnetic properties of manganese(II) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl-4H-[1,3,4] thiadiazolo[2,3-c][1,2,4]triazin-4-one

Substance Manganese(II) complex with triazine ligand derived from 3-benzyl-7-hydrazinyl4H-[1,3,4]thiadiazolo[2,3-c]- [1,2,4]triazin-4-one; [Mn(HL)2]Cl2

Gross Formula C22H20Cl2MnN12O2S2

Properties Molar magnetic moment

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Data

131

Structure [Mn(HL)2]Cl2;

H

N

H

N

N

HN

O

N

S .Cl2

N

Mn

N

S

N

NH

O

N

N

N

H

H

HL ¼ triazine ligand derived from 3-benzyl-7-hydrazinyl4H-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one H2 N N C O

S

N N

NH NH2

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.62

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Faraday

Remarks octahedral geometry

132

Magnetic properties of manganese(II) complex with triazine ligand. . .

Symbols and Abbreviations Short form T χg χM Faraday pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) Faraday method effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference G.G. Mohamed, M.A. Badaway, M.M. Omar, M.M. Nassar, A.B. Kamel, Spectrochim. Acta A 77, 773 (2010)

Magnetic properties of manganese(II) complex with pyrimidine derived Schiff-base

Substance Bis[S-methyl-3-{2-S-methyl-6-methyl-4-pyrimidyl)methyl}dithiocarbazate] manganese(II); [Mn(L)2]

Gross Formula C18H22MnN6S6

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_43

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134

Magnetic properties of manganese(II) complex with pyrimidine derived Schiff-base

Structure [Mn(L)2]; HL ¼ S-methyl-3-{2-S-methyl-6-methyl-4-pyrimidyl)methyl}dithiocarbazate H H S N S N N CH3

S

N CH3

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.82

ΘP [K] –

Method VSM

Remarks distorted octahedral arrangement

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm VSM μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule vibrating-sample magnetometer effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Roy, T.N. Mandal, A.K. Barik, S. Gupta, R.J. Butcher, M. Nethaji, S.K. Kar, Polyhedron 27, 593 (2008)

Magnetic properties of manganese(II) complex with pyrimidine derived Schiff-base

Substance Bis[S-benzyl-3-{(2-S-methyl-6-methyl-4-pyrimidyl)methyl}dithiocarbazate]manganese(II); [Mn(L)2]

Gross Formula C30H30MnN8S6

Properties Molar magnetic moment

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136

Magnetic properties of manganese(II) complex with pyrimidine derived Schiff-base

Structure [Mn(L)2]; HL ¼ S-benzyl-3-{(2-S-methyl-6-methyl-4-pyrimidyl)methyl}dithiocarbazate H H S N N N S CH3 S

N CH2

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.85

ΘP [K] –

Method VSM

Remarks distorted octahedral arrangement

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm VSM μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule vibrating-sample magnetometer effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Roy, T.N. Mandal, A.K. Barik, S. Gupta, R.J. Butcher, M. Nethaji, S.K. Kar, Polyhedron 27, 593 (2008)

Magnetic properties of manganese(II) complex with 17-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety

Substance Manganese(II) complex with macrocyclic Schiff-base ligand obtained from 2,6-diacetylpyridine and 1,4-bis(3-aminopropyl)piperazine; [Mn(L)Cl]ClO4.2H2O

Gross Formula C19H33Cl2MnN5O6

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_45

137

Magnetic properties of manganese(II) complex with 17-membered. . .

138

Structure [Mn(L)Cl]ClO4.2H2O; H3C N

N Mn

N

Cl

N

ClO4.2H2O N

H3 C

L ¼ Schiff-base ligand obtained from 2,6-diacetylpyridine and 1,4-bis(3-aminopropyl)piperazine H3C N

N

N

N

N

H3C

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.54

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Johnson Matthey

Remarks high-spin Mn(II)

Reference

139

Symbols and Abbreviations Short form T χg χM pm Johnson Matthey μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Johnson Matthey balance effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference H. Keypour, M. Rezaeivala, L. Valencia, P. Perez-Lourido, Polyhedron 27, 3172 (2008)

Magnetic properties of manganese(II) complex with 16-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety

Substance Manganese(II) complex with macrocyclic Schiff-base ligand obtained from 2,6-pyridinecarbaldehyde and N,N(2-aminoethyl)(3-aminopropyl)piperazine; [Mn(L)Cl(CH3OH)]ClO4

Gross Formula C16H25Cl2MnN5O5

Properties Molar magnetic moment

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140

Symbols and Abbreviations

141

Structure L ¼ Schiff-base ligand obtained from 2,6-pyridinecarbaldehyde and N,N(2-aminoethyl) (3-aminopropyl)piperazine

[Mn(L)Cl(CH3OH)]ClO4; H N

N Mn

N N

Cl

H

ClO4 N

N

N

N

N

N

H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.44

ΘP [K] –

Method Johnson Matthey

Remarks high-spin Mn(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm Johnson Matthey μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Johnson Matthey balance effective magnetic moment paramagnetic Curie constant (Weiss constant)

142

Magnetic properties of manganese(II) complex with 16-membered. . .

Reference H. Keypour, M. Rezaeivala, L. Valencia, P. Perez-Lourido, Polyhedron 27, 3172 (2008)

Magnetic properties of manganese(II) complex with 16-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety

Substance Manganese(II) complex with macrocyclic Schiff-base ligand obtained from 2,6-diacetylpyridine and N,N(2-aminoethyl)(3-aminopropyl)piperazine; [Mn(L)Cl(CH3OH)]ClO4

Gross Formula C18H29Cl2MnN5O5

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_47

143

Magnetic properties of manganese(II) complex with 16-membered. . .

144

Structure [Mn(L)Cl(CH3OH)]ClO4; CH3 N

N Mn

N

Cl

N

ClO4 N

CH3

L ¼ Schiff-base ligand obtained from 2,6-diacetylpyridine and N,N(2-aminoethyl) (3-aminopropyl)piperazine CH3 N

N

N

N

N

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.33

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Johnson Matthey

Remarks high-spin Mn(II)

Reference

145

Symbols and Abbreviations Short form T χg χM pm Johnson Matthey μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Johnson Matthey balance effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference H. Keypour, M. Rezaeivala, L. Valencia, P. Perez-Lourido, Polyhedron 27, 3172 (2008)

Magnetic properties of manganese(II) complex with 17-membered pentaaza macrocyclic Schiff-base ligand containing piperazine moiety

Substance Manganese(II) complex with macrocyclic Schiff-base ligand obtained from 2,6-pyridine carbaldehyde with 1,4-bis(3-aminopropyl)piperazine; [Mn(L)Cl]ClO4

Gross Formula C17H25Cl2MnN5O4

Properties Molar magnetic moment

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Reference

147

Structure L ¼ Schiff-base ligand obtained from 2,6-pyridine carbaldehyde with 1,4-bis(3-aminopropyl)piperazine

[Mn(L)Cl]ClO4; H N

N

H

Mn

N N

Cl

ClO4

N

N

N

N

N

N

H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.59

ΘP [K] –

Method Johnson Matthey

Remarks high-spin Mn(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm Johnson Matthey μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Johnson Matthey balance effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference H. Keypour, M. Rezaeivala, L. Valencia, P. Perez-Lourido, Polyhedron 27, 3172 (2008)

Magnetic properties of mixed ligand manganese(II) complex with N0 -(pyridine3-carboxyl)-hydrazinecarbodithioic acid ethyl ester and 1,10-phenanthroline

Substance Manganese(II) complex with N0 -(pyridine-3-carboxyl)-hydrazinecarbodithioic acid ethyl ester and 1,10-phenanthroline; [Mn(HL)2(phen)]

Gross Formula C30H28MnN8O2S4

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_49

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Data

149

Structure [Mn(HL)2(phen)];

H2L ¼ N0 -(pyridine-3-carboxyl)hydrazinecarbodithioic acid ethyl ester O H N SCH2CH3 N H S N

phen ¼ 1,10-phenanthroline

N

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 6.10

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Faraday

Remarks high-spin Mn(II) centre possessing distorted octahedral geometry

150

Magnetic properties of mixed ligand manganese(II) complex with N0 -(pyridine. . .

Symbols and Abbreviations Short form T χg χM Faraday pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) Faraday method effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference M. Singh, R.J. Butcher, N.K. Singh, Polyhedron 27, 3451 (2008)

Magnetic properties of manganese(II) complex with hexadentate Schiff-base ligand

Substance Manganese(II) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane1,8-diamine; [Mn(H2L)]

Gross Formula C22H24MnN4O6

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_50

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152

Magnetic properties of manganese(II) complex with hexadentate Schiff-base ligand

Structure [Mn(H2L)]; H4L ¼ 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine HOOC COOH HO OH C

N

NH NH

N

C H

H

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.81

ΘP [K] –

Method Gouy

Remarks a) 1D zig-zag chains are linked together to generate a supramolecular sheet b) octahedral coordination around Mn(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T Gouy χg χM pm μeff ΘP

Full form temperature Gouy method or Pascal method magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Sarkar, S. Biswas, M.-S. Liao, T. Kar, Y. Aydogdu, F. Dagdelen, G. Mostafa, A.P. Chattopadhyay, G.P.A. Yap, R.-H. Xie, A.T. Khan, Polyhedron 27, 3359 (2008)

Magnetic properties of manganese(II) complex with mesogenic Schiff-base

Substance Manganese(II) complex with N,N0 -di-4-(40 -pentyloxybenzoate)salicylidene diaminoethane; [Mn(L)]

Gross Formula C40H42MnN2O8

Properties Molar magnetic moment

Structure [Mn(L)];

H2L ¼ mesogenic schiff-base N,N0 -di-4-(40 -pentyloxybenzoate) salicylidene diaminoethane O O

O

OH N H

H N HO

O

O

O

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154

Magnetic properties of manganese(II) complex with mesogenic Schiff-base

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.85

ΘP [K] –

Method Faraday

Remarks octahedral

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Faraday

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Faraday method

Reference A.K. Singh, S. Kumari, T.N.G. Row, J. Prakash, K.R. Kumar, B. Sridhar, T.R. Rao, Polyhedron 27, 3710 (2008)

Magnetic properties of aqua-bridged binuclear manganese(II)

Substance catena-poly-{μ-Aqua-tetrakis[(4-carboxymethoxy-2,3-bis-4-methylphenylsulfanylnaphthalene-1-yloxyacetato]dimanganese(II)}; [Mn2(μ-H2O)(py)4(L)4]n

Gross Formula C76H66Mn2N4O13S4

Properties Molar magnetic moment and Weiss constant

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156

Magnetic properties of aqua-bridged binuclear manganese(II)

Structure [Mn2(μ-H2O)(py)4(L)4]n; CH3

H3C

H 3C

N

S

O

O O

O O

N

O

S O

O

Mn

O

O OH2 O Mn N

O O

O

N O S

O

S

O

CH3

O

O S

S

CH3

CH3

O O

n

O O

O S

S

CH3

CH3

Na2L ¼ disodium salt of 4-carboxymethoxy-2,3-bis4-methylphenyl; sulfanyl-naphthalene1-yloxyaceticacid -

N

O Na+

O O

S

CH3

S

CH3

O O

-

O Na+

py ¼ pyridine

Reference

157

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.42

ΘP [K] 68.75

Method –

Remarks 1D coordination polymer

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) the compound shows antiferromagnetic behavior (ii) plot of χ MT versus T shows maxima phase transition, with: TN ¼ 150 K (Neel temperature) C ¼ 1.25 cm3 K mol1 θ ¼ 68.75 K

Symbols and Abbreviations Short form T χg χM pm μeff ΘP TN θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Neel temperature Curie constant Curie temperature

Reference W.M. Singh, A. Karmakar, J.B. Baruah, Inorg. Chem. Commun. 11, 576 (2008)

Magnetic properties of dinuclear manganese(II) complex with thiophenedicarboxylate

Substance Dinuclear manganese(II) complex with thiophenedicarboxylate; [Mn2(tdc)2(dmf)2]n

Gross Formula C18H18Mn2N2O10S2

Properties Molar magnetic moment

Structure [Mn2(tdc)2(dmf)2]n;

H2tdc ¼ 2,5-thiophenedicarboxylic acid; OH

HO S O O dmf ¼ N,N-dimethylformamide H3C O N

H3C

C

H

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Reference

159

Data T [K] 300 2.0

χg [106 emu/g] –

χM pm or μeff [106 emu/mol] [μB] – 8.33 0.75

ΘP [K] –

Method SQUID

Remarks dinuclear units link to 3D supramolecular structure

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) antiferromagnetic interactions between Mn(II) ions indicated

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference H.-B. Yuan, S.-Y. Yang, Z.-X. Xie, R.-B. Huang, S.R. Batten, Inorg. Chem. Commun. 12, 755 (2009)

Magnetic properties of bis-m-h0 carboxylate-bridged dinuclear manganese(II) complex containing a tetradentate tripodal ligand

Substance Bis-μ-carboxylate bridged dinuclear manganese(II) complex with N-(benzimidazol2-ylmethyl)iminodiacetic acid; [Mn2(HL)2(H2O)2]

Gross Formula C24H26Mn2N6O10

Properties Molar magnetic moment and exchange energy

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160

Data

161

Structure [Mn2(HL)2(H2O)2]; H3L ¼ N-benzimidazol-2-yl-methyl)iminodiacetic acid H O N OH N N

O HO

Data T [K] 300 30 2.0

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 8.16 7.88 4.57

ΘP [K] –

Method SQUID

Remarks dinuclear

162

Magnetic properties of bis-m-Z0 -carboxylate-bridged dinuclear manganese(II). . .

Additional Remarks (i) temperature dependence of μeff and χ M–1 is shown in Fig. 1 (ii) magnetic behavior indicated weakly antiferromagnetic coupling (iii) good fit parameters being: J ¼ –0.471 cm–1 g ¼ 1.940 O

H HO HN

N

O

O

Mn

Mn

O O

N

N

O

O

N

NH

OH O

H

Fig. 1 [Mn2(HL)2(H2O)2]. Temperature dependence of μeff and χ M–1

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID χ M1 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device inverse molar susceptibility Lande factor

Reference D. Moon, J. Kim, M. Oh, B.J. Suh, M.S. Lah, Polyhedron 27, 447 (2008)

Magnetic properties of trinuclear manganese(II) complex with thiophenedicarboxylate

Substance Trinuclear manganese(II) complex with thiophenedicarboxylate; [Mn3(tdc)3(dmf)3]n

Gross Formula C27H27Mn3N3O15S3

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_55

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164

Magnetic properties of trinuclear manganese(II) complex. . .

Structure [Mn3(tdc)3(dmf)3]n;

H2tdc ¼ 2,5-thiophenedicarboxylic acid; OH

HO S

O O dmf ¼ N,N-dimethylformamide H3C O N C H HC 3

Data T [K] 300 2.0

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 12.69 0.85

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks trinuclear units linked to give 3D structure

Reference

165

Additional Remarks (i) antiferromagnetic interactions between Mn(II) ions indicated

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference H.-B. Yuan, S.-Y. Yang, Z.-X. Xie, R.-B. Huang, S.R. Batten, Inorg. Chem. Commun. 12, 755 (2009)

Part V Re

Magnetic properties of metallamacrocycle of manganese(II,III) with (z)-3-(salicylhydrazinocarbonyl) propenoic acid

Substance Metallamacrocycle of manganese(II,III) with (z)-3-(salicylhydrazinocarbonyl) propenoic acid; [MnII10 MnIII 4 (L)8(HL)2(H2O)2(CH3OH)14].8H2O.8CH3OH

Gross Formula C132H170Mn14N20O82

Properties Molar magnetic moment and Weiss constant

Structure [MnII10 MnIII 4 (L)8(HL)2(H2O)2(CH3OH)14].8H2O.8CH3OH; H4L ¼ (z)-3-(salicylhydrazinocarbonyl)propenoic acid OH O O H N OH N H O

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166

Additional Remarks

167

Data T [K] 300 100 2.0

χM pm or μeff χg [106 emu/g] [106 emu/mol] [μB] – – 19.01 18.27 9.38

ΘP [K] Method 13.5 –

Remarks a) cross-net shaped metallomacrocycle b) all the manganese ions have distorted octahedral geometry except Mn5 which has square-pyramidal coordination

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) plot of χ M1and μeff versus T is shown in Fig. 1 (ii) T > 20.2, Curie-Weiss behavior observed, with: C ¼ 47.33 cm3 K mol1 θ ¼ 13.5 K (iii) antiferromagnetic coupling indicated

III Fig. 1 [MnIII 10 Mn4 (L)8(HL)2(H2O)2(CH3OH)14].3H2O.8CH3OH.13H2O. Temperature dependence of χ M-1 and μeff

168

Magnetic properties of metallamacrocycle of manganese(II,III). . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP χ M1 θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) inverse molar susceptibility Curie constant Curie temperature

Reference F.-P. Xioa, L.-F. Jin, Inorg. Chem. Commun. 11, 717 (2008)

Magnetic properties of manganese(II) complex with L-3-phenyl-2(3-phenyl-ureido)propionic acid

Substance catena-poly-{Diaqua-di[L-3-phenyl-2-(3-phenyl-ureido)propionato] manganese(II)}; [Mn(L)2(H2O)2]n

Gross Formula C32H34MnN4O8

Properties Molar magnetic moment

Structure [Mn(L)2(H2O)2]n;

HL ¼ L-3-phenyl-2-(3-phenyl-ureido)propionic acid OH H H N N O O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_57

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170

Magnetic properties of manganese(II) complex with L-3-phenyl. . .

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.12

ΘP [K] –

Method –

Remarks 1D polymer, distorted octahedral Mn(II) having d5 configuration in weak field

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference A. Karmakar, J.B. Baruah, Inorg. Chem. Commun. 12, 140 (2009)

Magnetic properties of manganese(II) diphosphonate

Substance Manganese(II) diphosphonate; [Mn(H2L)].3H2O / {[Mn(H2L)].3H2O}n

Gross Formula C7H15MnNO10P2

Properties Molar magnetic moment and exchange energy

Structure {[Mn(H2L)].3H2O}n;

H4L ¼ 1-hydroxy-2-(2-pyridyl)ethylidene1,1-diphosphonic acid O OH H2 C C

P

OH OH

P

N O

OH OH

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172

Magnetic properties of manganese(II) diphosphonate

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 8.35/Mn2

ΘP [K] –

Method –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) plot of χ M and χ MT versus T is shown in Fig. 1 (ii) weak antiferromagnetic interactions, with: J ¼ 0.41 cm1 zJ0 ¼ 0.00775 cm1 (zero-field splitting parameter) g ¼ 2.0

Fig. 1 {[Mn(H2L)].3H2O}n. Temperature dependence of χ M and χ MT

Remarks ladder-like chain structure, Mn(II) adopts octahedral geometry

Reference

173

Symbols and Abbreviations Short form T χg χM pm μeff ΘP D g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) zero-field splitting parameter Lande factor

Reference Y. Ma, R. Yuan, L. Zheng, Inorg. Chem. Commun. 12, 890 (2009)

Magnetic properties of manganese(III) complex with sulphonato-substituted Schiff-base

Substance Manganese(III) complex with 1,3-bis(5-sulphonatosalicylidenamino)propan-2-ol; Na[Mn(5-SO3-L)(H2O)].5H2O

Gross Formula C17H16MnN2NaO10S2

Properties Molar magnetic moment, Weiss constant and exchange energy

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Data

175

Structure Na[Mn(5-SO3-L)(H2O)].5H2O; N O3S

S

N

Mn O

SO3Na O N

S

N

Mn

O3 S O

SO3Na O N

S

N

Mn

O3S O

SO3Na O

Na2(5-SO3-L) ¼ 1,3-bis(5-sulphonatosalicylidenamino)propan-2-ol OH

N NaO3S

N

OH HO

SO3Na

Data T [K] RT–100 100–20 2.0

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 4.87 4.51 3.29

ΘP [K] 6.7

Method SQUID

Remarks 1D polymer

176

Magnetic properties of manganese(III) complex with sulphonato-substituted. . .

Additional Remarks (i) temperature dependence of χ M and χ MT is shown in Fig. 1 (ii) Curie-Weiss behavior, with: C ¼ 2.96 cm3Kmol–1 θ ¼ –6.7 K (iii) χ M data analyzed using 1D chain model; best-fit parameters are: J ¼ –0.16 cm–1 g ¼ 1.931

Fig. 1 Na[Mn(5-SO3-L)(H2O)].5H2O. Temperature dependence of χ M (□) and χ MT (Δ). The solid line show the best-fit on the Heisenberg chain model with parameters described in the text

Reference

177

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie constant Curie temperature

Reference D. Moreni, V. Daier, C. Palopoli, J.P. Tuchagues, S. Signrella, J. Inorg. Biochem. 104, 496 (2010)

Magnetic properties of manganese(III) complex with 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaocatane1,8-diamine

Substance Manganese(III) complex with 1,8-N-bis(3-carboxy)disalicylidene)-3,6-diazaocatane1,8-diamine; [Mn(H2L)]OAc

Gross Formula C24H27MnN4O8

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_60

178

Data

179

Structure [Mn(H2L)]OAc; H C N HOOC

NH

O Mn O

HOOC

Cl.2H2O NH

N C H H4L ¼ 1,8-N-bis(3-carboxy)disalicylidene)-3,6-diazaocatane-1,8-diamine HOOC

COOH HO

OH C

N

NH NH

N

C H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 4.78

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks pseudo-octahedral

180

Magnetic properties of manganese(III) complex with 1,8-N-bis(3-carboxy). . .

Additional Remark (i) absence of exchange or super-exchange interactions observed

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Gouy

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Gouy method or Pascal method

Reference S. Sarkar, K. Dey, Spectrochim. Acta A 77, 740 (2010)

Magnetic properties of 18-membered hexanuclear manganese(III) macrocycle

Substance Hexanuclear manganese(III) complex with N-acetyl-3-methyl-salicylhydrazide; [Mn6(L)6(CH3OH)6].6H2O

Gross Formula C66H90Mn6N12O30

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_61

181

182

Magnetic properties of 18-membered hexanuclear manganese(III) macrocycle

Structure [Mn6(L)6(CH3OH)6].6H2O;

H3L ¼ N-acetyl-3-methyl-salicylhydrazide CH3 OH O H N N CH3 H O

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.12

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method –

Remarks planar 18-membered ring, stereochemistry around Mn(III) is propeller shape

Reference

183

Additional Remarks (i) plots of χ M-1 and χ MT versus T are shown in Fig. 1 (ii) weak antiferromagnetic interactions observed

Fig. 1 [Mn6(L)6(CH3OH)6].6H2O. Temperature dependence of χ MT, χ M-1 and χ M (inset)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP χ M1

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) inverse molar susceptibility

Reference T.P. Shu, Z.J. Chen, H.-M. Feng, J.-L. Wen, K.-W. Lei, Inorg. Chem. Commun. 12, 672 (2009)

Magnetic properties of polymeric manganese(III) carboxylate complex with salicylaldoxime

Substance Manganese(III) carboxylate complex with salicylaldoxime; {[Mn3(μ3-O)(O2CPh)2(salox)3(Me2CO)]Me2CO}n

Gross Formula C41H37Mn3N3NaO13

Properties Product of molar magnetic susceptibility with temperature and exchange energy

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184

Data

185

Structure {[Mn3(μ3-O)(O2CPh)2(salox)3(Me2CO)] Me2CO}n; N O

Ph O

L O O

N

Mn

O

O

C H

O

N

N

O N

OH

O

O

Mn

Mn

Mn O

Na

O

H2salox ¼ salicylaldoxime

O

O

O

O

Ph L = Me2CO

Data T [K] 300 2.0

χg [106 emu/g] –

χ MT [cm3 K mol1] 6.64 0.51

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 1D polymeric structure

OH

186

Magnetic properties of polymeric manganese(III) carboxylate complex. . .

Additional Remarks (i) χ MT versus T plot is shown in Fig. 1 (ii) antiferromagnetic interactions indicated (iii) best-fit parameters are: J1~J2 ¼ 11.8 cm1 g ¼ 2.01 (iv) S ¼ 2 is the ground state Fig. 1 {[Mn3(μ3-O) (O2CPh)2(salox)3(Me2CO)] Me2Co}n. Temperature dependence of χ MT

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference C.P. Raptopoulou, A.K. Boudalis, K.N. Lazarou, V. Psycharis, N. Panopoulos, M. Fardis, G. Diamantopoulos, J.-P. Tuchagues, A. Mari, G. Papavassiliou, Polyhedron 27, 3575 (2008)

Magnetic properties of hexanuclear manganese(III) carboxylate complex with salicylaldoxime

Substance Manganese(III) carboxylate complex with salicylaldoxime; [Mn6(μ-O)2(O2CPh)2(salox)6(py)2(H2O)2].6MeCN

Gross Formula C66H54Mn6N8O20

Properties Product of molar magnetic susceptibility with temperature

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_63

187

188

Magnetic properties of hexanuclear manganese(III) carboxylate complex. . .

Structure [Mn6(μ-O)2(O2CPh)2(salox)6(py)2(H2O)2].6MeCN; O O O 2 N N Mn L O L Mn O O N Mn O O O 3Mn N O O 1 L Mn L Mn N N O O O L = py; L' = OH2 H2salox ¼ salicylaldoxime;

py ¼ pyridine

OH

C H

N

N OH

Data T [K] 300 30 10

χ MT pm or μeff χg [106 emu/g] [cm3 K mol1] [μB] – 15.62 – 7.63 19.22

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks a) two [Mn3(μ5-O)7+ triangular subunits linked by salox2- ligands b) coordination geometry around Mn(1) and Mn(3) is distorted octahedral while that of Mn(2) is square-pyramidal

Reference

189

Additional Remarks (i) χ MT versus T plot is shown in Fig. 1 (ii) magnetic behavior shows the interplay of both ferro- and antiferromagnetic interactions (iii) S ¼ 4 is the ground state Fig. 1 [Mn6(μ-O)2(O2CPh)2 (salox)6(py)2(H2O)2.6MeCN. Temperature dependence of χ MT

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference C.P. Raptopoulou, A.K. Boudalis, K.N. Lazarou, V. Psycharis, N. Panopoulos, M. Fardis, G. Diamantopoulos, J.-P. Tuchagues, A. Mari, G. Papavassiliou, Polyhedron 27, 3575 (2008)

Magnetic properties of manganese(III) complex with 2-(2-pyridylmethyleneamino) pyridine

Substance Manganese(III) complex with 2-(2-pyridylmethyleneamino)pyridine; [Mn(L)2]Cl.3H2O

Gross Formula C22H26ClMnN6O5

Properties Molar magnetic moment

Structure HL ¼ 2-(2-pyridylmethyleneamino) pyridine

[Mn(L)2]Cl.3H2O;

N Mn2+

N

O

N

Cl

N N

N

2

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_64

190

Additional Remarks

191

Data T [K] 77

χg [106 emu/g] –

χM pm or μeff [106 emu/mol] [μB] – 2.8

ΘP [K] –

Method SQUID

Remarks a) low-spin, geometry around Mn(II) is axially compressed octahedral b) compound shows spin crossover behaviour between 300-77 K c) at 300 K, high-spin limit is entropically inaccessible

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) μeff versus T plot is shown in Fig. 1 (ii) at 77 K, the μeff converges close to the low-spin (LS, S ¼ 1) value (2.8μB) (iii) at 300 K, the HS (S ¼ 2) limit is entropically inaccessible, as this is a one-electron spin crossover

Fig. 1 [Mn(L)2]Cl.3H2O. Temperature dependence of μeff

192

Magnetic properties of manganese(III) complex with 2-(2-pyridyl. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference Z. Liu, S. Liang, X. Di, J. Zhang, Inorg. Chem. Commun. 11, 783 (2008)

Magnetic properties of manganese(II) coordination polymer with mixed pyrimidine-2-carboxylate and oxalate bridges

Substance poly-Manganese(II) coordination polymer with mixed pyrimidine-2-carboxylate and oxalate bridges; [Mn2(pymca)2(ox)(H2O)2]n

Gross Formula C12H10Mn2N4O10

Properties Product of molar magnetic susceptibility with temperature and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_65

193

Magnetic properties of manganese(II) coordination polymer with. . .

194

Structure [Mn2(pymca)2(ox)(H2O)2]n;

Hpymca ¼ pyrimidine-2-carboxylic acid; O OH C N

ox2- ¼ oxalate anion O O

O

N

O

Data T [K] 300

χ MT χg [106 emu/g] [cm3Kmol1] – 4.18

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 10.8

Method SQUID

Remarks a) 2D coordination polymer b) local coordination environment around each Mn2+ is octahedral

Reference

195

Additional Remarks (i) temperature dependence of χ M and χ MT is shown in Fig. 1 (ii) >23 K, Curie-Weiss law is obeyed, with: θ¼10.8 K (iii) compound is a spin-canted antiferromagnet with waek ferromagnetic transition below Tc ¼ 2.4 K Fig. 1 [Mn2(pymca)2(ox) (H2O)2]n. Temperature dependence of χ M and χ MT

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Curie constant Curie temperature

Reference J.-Y. Zhang, Y. Ma, A.-L. Cheng, Q. Yue, Q. Sun, E.-Q. Gan, Dalton Trans. 2061 (2008)

Magnetic properties of rhenium(III) complex of 1-(2-pyridylazo)-2-naphthol

Substance Bromo-bis[1-(2-pyridylazo)-2-naphtholato]rhenium(III) dichloroformate; [ReBr(pan)2].2CHCl3

Gross Formula C32H22BrCl6N6O2Re

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_66

199

200

Magnetic properties of rhenium(III) complex of 1-(2-pyridylazo)-2-naphthol

Structure [ReBr(pan)2].2CHCl3;

Hpan ¼ 1-(2-pyridylazo)-2-naphthol N N

N OH

Additional Remark

201

Data T [K] 300 1.8

χM χg [106 emu/g] [106 emu/mol] – –

pm or μeff [μB] 2.25 0.18

ΘP [K] –

Method SQUID

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) χ M versus T and μeff versus T plot is shown in Fig. 1 Fig. 1 [ReBr(pan)2].2CHCl3. Temperature dependence of χ M (○) and μeff (●)

Remarks slightly distorted heptanuclear capped trigonal-prismatic Re(III) complex with d4 low-spin electronic configuration

202

Magnetic properties of rhenium(III) complex of 1-(2-pyridylazo)-2-naphthol

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference B. Machura, J. Mrozinski, R. Kruszynski, J. Kusz, Polyhedron 27, 3013 (2008)

Magnetic properties of rhenium(III) complex with 1-isoquinoline phenyl ketone

Substance Trichloro(1-isoquinolinyl phenyl ketone) triphenylphosphinerhenium(III); [ReCl3(L)(PPh3)]

Gross Formula C34H26Cl3NOPRe

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_67

203

204

Magnetic properties of rhenium(III) complex with 1-isoquinoline phenyl ketone

Structure [ReCl3(L)(PPh3)];

L ¼ 1-isoquinoline phenyl ketone N

O

Data T [K] 300 1.8

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.91 0.82

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks octahedral, d4 low-spin

Reference

205

Additional Remark (i) 3T1g ground state arises because of large spin-orbit coupling

Symbols and Abbreviations Short form T χg χM SQUID pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) superconducting quantum interference device effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference B. Machura, R. Kruszynski, J. Mrozinski, J. Kusz, Polyhedron 27, 1739 (2008)

Magnetic properties of hetero-trimetallic Gd-Re-Te three dimensional coordination polymer

Substance Ion-pair complex having triaquagadolium(III) cation and hexacyanotelluraterhenate cluster anion; {[Gd(H2O)3][Re6Te8(CN)6]}.2.5H2O

Gross Formula C6H13GdN6O6.5Re6Te8

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_68

206

Data

207

Structure {[Gd(H2O)3][Re6Te8(CN)6]}.2.5H2O

Structure of cluster anion

Data T [K] 300

χg [10 –

6

emu/g]

χM [10 –

6

emu/mol]

pm or μeff [μB] 8.13

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQID

Remarks ion-pair complex

208

Magnetic properties of hetero-trimetallic Gd-Re-Te three. . .

Symbols and Abbreviations Short form T χg χM pm SQUID μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule superconducting quantum interference device effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference M.S. Tarasenko, N.G. Naumov, D. Yu, S.-J.K. Naumov, V.E. Fedorov, Polyhedron 27, 2357 (2008)

Magnetic properties of hetero-trimetallic Ho-Re-Te three dimensional coordination polymer

Substance Ion-pair complex having tetraaquaholmium(III) cation and hexacyanotelluraterhenate cluster anion; {[Ho(H2O)4][Re6Te8(CN)6]}.2.5H2O

Gross Formula C6H13HoN6O6.5Re6Te8

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_69

209

210

Magnetic properties of hetero-trimetallic Ho-Re-Te three dimensional coordination. . .

Structure {[Ho(H2O)4][Re6Te8(CN)6]}.2.5H2O

Structure of cluster anion

Data T [K] 300

χg [10
6 emu/g] –

χM [10
6 emu/mol] –

pm or μeff [μB] 10.79

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQID

Remarks ion-pair complex

Reference

211

Additional Remark (i) temperature dependence of μeff and χ M–1 is shown in Fig. 1 (ii) Curie-Weiss law followed (iii) the value of μeff is in good agreement with μeff (10.78 μB), calculated for two weekly interacting magnetic centers: H3þ O (μeff ¼ 10.61 μB) and paramagnetic anion [Re6Te9(CN)6]3- (μeff ¼ 1.96 μB)

Fig. 1 {[Ho(H2O)4][Re6Te8(CN)6]}.2.5H2O. Temperature dependence of μeff (○) and χ M–1 (●)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID χ M
1

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device inverse molar susceptibility

Reference M.S. Tarasenko, N.G. Naumov, D. Yu, S.-J.K. Naumov, V.E. Fedorov, Polyhedron 27, 2357 (2008)

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand (as perchlorate salt)

Substance Bis{2,4-di(6-picolyl)-6-(bromophenyl)-1,3,5-triazine}iron(II) perchlorate; [Fe(L)2](ClO4)2

Gross Formula C42H34Br2Cl2FeN6O9

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_70

215

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand. . .

216

Structure L ¼ 2,4-di(6-picolyl)6-(bromophenyl) Br

[Fe(L)2](ClO4)2;

Br

N

N

N

N N

N

II

Fe

N

(ClO4)2

N N

N

N

N

N

N

N

Br

Data T [K] 340 4.0

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 5.4 3.9

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks high-spin Fe(II) complex (S¼2)

Reference

217

Additional Remarks (i) plot of temperature dependence of μeff is shown in Fig. 1 (ii) reduction of μeff at lower temperature may be associated with zero-field splitting of the spin quintet states (iii) magnetic data suggest the complex to be pure Curie paramagnet Fig. 1 [Fe(L)2](ClO4)2. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference E.A. Medlycott, G.S. Hanan, T.S.M. Abedin, L.K. Thompson, Polyhedron 27, 493 (2008)

Part VI Fe

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as perchlorate salt

Substance Bis{2,4-di(20 -pyrazyl)-6-(bromophenyl)-1,3,5-triazine}iron(II) perchlorate hemihydrate; [Fe(L)2](ClO4)2.0.5H2O

Gross Formula C34H21Br2Cl2FeN14O8.5

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_71

218

Structure

219

Structure [Fe(L)2](ClO4)2.0.5H2O; Br

N N

N N

N N

Fe

N N

N

II

(ClO4)2.0.5H2O

N

N

N N

N

Br L ¼ 2,4-di(20 -pyrazyl)-6-(bromophenyl)-1,3,5-triazine Br

N

N N

N N

N N

220

Magnetic properties of iron(II) complex with 1,3,5-triazine. . .

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 4.2

ΘP [K] –

Method SQUID

Remarks high-spin complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form SQUID T χg χM pm μeff ΘP

Full form superconducting quantum interference device temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference E.A. Medlycott, G.S. Hanan, T.S.M. Abedin, L.K. Thompson, Polyhedron 27, 493 (2008)

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as perchlorate salt

Substance Bis{2,4-di(20 -pyridyl)-6-(bromophenyl)-1,3,5-triazine}iron(II) hexafluorophosphate; [Fe(L)2](PF6)

Gross Formula C38H24Br2F12FeN10P2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_72

221

222

Magnetic properties of iron(II) complex with 1,3,5-triazine. . .

Structure L ¼ 2,4-di(20 -pyridyl)-6(bromophenyl)-1,3,5-triazine Br

[Fe(L)2](PF6); Br

N

N

N

N N

N

II

Fe

N

(PF6)2

N N

N

N

N

N

N

N

Br

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.5

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks hexa-coordination

Reference

223

Symbols and Abbreviations Short form SQUID T χg χM pm μeff ΘP

Full form superconducting quantum interference device temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference E.A. Medlycott, G.S. Hanan, T.S.M. Abedin, L.K. Thompson, Polyhedron 27, 493 (2008)

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as perchlorate salt

Substance Bis(bromophenyl-2,2:600 ,200 -terpyridine)iron(II) perchlorate monohydrate; [Fe(L)2](ClO4)2.H2O

Gross Formula C42H30Br2Cl2FeN6O9

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_73

224

Structure

225

Structure [Fe(L)2](ClO4)2.H2O; Br

N N N

(ClO4)2.H2O

N

II

Fe

N

N

Br L ¼ bromophenyl-2,2:600 ,200 -terpyridine Br

N N

N

226

Magnetic properties of iron(II) complex with 1,3,5-triazine. . .

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.1

ΘP [K] –

Method SQUID

Remarks hexa-coordination

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form SQUID T χg χM pm μeff ΘP

Full form superconducting quantum interference device temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference E.A. Medlycott, G.S. Hanan, T.S.M. Abedin, L.K. Thompson, Polyhedron 27, 493 (2008)

Magnetic properties of iron(II) complex with 1,3,5-triazine containing ligand as hexafluorophosphate salt

Substance Bis(bromophenyl-2,2:600 ,200 -terpyridine)iron(II) hexafluorophosphate; [Fe(L)2](PF6)2

Gross Formula C46H34Br2F12FeN8P2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_74

227

228

Magnetic properties of iron(II) complex with 1,3,5-triazine. . .

Structure L ¼ bromophenyl-2,2: 600 ,200 -terpyridine Br

[Fe(L)2](PF6)2;

Br

N N

N

II

N

Fe N

(PF6)2

N N

N

N

Br

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.5

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks hexa-coordination

Reference

229

Symbols and Abbreviations Short form SQUID T χg χM pm μeff ΘP

Full form superconducting quantum interference device temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference E.A. Medlycott, G.S. Hanan, T.S.M. Abedin, L.K. Thompson, Polyhedron 27, 493 (2008)

Magnetic properties of iron(II) complex with thiocyanate, tris-pyrazolylmethane and pyridine

Substance Tris-[(3,5-dimethylpyrazol-1-yl)methane]pyridinedithiocyanatoiron(II); [Fe(NCS)2(tpm)(py)]

Gross Formula C23H27FeN9S2

Properties Product of molar magnetic susceptibility with temperature

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_75

230

Reference

231

Structure tpm ¼ tris(3,5-dimethylpyrazol-1-yl)methane;

[Fe(NCS)2(tpm)(py)];

N N N N

N

N

N Fe N

N N

C

S N N

C

N N

N

S py ¼ pyridine

N

Data T [K] 300-50

χg [106 emu/g] –

χ MT [cm3 K mol1] 3.4–3.3

pm or μeff [μB] –

ΘP [K] –

Method SQUID

Remarks high-spin

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference A.A. Salaudeen, C.A. Kilner, M.A. Halcrow, Polyhedron 27, 2569 (2008)

Magnetic properties of iron(II) complex with selenocyanate, tris-pyrazolylmethane and pyridine

Substance Tris-[(3,5-dimethylpyrazol-1-yl)methane]pyridinediselenocyanatoiron(II); [Fe(NCSe)2(tpm)(py)]

Gross Formula C23H27FeN9S2

Properties Product of molar magnetic susceptibility with temperature

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232

Reference

233

Structure tpm ¼ tris(3,5-dimethylpyrazol-1-yl)methane;

[Fe(NCSe)2(tpm)(py)];

N N N N

N

N

N Fe N

N N

C

Se N N

C

N N

N

Se py ¼ pyridine

N

Data T [K] 300-50

χg [106 emu/g] –

χ MT [cm3 K mol1] 3.4–3.3

pm or μeff [μB] –

ΘP [K] –

Method SQUID

Remarks high-spin

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference A.A. Salaudeen, C.A. Kilner, M.A. Halcrow, Polyhedron 27, 2569 (2008)

Magnetic properties of iron(II) complex with selenocyanate, tris-pyrazolylmethane and imidazole

Substance Tris-[(3,5-dimethylpyrazol-1-yl)methane]imidazoledithiocyanatoiron(II); [Fe(NCS)2(tpm)(im)]

Gross Formula C21H26FeN10S2

Properties Product of molar magnetic susceptibility with temperature

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234

Symbols and Abbreviations

235

Structure tpm ¼ tris(3,5-dimethylpyrazol-1-yl)methane;

[Fe(NCS)2(tpm)(im)]; N N N N

N

N

N Fe N

N N

NH

C

S

N N C

N N

N

S

im ¼ imidazole

N

N H

Data T [K] 300-50

χg [106 emu/g] –

χ MT [cm3 K mol1] 3.4–3.3

pm or μeff [μB] –

ΘP [K] –

Method SQUID

Remarks high-spin

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

236

Magnetic properties of iron(II) complex with selenocyanate,. . .

Reference A.A. Salaudeen, C.A. Kilner, M.A. Halcrow, Polyhedron 27, 2569 (2008)

Magnetic properties of dinuclear iron(II) complex with thiocyanate, tris-pyrazolylmethane and 4,40 -bipyridine

Substance μ-4,40 -Bipyridine-di{[tris-[(3,5-dimethylpyrazol-1-yl)methane] dithiocyanatoiron(II); {[Fe(NCS)2(tpm)]2(μ-4,40 -bipy)}.H2O

Gross Formula C46H54Fe2N18OS4

Properties Product of molar magnetic susceptibility with temperature

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_78

237

Magnetic properties of dinuclear iron(II) complex with thiocyanate,. . .

238

Structure {[Fe(NCS)2(tpm)]2(μ-4,40 -bipy)}.H2O;

N N N N N

N Fe N

S

S

C

C

N N

N N

C

tpm ¼ tris(3,5-dimethylpyrazol-1-yl) methane; N

S

N

N N

C

N

N

S

N Fe N N

N N N

N 4,40 -bipy ¼ 4,40 -bipyridine N

N

Data T [K] 300–50

χg [106 emu/g] –

χ MT [cm3 K mol1] 6.8–6.7

pmor μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 4,40 -bipyridine bridged dinuclear complex, high-spin Fe(II)

Reference

239

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference A.A. Salaudeen, C.A. Kilner, M.A. Halcrow, Polyhedron 27, 2569 (2008)

Magnetic properties of dinuclear iron(II) complex with selenocyanate, tris-pyrazolylmethane and 4,40 -bipyridine

Substance μ-4,40 -Bipyridine-di{[tris-[(3,5-dimethylpyrazol-1-yl)methane]diselenocyanatoiron(II); {[Fe(NCSe)2(tpm)]2(μ-4,40 -bipy)}

Gross Formula C46H52Fe2N18Se4

Properties Product of molar magnetic susceptibility with temperature

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_79

240

Data

241

Structure {[Fe(NCSe)2(tpm)]2(μ-4,40 -bipy)};

N N N N N

N Fe N

Se

Se

C

C

N N

N N

C

tpm ¼ tris(3,5-dimethylpyrazol-1-yl) methane; N

Se

N N

C

N N

N

Se

N Fe N N

N N N

N 4,40 -bipy ¼ 4,40 -bipyridine N

N

Data T [K] 300–50

χg [106 emu/g] –

χ MT [cm3 K mol1] 6.8–6.7

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 4,40 -bipyridine bridged dinuclear complex, high-spin Fe(II)

242

Magnetic properties of dinuclear iron(II) complex with selenocyanate,. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference A.A. Salaudeen, C.A. Kilner, M.A. Halcrow, Polyhedron 27, 2569 (2008)

Magnetic properties of ion-pair complex of bis(4-methylpyridine)iron(II) cation and dicyanoaurate(I) anion

Substance Bis(4-methylpyridine)iron(II) di[dicyanoaurate(I)]; [Fe(4-Mepy)2][Au(CN)2]2

Gross Formula C16H14Au2FeN6

Properties Product of molar magnetic susceptibility with temperature

Structure [Fe(4-Mepy)2][Au(CN)2]2;

4-Mepy ¼ 4-methylpyridine CH3

N

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_80

243

244

Magnetic properties of ion-pair complex of bis(4-methylpyridine)iron(II). . .

Data T [K] 300 197 197–182 50 K, Curie-Weiss law is obeyed, with: C ¼ 0.40 cm3 K mol1 θ ¼ 2.02 K (iii) χ M data analyzed through Bleaney-Bowers expression, yielded best-fit parameters, as: J/k ¼ 4.3 K (3.0 cm1) g ¼ 2.10 Fig. 1 {[Cu(L)]2(pz)} (ClO4)2. Temperature dependence of χ M (○) and χ MT (●). The solid lines represent the best fittings

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie constant Curie temperature

Reference P. Gomez-Saiz, R. Gil-Garcia, M.A. Maestro, J.L. Pizarro, M.I. Arriortua, L. Lezana, T. Rojo, M. Gonzalez-Alvarez, J. Borras, J. Garcia-Tojal, J. Inorg. Biochem. 102, 1910 (2008)

Magnetic properties of dinuclear copper(II) complex with pyridine-2-carbaldehyde thiosemicarbazone and dicyanamide

Substance μ-Dicyanamido-bis(pyridine-2-carbaldehydethiosemicarbazone)dicopper(II) perchlorate; [{[Cu(L)]2(dca)}(ClO4)]n

Gross Formula C16H14ClCu2N11O4S2

Properties Molar magnetic moment, molar magnetic susceptibility, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_420

1141

Magnetic properties of dinuclear copper(II) complex with pyridine-2. . .

1142

Structure [{[Cu(L)]2(dca)}(ClO4)]n;

HL ¼ pyridine-2-carbaldehydethiosemicarbazone;

CH

N

N

NH

NH2 S dca ¼ dicyanamide

N C

N

C

N

Additional Remarks

1143

Data T [K] RT 6.5

χg [106 emu/g] – –

χM [106 emu/mol] – 66,000

pm or μeff [μB] 1.79

ΘP [K] 2.80

Method SQUID

Remarks Ladder-like chains of dimer, each Cu(II) having square-pyramidal geometry

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Plots of χ M versus T and χ MT versus T are shown in Fig. 1 (ii) >50 K, Curie-Weiss law is obeyed, with: C ¼ 0.41 cm3 K mol1 θ ¼ 2.80 K (iii) χ M data analyzed through Bleaney-Bowers expression, yielded best-fit parameters, as: J/k ¼ 5.1 K (3.0 cm1) z’J’ ¼ +0.9 K (+0.6 cm1) (intradimer exchange interaction parameter g ¼ 2.08 Fig. 1 [{[Cu(L)]2(dca)} (ClO4)]n. Temperature dependence of χ M (○) and χ MT (●). The solid lines represent the best fittings

1144

Magnetic properties of dinuclear copper(II) complex with pyridine-2. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID z0 J0 g θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device intradimer exchange interaction parameter Lande factor Curie constant Curie temperature

Reference P. Gomez-Saiz, R. Gil-Garcia, M.A. Maestro, J.L. Pizarro, M.I. Arriortua, L. Lezana, T. Rojo, M. Gonzalez-Alvarez, J. Borras, J. Garcia-Tojal, J. Inorg. Biochem. 102, 1910 (2008)

Magnetic properties of syn-anti acetatebridged dinuclear copper(II) complex with 1,10-phenanthroline

Substance μ-Acetato-di[1,10-phenanthrolinecopper(II)] hexafluorophosphate; [Cu(phen)2]2 (μ-OAc)}(PF6)3

Gross Formula C50H35Cu2F18N8O2P3

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_421

1145

Magnetic properties of syn-anti acetate-bridged dinuclear copper(II). . .

1146

Structure phen ¼ 1,10-phenanthroline

[Cu(phen)2]2(μ-OAc)}(PF6)3;

N

N

Data T [K]

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.63

ΘP [K] –

Method Evans

Remarks Dinuclear syn-anti coordination with a trigonal-bipyramidal geometry for Cu(1) center and a distorted squarebased pyramidal geometry for the Cu(2) center

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg Evans χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) Evans balance magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference

1147

Reference H. Hadadzadeh, S.J.A. Fatemi, S.R. Hosseinian, H.R. Khavasi, R. Pottgen, Polyhedron 27, 249 (2008)

Magnetic properties of mixed ligand dicopper complex with dibenzodioxatetraazamacrocycle and succinate

Substance Mixed ligand dicopper complex with dibenzodioxatetraazamacrocycle and succinate; [Cu2(L)Cl2(suc)]

Gross Formula C28H46Cl2Cu2N4O9

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_422

1148

Data

1149

Structure [Cu2(L)Cl2(suc)]

L ¼ 26-membered dibenzodioxatetraazamacrocycle;

NH

HN O

O N H suc2 ¼ succinate anion O H2C C O O H2C C O

NH

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.0

ΘP [K] –

Method Faraday

Remarks Dinuclear

1150

Magnetic properties of mixed ligand dicopper complex with dibenzodioxa. . .

Additional Remarks (i) Thermal dependence of μeff is shown in Fig. 1 (ii) χ M data analyzed through Bleaney-Bowers equation, best-fit parameters being: 2 J/K ¼ -576 K ρ ¼ 0.17% (molar fraction of paramagnetic impurity) (iii) Strong antiferromagnetic interactions observed

Fig. 1 [Cu2(L)Cl2(suc)]. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Faraday ϱ J

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Faraday method molar fraction of paramagnetic impurity exchange energy

Reference S. Carvalho, R. Delgado, M.G.B. Drew, V. Felix, M. Figueira, R.T. Henriques, Polyhedron 27, 679 (2008)

Magnetic properties of mixed ligand dicopper complex with dibenzodioxatetraazamacrocycle and oxalate

Substance Mixed ligand dicopper complex with dibenzodioxatetraazamacrocycle and oxalate; [Cu2(H2)(L)(ox)3].4H2O

Gross Formula C30H46Cu2N4O18

Properties Molar magnetic moment and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_423

1151

Magnetic properties of mixed ligand dicopper complex. . .

1152

Structure [Cu2(H2)(L)(ox)3].4H2O;

L ¼ 26-membered dibenzodioxatetraazamacrocycle; HN

NH

O

O N H ox2 ¼ oxalate anion O O

O

NH

O

Data T [K] 225

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.5

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 12.8

Method Faraday

Remarks Oxalate bridged dinuclear complex

Reference

1153

Additional Remarks (i) Thermal dependence of μeff is shown in Fig. 1 (ii) Curie-Weiss behavior observed, with: θ ¼ 12.8 K Fig. 1 [Cu2(H2)(L) (ox)3].4H2O. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Faraday θ

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Faraday method Curie constant

Reference S. Carvalho, R. Delgado, M.G.B. Drew, V. Felix, M. Figueira, R.T. Henriques, Polyhedron 27, 679 (2008)

Magnetic properties of dinuclear copper(II) complex with deprotonated 2-(5-carboxy1H-pyrazol-3-yl)-4,4,5,5-tetramethyl-4, 5-dihydro-1H-imidazole

Substance Dinuclear copper(II) complex with deprotonated 2-(5-carboxy-1H-pyrazol-3-yl)4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole; [Cu2(dmf)2(L)2]

Gross Formula C28H42Cu2N10O8

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_424

1154

Data

1155

Structure [Cu2(dmf)2(L)2];

L ¼ deprotonated 2-(5-carboxy-1H-pyrazol-3-yl)4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole

O

N

O

NH N

dmf ¼ dimethylformamide H3C O H3C

O N

C

H

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] ~2.50

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Dinuclear, each of the two Cu(II) ions surrounded by a square pyramid

1156

Magnetic properties of dinuclear copper(II) complex with deprotonated. . .

Additional Remarks (i) Temperature dependence of μeff is shown in Fig. 1 (ii) Effective values of exchange interactions are: JCuCu ¼ 72 cm1 gCu ¼ 2.19

Fig. 1 [Cu2(dmf)2(L)2]. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference E.V. Tretyakov, S.E. Tolstikov, E.V. Gorelik, M.V. Fedin, G.V. Romansenko, A.-S. Bogomyakov, V.I. Ovcharenko, Polyhedron 27, 739 (2008)

Magnetic properties of dinuclear copper(II) acetato complex with pyrazol-3-ylsubstituted imino nitroxide

Substance Dinuclear copper(II) acetato complex with pyrazol-3-yl-substituted imino nitroxide; [Cu2(OAc)2(H2O)2(L)2]

Gross Formula C24H40Cu2N8O8

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_425

1157

Magnetic properties of dinuclear copper(II) acetato complex. . .

1158

Structure [Cu2(OAc)2(H2O)2(L)2];

dmf ¼ dimethylformamide H3C O N C H HC

HL ¼ pyrazol-3-yl-substituted imino nitroxide O N H N

N

3

NH

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.46

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Dinuclear, each of the two Cu(II) ions surrounded by a square-pyramid

Reference

1159

Additional Remarks (i) Temperature dependence of μeff is shown in Fig. 1 (ii) Effective values of exchange interactions are: JCuCu ¼ 74 cm1 JRCu ¼ 16 cm1 gCu ¼ 2.12.

Fig. 1 [Cu2(OAC)2 (H2O)2(L)2]. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference E.V. Tretyakov, S.E. Tolstikov, E.V. Gorelik, M.V. Fedin, G.V. Romansenko, A.-S. Bogomyakov, V.I. Ovcharenko, Polyhedron 27, 739 (2008)

Magnetic properties of dinuclear copper(II) complex with 5-carboxy-pyrazol-3-ylsubstituted nitronyl nitroxide

Substance Dinuclear copper(II) acetato complex with 5-carboxypyrazol-3-yl-substituted nitronyl nitroxide;[Cu2(H2O)2(L)2].2dmf

Gross Formula C28H44Cu2N10O12

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_426

1160

Data

1161

Structure L ¼ deprotonated 5-carboxypyrazol3-yl-substituted nitronyl nitroxide O O N

[Cu2(H2O)2(L)2].2dmf;

N O

O N

NH

dmf ¼ dimethylformamide H3C O N C H HC 3

Data T [K] 100–2.0

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.46

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Dinuclear, each of the two Cu(II) ions surrounded by a squarepyramid

1162

Magnetic properties of dinuclear copper(II) complex with 5-carboxy. . .

Additional Remarks (i) Temperature dependence of μeff is shown in Fig. 1 (ii) Effective values of exchange interactions are: JCuCu ¼ 72 cm1 JRCu ¼ +101 cm1 gCu ¼ 1.93

Fig. 1 [Cu2(H2O)2(L)2].dmf. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference E.V. Tretyakov, S.E. Tolstikov, E.V. Gorelik, M.V. Fedin, G.V. Romansenko, A.-S. Bogomyakov, V.I. Ovcharenko, Polyhedron 27, 739 (2008)

Magnetic properties of chloro bridged dinuclear copper(II) complex with 2-acetyl2-thiazoline hydrazone

Substance Di-μ-chloro-di[chloro(2-acetyl-2-thiazoline hydrazone)copper(II); {[CuCl(ath)]2(μ-Cl)2}

Gross Formula C10H18Cl4Cu2N6S2

Properties Molar magnetic moment, product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_427

1163

Magnetic properties of chloro bridged dinuclear copper(II) complex. . .

1164

Structure {[CuCl(ath)]2(μ-Cl)2};

ath ¼ 2-acetyl-2-thiazoline hydrazone N N NH 2

S H3C

Data T [K] RT

χg [106 emu/g] –

χ MT [cm3 K mol1] 2.98  103

pm or μeff [μB] 1.89

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 17.2

Method –

Remarks Dinuclear, geometry around each Cu(II) centre being distorted tetragonal-pyramid

Additional Remarks

1165

Additional Remarks (i) χ M versus T (■) and χ MT versus T (○) plots are shown in Fig. 1 (ii) >10 K, Curie-Weiss behavior observed, with: C ¼ 0.95 cm3 K mol1 θ ¼ 17.2 K (iii) χ M data analyzed through Bleaney-Bowers equation and yielded best-fit parameters as: J ¼ 7.52 cm1 g ¼ 2.14 ϱ ¼ 0.085% (molar fraction of paramagnetic impurity)

Fig. 1 {[CuCl(ath)]2(μ-Cl)2}. Temperature dependence of χ M (■) and χ MT (○). The solid lines represent the best-fit of the data with the Bleaney-Bowers expression below:

χM ¼

2Ng 2 μ2B Ng 2 μ2B p ð1 pÞ þ 2K B T K B T ½3 þ expð2J=K B T Þ

where: J ¼ exchange coupling ϱ ¼ molar fraction of paramagnetic impurity

1166

Magnetic properties of chloro bridged dinuclear copper(II) complex. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP ϱ g θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) molar fraction of paramagnetic impurity Lande factor Curie constant Curie temperature

Reference E. Vinuelas-Zahinos, M.A. Maldonado-Rogado, F. Luna-Giles, F.J. Barros-Garcia, Polyhedron 27, 879 (2008)

Magnetic properties of hydroxo-bridged dinuclear copper(II) complex with saccharinate-N

Substance Di-[μ-hydroxo-(N,N-diethylethylenediamine)(saccharinato-N)copper(II)] dihydrate; [Cu(μ-OH)(sac-N)(deten)]2.2H2O

Gross Formula C26H46Cu2N6O10S2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_428

1167

Magnetic properties of hydroxo-bridged dinuclear copper(II) complex. . .

1168

Structure sac-N ¼ saccharinate; O

[Cu(μ-OH)(sac-N)(deten)]2.2H2O;

N S O

O

deten ¼ N,N-diethylethylen ediamine C2H5 NH2 N C2H5

Data T [K] RT

χg [106 emu/g] –

χ MT [cm3 K mol1] –

pm or μeff [μB] 2.20

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks Dinuclear, both Cu(II) ions having squarepyramidal geometry

Reference

1169

Additional Remark (i) Sub-normal value of μeff indicated antiferromagnetic interactions

Symbols and Abbreviations Short form T Gouy χg χM pm μeff ΘP

Full form temperature Gouy method or Pascal method magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference O.Z. Yesilel, C. Darcan, E. Sahin, Polyhedron 27, 905 (2008)

Magnetic properties of hydroxo-bridged dinuclear copper(II) complex with saccharinate-O

Substance Di-[μ-hydroxo-(N,N,N0 N0 -tetramethylethylenediamine)(saccharsinato-O)copper(II)]; [Cu(μ-OH)(sac-O)(tmen)]2

Gross Formula C26H42Cu2N6O8S2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_429

1170

Data

1171

Structure [Cu(μ-OH)(sac-O)(tmen)]2;

sac-O ¼ saccharinate; O N S O

O

tmen ¼ N,N,N0 N0 -tetramethylethyle nediamine CH3 H3C N N CH3 H3C

Data T [K] RT

χg [106 emu/g] –

χ MT [cm3 K mol1] –

pm or μeff [μB] 2.24

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks Dinuclear, both Cu(II) ions having squarepyramidal geometry

1172

Magnetic properties of hydroxo-bridged dinuclear copper(II) complex. . .

Additional Remark (i) Sub-normal value of μeff indicated antiferromagnetic interactions

Symbols and Abbreviations Short form T Gouy χg χM pm μeff ΘP

Full form temperature Gouy method or Pascal method magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference O.Z. Yesilel, C. Darcan, E. Sahin, Polyhedron 27, 905 (2008)

Magnetic properties of 2-nitrobenzoatocopper(II) complex containing N,N-dimethylformamide

Substance Bis-[N,N-dimethylformamide)-bis(2-nitrobenzoato)dicopper(II)]; [Cu2(L)4(dmf)2]

Gross Formula C34H30Cu2N6O18

Properties Molar magnetic moment, product of molar magnetic susceptibility with temperature and exchange energy

Structure [Cu2(L)4(dmf)2];

HL ¼ 2-nitrobenzoic acid; O OH

dmf ¼ N,N-dimethylformamide H3C O N

H3C

C

H

NO2

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_430

1173

1174

Magnetic properties of 2-nitrobenzoatocopper(II) complex. . .

Data T [K] 300 50

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.238 0.002

pm or μeff [μB] 1.38 ~0.13

ΘP [K] –

Method SQUID

Remarks Dinuclear, two Cu(II) are bridged by four carboxylate groups, square-pyramidal coordination around Cu(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Plots of χ M and χ MT versus T are shown in Fig. 1 (ii) χ M data suggest very weak ferromagnetic interaction between Cu(II) centers (iii) Best-fitting parameters were obtained with: 2J ¼ 320 cm1 zJ’ ¼ 0.051 cm1 gdia ¼ 2.20 gmon ¼ 2.16 ϱ ¼ 0.38% (molar fraction of paramagnetic impurity) Fig. 1 [Cu2(L)4(dmf)2]. Temperature dependence of χ M (●) and χ MT (○). The solid line was generated from the best-fit magnetic parameters

Reference

1175

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID ϱ zJ 0 J

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device molar fraction of paramagnetic impurity interdimer exchange interaction parameter exchange energy

Reference J. Kavalirova, M. Korabik, P. Stachova, J. Moncol, R. Sillanpaa, T. Lis, D. Miklos, M. Melnik, J. Mrozinski, D. Valigura, Polyhedron 27, 1333 (2008)

Magnetic properties of dinuclear copper(II) complex with pyrazine and 2-phenyl-2(2-pyridyl)imidazolidine (as perchlorate salt)

Substance Bis[2-phenyl-2-(2-pyridyl)imidazolidine]pyrazinedicopper(II) monoacetonitrilate hemihydrate; [Cu2(L)2(pyz)](ClO4)4.CH3CN.0.5H2O

Gross Formula C34H38Cl4Cu2N9O16.5

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_431

1176

Reference

1177

Structure [Cu2(L)2(pyz)](ClO4)4.CH3CN.0.5H2O;

L ¼ 2-phenyl-2-(2-pyridyl) imidazolidine;

HN

NH

N

pyz ¼ pyrazine N

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.09

ΘP [K] –

Method –

Remarks Dinuclear

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S.M. Emam, P. McArdle, J. McManus, M. Mahon, Polyhedron 27, 2379 (2008)

Magnetic properties of dinuclear copper(II) complex with 28-membered [2 + 2] macrocyclic ligand derived from 1,4-bis (20 -formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane (as nitrate salt)

Substance Copper(II) complex with 28-membered [2 + 2] macrocyclic ligand derived from 1,4-bis(20 -formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane (as nitrate salt); [Cu2L](NO3)4.2CH3CN

Gross Formula C44H56Cu2N8O16

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_432

1178

Data

1179

Structure [Cu2L](NO3)4.2CH3CN;

L ¼ 28-membered [2 + 2] macrocyclic ligand derived from 1,4-bis(20 -formylphenyl)-1,4-dioxabutane and cis-1,2-diaminocyclohexane

O

O

NH HN NH HN

O

O

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.9

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method VSM

Remarks Dinuclear, both Cu(II) in a squareplanar environment

1180

Magnetic properties of dinuclear copper(II) complex with 28-membered. . .

Symbols and Abbreviations Short form VSM T χg χM pm μeff ΘP

Full form vibrating-sample magnetometer temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference M.d.C. Fernandez-Fernandez, R.B. de la Calle, A. Macias, L.V. Matarranz, P. Perez-Lourido, Polyhedron 27, 2301 (2008)

Magnetic properties of dinuclear copper(II) complex with pyrimidine derived Schiff-base ligand and 4,40 -bipyridine

Substance μ-4,4’-Bipyridinedicopper(II) complex with salicylhydrazone of 2-hydrazino4,6-dimethylpyrimidine; [Cu2(L)2(4,40 -bipy)(NO3)2]

Gross Formula C46H40Cu2N14O8

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_433

1181

Magnetic properties of dinuclear copper(II) complex with pyrimidine derived. . .

1182

Structure [Cu2(L)2(4,40 -bipy)(NO3)2];

HN N

N

O

N

Cu

N

NO3

NO3 N

N

N

Cu

NH

N

O

HL ¼ salicylhydrazone of 2-hydrazino-4,6-dimethylpyridine HO

N N

N H

N

4,40 -bipy ¼ 4,40 -bipyridine N

N

Data T [K] RT 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.883 0.594

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 4,40 -bipyridine bridged dinuclear copper(II) geometry around both of Cu(II) being squarepyramidal

Reference

1183

Additional Remarks (i) Plot of χ MT versus T is shown in Fig. 1 (ii) χ M data analyzed through Bleaney-Bowers equation to yield best-fit parameters as: J ¼ 1.6 cm1 g ¼ 2.17 (iii) Very weak coupling indicated Fig. 1 [Cu2(L)2(4,40 -bipy) (NO3)2]. Temperature dependence of χ MT. The solid line represents the best-fit curve

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference S. Gupta, S. Pal, A.K. Barik, A. Hazra, S. Roy, T.N. Mandal, S.-M. Peng, G.-H. Lee, M.S. El-Fallah, J. Tercero, S.K. Kar, Polyhedron 27, 2519 (2008)

Magnetic properties of bis(m-phenoxo) bridged dinuclear copper(II) complex with pyrimidine derived Schiff-base ligand

Substance Bis(μ-phenoxo)bridged dinuclear copper(II) complex with salicylhydrazone of 2-hydrazino-4,6-dimethylpyrimidine; [Cu2(L)2(NO3)2]

Gross Formula C26H24Cu2N10O8

Properties Product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_434

1184

Data

1185

Structure [Cu2(L)2(NO3)2]; NH

N

N N

Cu

O

NO3

O2N

O

Cu

N

N

N NH

HL ¼ salicylhydrazone of 2-hydrazino-4,6-dimethylpyridine HO

N N

N H

N

Data T [K] RT 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.951 0.332

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 1.5

Method SQUID

Remarks Phenoxo bridged dinuclear copper(II) geometry around each Cu(II) being square pyramidal

1186

Magnetic properties of bis(m-phenoxo) bridged dinuclear copper(II). . .

Additional Remarks (i) Plot of χ MT versus T is shown in Fig. 1 (ii) Best-fit parameters being: J ¼ 1.8 cm1 θ ¼ 1.5 K g ¼ 2.25

Fig. 1 [Cu2(L)2(NO3)2]. Temperature dependence of χ MT. The solid line represents the best-fit curve

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference S. Gupta, S. Pal, A.K. Barik, A. Hazra, S. Roy, T.N. Mandal, S.-M. Peng, G.-H. Lee, M.S. El-Fallah, J. Tercero, S.K. Kar, Polyhedron 27, 2519 (2008)

Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand

Substance Binuclear copper(II) complex with macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis(3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11tetraazacyclotetradecane with 1,2-diaminoethane; [Cu2(L)(ClO4)]ClO4

Gross Formula C30H43Cl2Cu2N6O10

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_435

1187

1188

Magnetic properties of binuclear copper(II) complex with. . .

Structure [Cu2(L)(ClO4)]ClO4; CH3

N NH NH

N

O Cu O

N

(ClO4)

Cu ClO4

N

CH3

H2L ¼ macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis (3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11-tetraazacyclo-tetradecane with 1,2-diaminoethane CH3

N NH NH

N

OH

OH

CH3

N

N

Reference

1189

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.44

ΘP [K] –

Method VSM

Remarks Binuclear

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) χ M data fitted to modified Bleaney-Bowers equation, parameters obtained are: 2J ¼ 172 cm1 g ¼ 2.20

Symbols and Abbreviations Short form T χg χM pm μeff ΘP VSM g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) vibrating-sample magnetometer Lande factor

Reference S. Sreedaran, K.S. Bharathi, A.K. Rahiman, L. Jagadish, V. Kaviyarasan, V. Narayanan, Polyhedron 27, 2931 (2008)

Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand

Substance Binuclear copper(II) complex with macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis(3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11tetraazacyclotetradecane with 1,3-diaminopropane; [Cu2(L)(ClO4)]ClO4

Gross Formula C31H44Cl2Cu2N6O10

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_436

1190

Data

1191

Structure [Cu2(L)(ClO4)]ClO4; CH3

N NH NH

N

O Cu O

N

(ClO4)

Cu ClO4

N

CH3

H2L ¼ macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis (3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11-tetraazacyclo-tetradecane with 1,3-diaminopropane CH3

N NH NH

N

OH

N

OH

N

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.45

ΘP [K] –

Method VSM

Remarks Binuclear

1192

Magnetic properties of binuclear copper(II) complex with. . .

Symbols and Abbreviations Short form T χg VSM χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) vibrating-sample magnetometer magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Sreedaran, K.S. Bharathi, A.K. Rahiman, L. Jagadish, V. Kaviyarasan, V. Narayanan, Polyhedron 27, 2931 (2008)

Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand

Substance Binuclear copper(II) complex with macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis(3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11tetraazacyclotetradecane with 1,4-diaminobutane; [Cu2(L)(ClO4)]ClO4

Gross Formula C32H46Cl2Cu2N6O10

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_437

1193

1194

Magnetic properties of binuclear copper(II) complex with. . .

Structure [Cu2(L)(ClO4)]ClO4; CH3

N NH NH

N

O Cu

N

(ClO4)

Cu O

ClO4

N

CH3

H2L ¼ macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis (3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11-tetraazacyclo-tetradecane with 1,4-diaminobutane CH3

N NH NH

N

OH

N

OH

N

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.31

ΘP [K] –

Method VSM

Remarks Binuclear

Reference

1195

Additional Remarks (i) Temperature dependence of χ M and μeff is shown in Fig. 1 (ii) χ M data analyzed through Bleaney-Bowers equation (iii) Strong antiferromagnetic interactions observed, with: 2 J ¼ 154 cm1 g ¼ 2.20 Fig. 1 [Cu2(L)(ClO4)]ClO4. Temperature dependence of χ M (□) and μeff (●)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP VSM g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) vibrating-sample magnetometer Lande factor

Reference S. Sreedaran, K.S. Bharathi, A.K. Rahiman, L. Jagadish, V. Kaviyarasan, V. Narayanan, Polyhedron 27, 2931 (2008)

Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand

Substance Binuclear copper(II) complex with macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis(3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11tetraazacyclotetradecane with 1,2-diaminobenzene; [Cu2(L)(ClO4)]ClO4

Gross Formula C34H42Cl2Cu2N6O10

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_438

1196

Data

1197

Structure [Cu2(L)(ClO4)]ClO4; CH3

N NH NH

N

O Cu

(ClO4)

Cu O

N

ClO4

N

CH3

H2L ¼ macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis (3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11-tetraazacyclo-tetradecane with 1,2-diaminobenzene CH3

N NH NH

N

OH

N

OH

N

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.47

ΘP [K] –

Method VSM

Remarks Binuclear

1198

Magnetic properties of binuclear copper(II) complex with. . .

Symbols and Abbreviations Short form T χg VSM χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) vibrating-sample magnetometer magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Sreedaran, K.S. Bharathi, A.K. Rahiman, L. Jagadish, V. Kaviyarasan, V. Narayanan, Polyhedron 27, 2931 (2008)

Magnetic properties of binuclear copper(II) complex with macrocyclic dicompartmental ligand

Substance Binuclear copper(II) complex with macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis(3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11tetraazacyclotetradecane with 1,8-diaminonaphthalene; [Cu2(L)(ClO4)]ClO4

Gross Formula C38H44Cl2Cu2N6O10

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_439

1199

1200

Magnetic properties of binuclear copper(II) complex with. . .

Structure [Cu2(L)(ClO4)]ClO4; CH3

N NH NH

N

O Cu

Cu O

N

(ClO4)

ClO4

N

CH3

H2L ¼ macrocyclic Schiff-base obtained by the (in situ) condensation of 1,8-[bis (3-formyl-2-hydorxy-5-methyl)benzyl]-1,4,8,11-tetraazacyclo-tetradecane with 1,8-diaminonaphthalene CH3

N NH NH

N

OH

N

OH

N

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 1.31

ΘP [K] –

Method VSM

Remarks Binuclear

Reference

1201

Additional Remarks (i) Temperature dependence of χ M and μeff is shown in Fig. 1 (ii) χ M data analyzed through Bleaney-Bowers equation (iii) Strong antiferromagnetic interactions observed, with: 2J ¼ 236 cm1 g ¼ 2.20 Fig. 1 [Cu2(L)(ClO4)]ClO4. Temperature dependence of χ M (□) and μeff (●)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP VSM g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) vibrating-sample magnetometer Lande factor

Reference S. Sreedaran, K.S. Bharathi, A.K. Rahiman, L. Jagadish, V. Kaviyarasan, V. Narayanan, Polyhedron 27, 2931 (2008)

Magnetic properties of dinuclear copper(II) complex with 1,2,4-triazolo-[1,5-a] pyrimidine

Substance Dinuclear copper(II) complex with 1,2,4-triazolo-[1,5-a]pyrimidine; [Cu2(OH)(H2O)2.5(tp)5](ClO4)3.1.5H2O

Gross Formula C25H29Cl3Cu2N20O17

Properties Product of molar magnetic susceptibility with temperature, molar magnetic moment and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_440

1202

Symbols and Abbreviations

1203

Structure tp ¼ 1,2,4-triazolo-[1,5-a]pyrimidine N N

[Cu2(OH)(H2O)2.5(tp)5](ClO4)3.1.5H2O;

N

N

Data T [K] RT 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.79 0.19

pm or μeff [μB] 1.81

ΘP [K] 9.424

Method SQUID

Remarks Dinuclear

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) Weak antiferromagnetic interactions indicated

Symbols and Abbreviations Short form T χg χM SQUID pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) superconducting quantum interference device effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

1204

Magnetic properties of dinuclear copper(II) complex. . .

Reference C.R. Maldonado, M. Quiros, J.M. Salas, Polyhedron 27, 2779 (2008)

Magnetic properties of dinuclear copper(II) hydrazido complex ligated by hydrotris(pyrazolyl)borate

Substance Copper(II) hydrazido complex ligated by hydrotris(pyrazolyl)borate; {[Cu(L)]2(μ-NCOOEt)2}

Gross Formula C66H112B2Cu2N16O8

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_441

1205

Magnetic properties of dinuclear copper(II) hydrazido complex ligated. . .

1206

Structure {[Cu(L)]2(μ-NCOOEt)2};

L
¼ hydrotris(3,5-diisopropyl-1-pyrazolyl)borate anion iPr

BH3

N iPr

N

3

Data T [K] RT

χg [10
6 emu/g] –

χM [10
6 emu/mol] –

pm or μeff [μB] 2.15

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Evans

Remarks Coordination geometry around Cu(II) ion is distorted square-pyramidal

Reference

1207

Symbols and Abbreviations Short form T χg χM pm Evans μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule Evans balance effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference K. Fujisawa, M. Sugiyama, Y. Miyashita, K.-I. Okamoto, Inorg. Chem. Commun. 12, 246 (2009)

Magnetic properties of amidocyanamide bridged dinuclear copper(II) complex with picolinic acid

Substance μ1,3-Amidocyanamido(diaquadipilolinato)dicopper(II) dihydrate; [Cu2(pic)2(μ1,3-H2NCO-N-CN)2(H2O)2].2H2O

Gross Formula C16H20Cu2N8O10

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_442

1208

Data

1209

Structure [Cu2(pic)2(μ1,3-H2NCO-N-CN)2(H2O)2].2H2O;

Hpic ¼ picolinic acid OH O

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.90

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Dinuclear, each Cu(II) having distorted squareplanar geometry

1210

Magnetic properties of amidocyanamide bridged dinuclear copper(II). . .

Additional Remarks (i) Temperature dependence of μeff and χ A is shown in Fig. 1 (ii) χ M data analyzed thorugh Bleaney-Bowers equation and yielded: J ¼ 13.6 cm1 g ¼ 2.16 (iii) Weak antiferromagnetic coupling indicated

Fig. 1 [Cu2(pic)2 (μ1,3-H2NCO-N-CN)2 (H2O)2].2H2O. Temperature dependence of χ A and μeff. The solid lines represent the best-fit values as described in the text

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference S.S. Massoud, F.R. Louka, M. Mikuriya, H. Ishida, F.A. Mautner, Inorg. Chem. Commun. 12, 420 (2009)

Magnetic properties of imidazolatobridged homo-dinuclear copper(II) complex with macrocyclic ligand

Substance μ-Imidazolato[3,6,9,16,19,22-hexaaza-6,10-bis(1H-imidazol-4-ylmethyl)tricycle [22,2,2,2]triaconta-1,11,13,24,27,29-hexaene]dicopper(II) perchlorate tetrahydrate; [Cu2L(im)](ClO4)3.4H2O

Gross Formula C35H57Cl3Cu2N12O16

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_443

1211

Magnetic properties of imidazolato-bridged homo-dinuclear copper(II). . .

1212

Structure [Cu2L(im)](ClO4)3.4H2O;

L ¼ macrocyclic ligand derived from N-(2-aminoethyl)-N(1H-imidazol-4-ylmethyl)-ethane-1,2-diamine and trephthaldehyde

HN

NH

N

N

N H

HN

N

im ¼ 1-imidazole

N

NH

HN

NH

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.48

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) having distorted bipyramidal geometry

Reference

1213

Additional Remarks (i) Temperature dependence of χ M and χ MT is shown in Fig. 1 (ii) Magnetic behavior indicated antiferromagnetic interactions (iii) χ M data analyzed through Bleaney-Bowers expression, close fit parameters being: 2J ¼ –109.4 cm–1 g ¼ 2.18 ϱ ¼ 0.009% (molar fraction of paramagnetic impurity) Fig. 1 [Cu2L(im)] (ClO4)3.4H2O. Temperature dependence of χ M and χ MT

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID ϱ g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device molar fraction of paramagnetic impurity Lande factor

Reference Q. Yuan, K. Cai, Z.-P. Qi, Z.-S. Bai, Z. Su, W.-Y. Sun, J. Inorg. Biochem. 103, 1156 (2009)

Magnetic properties of macrocyclic unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy)ethane and 1,8-diaminonaphthalene

Substance Binucler copper(II) complex with macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol, 1,2-bis(aminoxy)ethane and 1,8-diaminonaphthalene; [Cu2L(ClO4)(H2O)]ClO4

Gross Formula C28H26Cl2Cu2N4O13

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_444

1214

Structure

1215

Structure [Cu2L(ClO4)(H2O)]ClO4; CH3

O

O

N N

N (ClO4)

Cu

Cu O

OH2

ClO4

O

N

CH3 H2L ¼ macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy) ethane and 1,8-diaminonaphthalene CH3

O

N

OH

N

O

N

OH

N

CH3

1216

Magnetic properties of macrocyclic unsummetrical binuclear copper(II). . .

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.39/Cu

ΘP [K] –

Method SQUID

Remarks Unsymmetrical binuclear complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference S. Anbu, M. Kandaswamy, P. Suthakaran, V. Murugan, B. Varghese, J. Inorg. Biochem. 103, 401 (2009)

Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy)ethane and 1,2-diaminobenzene

Substance Binucler copper(II) complex with macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol, 1,2-bis(aminoxy)ethane and 1,2-diaminobenzene; [Cu2L(ClO4)(H2O)]ClO4

Gross Formula C24H24Cl2Cu2N4O13

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_445

1217

1218

Magnetic properties of unsummetrical binuclear copper(II) complex. . .

Structure [Cu2L(ClO4)(H2O)]ClO4; CH3

O

O

N N

ClO4

N

Cu

Cu O

OH2

O

(ClO4) N

CH3 H2L ¼ macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy) ethane and 1,4-diaminobenzene CH3

O

N

OH

N

O

N

OH

N

CH3

Reference

1219

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.37/Cu

ΘP [K] –

Method SQUID

Remarks Unsymmetrical binuclear complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference S. Anbu, M. Kandaswamy, P. Suthakaran, V. Murugan, B. Varghese, J. Inorg. Biochem. 103, 401 (2009)

Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy)ethane and 1,4-diaminobutane

Substance Binucler copper(II) complex with macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol, 1,2-bis(aminoxy)ethane and 1,4-diaminobutane; [Cu2L(ClO4)(H2O)]ClO4

Gross Formula C24H30Cl2Cu2N4O13

Properties Molar magnetic susceptibility, molar magnetic moment, exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_446

1220

Structure

1221

Structure [Cu2L(ClO4)(H2O)]ClO4; CH3

O

N

O

N

O

N

Cu

Cu ClO4

OH2

O

(ClO4) N

CH3 H2L ¼ macrocyclic ligand derived from 2,6-diformylphenol-1,2-bis(aminoxy) ethane and 1,4-diaminobutane CH3

O

N

OH

N

O

N

OH

N

CH3

1222

Magnetic properties of unsummetrical binuclear copper(II) complex. . .

Data T [K] 298

χg [106 emu/g] –

χM [103 cm3 mol1] 2.4

pm or μeff [μB] 1.31/Cu

ΘP [K] –

Method SQUID

Remarks Unsymmetrical binuclear complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Magnetic behavior indicated antiferromagnetic coupling (ii) χ M data (298-80 K) were analyzed through Bleaney-Bowers equation (iii) The value of coupling constant being: 2J ¼ 104.4 cm1

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID J

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device exchange energy

Reference S. Anbu, M. Kandaswamy, P. Suthakaran, V. Murugan, B. Varghese, J. Inorg. Biochem. 103, 401 (2009)

Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformyl-4-methylphenol 1,2bis(aminoxy)ethane and propylenediamine

Substance Binucler copper(II) complex with macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol, 1,2-bis(aminoxy)ethane and 1,3-diaminopropane; [Cu2L(ClO4)(H2O)]ClO4

Gross Formula C23H28Cl2Cu2N4O13

Properties Molar magnetic moment, magnetic susceptibility and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_447

1223

Magnetic properties of unsummetrical binuclear copper(II) complex. . .

1224

Structure [Cu2L(ClO4)(H2O)]ClO4; CH3

O

O

N N

ClO4

N

Cu

Cu O

OH2

N

O

CH3 H2L ¼ macrocyclic ligand derived from 2,6-diformyl-4-methylphenol 1,2-bis (aminoxy)ethane and propylenediamine CH3

O

N

OH

N

O

N

OH

N

CH3

Additional Remarks

1225

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] 2400

pm or μeff [μB] 1.30/Cu

ΘP [K] –

Method SQUID

Remarks a) Unsymmetrical binuclear complex b) Cu ion with water ligand has distorted octahedral geometry c) The other Cu ion has squarepyramidal geometry

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks

Fig. 1 [Cu2L(ClO4)(H2O)] ClO4. Temperature dependence of χ M and μeff

3.6

1.4

3.4

1.2

3.2

1.0

3.0 0.8

2.8

0.6

2.6

0.4

2.4 50

100

150

200

250

Temperature T [K]

300

Effective magnetic moment meff [mB]

Temperature dependence of χ M and μeff is shown in Fig. 1 Magnetic behavior indicated antiferromagnetic coupling χ M data (298–80 K) were analyzed through Bleaney-Bowers equation The value of coupling constant being: 2 J ¼ 125.5 cm1 Molar susceptibility cM [cm3 mol-1]

(i) (ii) (iii) (iv)

1226

Magnetic properties of unsummetrical binuclear copper(II) complex. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID J

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device exchange energy

Reference S. Anbu, M. Kandaswamy, P. Suthakaran, V. Murugan, B. Varghese, J. Inorg. Biochem. 103, 401 (2009)

Magnetic properties of unsummetrical binuclear copper(II) complex with macrocyclic ligand derived from 2,6-diformyl-4-methylphenol 1,2bis(aminoxy)ethane and ethylenediamine

Substance Binucler copper(II) complex with macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol, 1,2-bis(aminoxy)ethane and 1,2-diaminoethane; [Cu2L(ClO4)(H2O)]ClO4

Gross Formula C22H26Cl2Cu2N4O13

Properties Molar magnetic moment, magnetic susceptibility and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_448

1227

1228

Magnetic properties of unsummetrical binuclear copper(II) complex. . .

Structure H2L ¼ macrocyclic ligand derived from 2,6-diformyl-4-methylphenol 1,2bis(aminoxy)ethane and ethylenediamine CH3

[Cu2L(ClO4)(H2O)]ClO4; CH3

O

O

N N

ClO4

N

Cu

Cu O

OH2

O

N

O

N

OH

N

O

N

OH

N

CH3 CH3

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] 2300

pm or μeff [μB] 1.28/Cu

ΘP [K] –

Method SQUID

Remarks Unsymmetrical binuclear complex

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Magnetic behavior indicated antiferromagnetic coupling (ii) χ M data (298-80 K) were analyzed through Bleaney-Bowers equation (iii) The value of coupling constant being: 2J ¼ 127.5 cm1

Reference

1229

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID J

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device exchange energy

Reference S. Anbu, M. Kandaswamy, P. Suthakaran, V. Murugan, B. Varghese, J. Inorg. Biochem. 103, 401 (2009)

Magnetic properties of macrocyclic symmetrical binuclear copper(II) complex derived from mononuclear copper(II) complex having macrocyclic ligand

Substance Binucler copper(II) complex with macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol and 1,2-bis(aminoxy)ethane; [Cu2L(H2O)2](ClO4)2

Gross Formula C22H26Cl2Cu2N4O16

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_449

1230

Data

1231

Structure H2L ¼ macrocyclic ligand derived in situ by the reaction of 2,6-diformyl-4-methylphenol and 1,2-bis(aminoxy)ethane)

[Cu2L(H2O)2](ClO4)2; CH3

CH3

O

O

N N

N

O

N

O

Cu

Cu O

OH2

O

OH2

(ClO4)2 O

N

OH

N

O

O

N

OH

N

O

CH3 CH3

Data T [K] 298

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.33/Cu

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, each Cu(II) is squarepyramidal

1232

Magnetic properties of macrocyclic symmetrical binuclear copper(II). . .

Symbols and Abbreviations Short form T SQUID χg χM pm μeff ΘP

Full form temperature superconducting quantum interference device magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Anbu, M. Kandaswamy, P. Suthakaran, V. Murugan, B. Varghese, J. Inorg. Biochem. 103, 401 (2009)

Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand

Substance Tetra-μ-{6-[2(-methoxybenzyl)amino]upurine}dichlorodicopper(II) chloride dihydrate; [Cu2(μ-HL)4Cl2]Cl2.2H2O

Gross Formula C52H56Cl4Cu2N20O6

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_450

1233

Magnetic properties of dinuclear copper(II) complex. . .

1234

Structure [Cu2(μ-HL)4Cl2]Cl2.2H2O; OMe NH HN

N

N Cl N N H

N

Cu

N

OMe

N

Cu

N N H

H N

N

N

N N

H N OMe

N

Cl2.2H2O

Cl

NH NH

MeO

HL ¼ 6-[(2-methoxybenzyl)amino]purine H N OMe

N

N N HN

Data T [K] 300–2

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) in squarepyramidal geometry

Reference

1235

Additional Remarks (i) Temperature dependence of μeff is shown in Fig. 1 (ii) Analysis of χ M data through proper expression gave the resulting J value as: J ¼ 266 cm1 g ¼ 2.2 (fixed) Fig. 1 [Cu2(μ-HL)4Cl2] Cl2.2H2O. Temperature dependence of μeff. The solid line represents best fitting

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand

Substance Tetra-μ-{6-[2(
methoxybenzyl)amino]purine}dicopper(II) chloride dihydrate; [Cu2(μ-HL)4Cl2]Cl2.2H2O (prepared differently)

Gross Formula C52H56Cl4Cu2N20O6

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_451

1236

Symbols and Abbreviations

1237

Structure [Cu2(μ-HL)4Cl2]Cl2.2H2O;

HL ¼ 6-[(2-methoxybenzyl)amino]purine N

H N

N N

OMe

HN

Data T [K] 300–2

χg [10
6 emu/g] –

χM [10
6 emu/mol] –

pm or μeff [μB] –

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) in squarepyramidal geometry

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) Analysis of χ M data yielded the parameters as: J ¼
256 cm
1 g ¼ 2.2 (fixed)

Symbols and Abbreviations Short form T χg χM pm SQUID g μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule superconducting quantum interference device Lande factor effective magnetic moment paramagnetic Curie constant (Weiss constant)

1238

Magnetic properties of dinuclear copper(II) complex. . .

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand

Substance Tetra-μ-{6-[(4-methoxybenzyl)amino]purine}dicopper(II) chloride dihydrate; [Cu2(μ-HL)4Cl2]Cl2.2H2O

Gross Formula C52H56Cl4Cu2N20O6

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_452

1239

Magnetic properties of dinuclear copper(II) complex. . .

1240

Structure [Cu2(μ-HL)4Cl2]Cl2.2H2O; MeO

NH HN N Cl N N H

N

N

N N

MeO

N

Cu

N N H

H N

N

Cu

N

OMe

N

H N Cl2.2H2O

N

Cl

NH NH

OMe

HL ¼ 6-[(4-methoxybenzyl)amino]purine H N MeO

N

N N HN

Data T [K] 300–2

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) in squarepyramidal geometry

Reference

1241

Additional Remark (i) Analysis of χ M data yielded the parameters as: J ¼ 261 cm1 g ¼ 2.2 (fixed)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of dinuclear copper(II) complex containing 6-(benzylamino)purine as bridging ligand

Substance Tetra-μ-{6-[(3,4-dimethoxybenzyl)amino]purine}dicopper(II) chloride dihydrate; [Cu2(μ-HL)4Cl2]Cl2.2H2O

Gross Formula C56H64Cl4Cu2N20O10

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_453

1242

Data

1243

Structure [Cu2(μ-HL)4Cl2]Cl2.2H2O; MeO

OMe

NH HN N Cl N N H

MeO

N

N

N N

MeO

N

Cu

N N H

H N

N

Cu

N

OMe

N

H N

OMe Cl2.2H2O

N

Cl

NH NH

OMe OMe

HL ¼ 6-[(3,4-dimethoxybenzyl)amino]purine MeO MeO

H N

N

N N HN

Data T [K] 300–2

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) in squarepyramidal geometry

1244

Magnetic properties of dinuclear copper(II) complex. . .

Additional Remark (i) Analysis of χ M data yielded the parameters as: J ¼ 269 cm1 g ¼ 2.2 (fixed)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of dinuclear copper(II) complex having chloro and 6-(benzylamino)purine as bridging ligand

Substance Di-μ-chloro-di-μ-{6-[(2-methoxybenzyl)amino]purine}dichlorodicopper(II); [Cu2(μ-HL)2(μ-Cl)2Cl2]

Gross Formula C26H26Cl4Cu2N10O2

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_454

1245

Magnetic properties of dinuclear copper(II) complex having chloro. . .

1246

Structure [Cu2(μ-HL)2(μ-Cl)2Cl2];

HL ¼ 6-[(2-methoxybenzyl)amino]purine H N

OMe NH

N Cl

Cu

N N HN

OMe

NH

N

N

N Cl

N

Cl

Cu

Cl

N N

NH HN MeO

Data T [K] 300–2

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) have trigonalbipyramidal geometry

Reference

1247

Additional Remark (i) Analysis of χ M data yielded the parameters as: J ¼ 78.9 cm1 g ¼ 2.2 (fixed)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of dinuclear copper(II) complex having chloro and 6-(benzylamino)purine as bridging ligand

Substance Di-μ-chloro-di-μ-{6-[(4-methoxybenzyl)amino]purine}dichlorodicopper(II); [Cu2(μ-HL)2(μ-Cl)2Cl2]

Gross Formula C26H26Cl4Cu2N10O2

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_455

1248

Data

1249

Structure [Cu2(μ-HL)2(μ-Cl)2Cl2];

HL ¼ 6-[(4-methoxybenzyl)amino]purine

OMe

H N

N N HN

MeO

NH NH

N N Cl

N

Cu N

N Cl Cl

Cu

Cl

N N

NH HN

OMe

Data T [K] 300–2

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) have trigonal bipyramidal geometry

1250

Magnetic properties of dinuclear copper(II) complex having chloro. . .

Additional Remark (i) Analysis of χ M data yielded the parameters as: J ¼ 114 cm1 g ¼ 2.2 (fixed)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of dinuclear copper(II) complex having chloro and 6-(benzylamino)purine as bridging ligand

Substance Di-μ-chloro-di-μ-{6-[(2,3-dimethoxybenzyl)amino]purine}dichlossrodicopper(II); [Cu2(μ-HL)2(μ-Cl)2Cl2]

Gross Formula C28H30Cl4Cu2N10O4

Properties Exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_456

1251

Magnetic properties of dinuclear copper(II) complex having chloro. . .

1252

Structure [Cu2(μ-HL)2(μ-Cl)2Cl2]; OMe OMe

N

NH

NH

HN

NH

N N Cl

HL ¼ 6-[(2,3-dimethoxybenzyl)amino]purine N N

Cu

N Cl Cl

N

Cu

Cl

MeO

N N

NH

MeO

HN MeO MeO

Data T [K] 300–2

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) have trigonal bipyramidal geometry

Reference

1253

Additional Remark (i) Analysis of χ M data yielded the parameters as: J ¼ 119 cm1 g ¼ 2.2 (fixed)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference P. Starthia, Z. Travnicek, R. Herchel, I. Popa, P. Suchy, J. Vanco, J. Inorg. Biochem. 103, 432 (2009)

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base

Substance Binuclear copper(II) complex with Schiff-base (obtained by the condensation of 7-amino-4-methylcoumarin and 2-hydroxybenzaldehyde); [Cu(L)2]2

Gross Formula C68H48Cu2N4O12

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_457

1254

Data

1255

Structure [Cu(L)2]2; HL ¼ Schiff-base obtained from 7-amino-4-methylcoumarin and 2-hydroxybenzaldehyde

O

O

N

OH

CH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.28/Cu2 1.63/Cu

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method JohnsonMatthey

Remarks Binuclear, coordination geometry around each Cu(II) being intermediate between distorted trigonalbipyramidal and square-pyramidal

1256

Magnetic properties of copper(II) complex with coumarin-derived Schiff-base

Additional Remark (i) Sub-normal value of μeff suggested antiferromagnetic interactions

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference B.S. Creaven, M. Devereux, D. Karcz, A. Kellett, M. McCann, A. Noble, M. Walsh, J. Inorg. Biochem. 103, 1196 (2009)

Magnetic properties of dinuclear copper(II) complex with ‘end-off’ compartmental Schiff-base ligand

Substance Dinuclear copper(II) complex with ‘end-off’ compartmental Schiff-base ligand; [Cu2(L)(μ-Cl)Cl2(H2O)2]

Gross Formula C27H23Cl3Cu2N6O8

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_458

1257

Magnetic properties of dinuclear copper(II) complex with ‘end-off’. . .

1258

Structure [Cu2(L)(μ-Cl)Cl2(H2O)2]; O HN H3C

OH2

H2O

N

O

Cu

Cu

O Cl

Cl Cl

NH N

CH3

O O

O

HL ¼ Schiff-base obtained from 1H-pyrazol-3,5-dicarboxylic hydrazide and 3-acytylcoumarin O O HN H3C

N

NH

NH

N

N O

CH3

O O

O

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.69

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Faraday

Remarks Dinuclear, octahedral geometry around each Cu(II)

Reference

1259

Additional Remark (i) Sub-normal value of μeff indicate weak antiferromagnetic coupling between metal centers

Symbols and Abbreviations Short form T χg Faraday χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) Faraday method magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference S. Budagumpi, V.K. Revankar, Spectrochim. Acta A 77, 184 (2010)

Magnetic properties of mixed ligand binuclear copper(II) complex with 1,10phenanthroline and N,N,N0 ,N0 -tetrakis (2-pyridylmethyl)benzene-1,3-diamine

Substance Mixed ligand binuclear copper(II) complex with 1,10-phenanthroline and N,N,N0 , N0 -tetrakis(2-pyridylmethyl)benzene-1,3-diamine; [Cu2(1,3-tpbd)(phen)2(H2O)2](ClO4)4

Gross Formula C54H48Cl4Cu2N10O18

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_459

1260

Data

1261

Structure [Cu2(1,3-tpbd)(phen)2(H2O)2](ClO4)4;

1,3-tpbd ¼ N,N,N,'N0 -tetrakis(2-pyridylmethyl)benzene-1,3-diamine N

N

N

N

N

N

phen ¼ 1,10-phenanthroline

N

N

Data T [K] 300 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.913 0.86257

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, both Cu(II) exhibit octahedral environment

1262

Magnetic properties of mixed ligand binuclear copper(II) complex. . .

Additional Remarks (i) χ M and χ MT versus T plots are shown in Fig. 1 (ii) Existence of antiferromagnetic interactions indicated (iii) The magnetic susceptibility was fitted according to the expressions (1)–(3): 1 2

ð1Þ

2Ng 2 β2 1  kT 3 þ e2J=kT

ð2Þ

χM 1  2zj0 =Ng2 β2 χ M

ð3Þ

H ¼ 2JS 1 :S2 S1 ¼ S2 ¼ χM ¼

χ chain ¼

where J ¼ exchange coupling parameter between S1 and S2 zJ ¼ interdimer exchange interaction parameter (iv) The best-fit parameters being: J ¼ 0.068 cm1 g ¼ 2.13 Fig. 1 [Cu2(1,3-tpbd) (phen)2(H2O)2](ClO4)4. Temperature dependence of χ M (Δ) and χ MT (◊)

Reference

1263

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference D.D. Li, F.-P. Huang, G.-J. Chen, C.-Y. Gao, J.-L. Tian, W. Gu, X. Liu, S.-P. Yan, J. Inorg. Biochem. 104, 431 (2010)

Magnetic properties of chloro-bridged binuclear copper(II) complex with N,N,N0 , N0 -tetrakis(2-pyridylmethyl)benzene-1,3diamine

Substance Chloro-bridged binuclear copper(II) complex with N,N,N0 ,N0 -tetrakis (2-pyridylmethyl)benzene-1,3-diamine; {Cu2(1,3-tpbd)(μ-Cl)2](ClO4)2(H2O)4.5(NaClO4)}1

Gross Formula C30H29Cl5Cu2N6NaO16.5

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_460

1264

Data

1265

Structure {Cu2(1,3-tpbd)(μ-Cl)2](ClO4)2(H2O)4.5(NaClO4)}1;

1,3-tpbd ¼ N,N,N,'N0 -tetrakis(2-pyridyl-methyl)benzene-1,3-diamine N

N

N

N

N

N

Data T [K] 300 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.811 0.05766

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks One-dimensional chain structure, each Cu(II) being in square pyramidal environment

1266

Magnetic properties of chloro-bridged binuclear copper(II) complex. . .

Additional Remarks (i) χ M and χ MT versus T plots are shown in Fig. 1 (ii) Existence of antiferromagnetic interactions indicated (iii) The magnetic susceptibility was fitted according to the expressions (1)–(3): 1 2

ð1Þ

2Ng 2 β2 1  kT 3 þ e2J=kT

ð2Þ

χM 1  2zj0 =Ng2 β2 χM

ð3Þ

H ¼ 2JS 1 :S2 S1 ¼ S2 ¼ χM ¼

χchain ¼

where J ¼ exchange coupling parameter between S1 and S2 zJ ¼ interdimer exchange interaction parameter (iv) The best-fit parameters being: J ¼ 2.76 cm1 g ¼ 2.11 zJ ¼ 0.26 cm1 Fig. 1 {Cu2(1,3-tpbd) (μ-Cl)2](ClO4)2(H2O)4. 5(NaClO4)}1. Temperature dependence of χ M (Δ) and χ MT (◊)

Reference

1267

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

Reference D.D. Li, F.-P. Huang, G.-J. Chen, C.-Y. Gao, J.-L. Tian, W. Gu, X. Liu, S.-P. Yan, J. Inorg. Biochem. 104, 431 (2010)

Magnetic properties of binuclear copper(II) complex with 1,2,4-triazole based ligand

Substance Binuclear copper(II) complex with 1,2,4-triazole based ligand; [Cu2(L)(μ-SO4)] (PF6)2

Gross Formula C28H30Cu2F12N10O4P2S

Properties Product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_461

1268

Data

1269

Structure [Cu2(L)(μ-SO4)](PF6)2;

L ¼ 3,5-bis[{(bis(pyridine-2-yl-methyl)amino)methyl}-4H-1,2,4-triazol-4-amine NH2 N N

N

H2 C

H2 C

N N

N

N

N N

Data T [K] 300 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.93 0.77

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 3.2

Method SQUID

Remarks Binuclear, distorted trigonalbipyramidal geometry around both Cu(II)

1270

Magnetic properties of binuclear copper(II) complex with 1,2,4-triazole. . .

Additional Remarks (i) Temperature dependence of χ MT and χ M1 is shown in Fig. 1 (ii) >28 K Curie-Weiss law obeyed, with: C ¼ 1.05 cm3 K mol1 θ ¼ 3.2 K (iii) χ M data analyzed through Bleaney-Bowers equation; best-fit parameters, being J ¼ 3.0 cm1 g ¼ 2.3 Fig. 1 [Cu2(L)(μ-SO4)] (PF6)2. Temperature dependence of χ MT (◊) and χ M1 (○). The solid lines represent the theoretical values

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID χ M1 g θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device inverse molar susceptibility Lande factor Curie constant Curie temperature

Reference D.-D. Li, J.-L. Tian, W. Gu, X. Liu, S.-P. Yan, J. Inorg. Biochem. 104, 171 (2010)

Magnetic properties of dinuclear copper(II) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine

Substance Dinuclear copper(II) complex with Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine; [Cu2(L)(NO3)2]

Gross Formula C18H30Cu2N8O8

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_462

1271

Magnetic properties of dinuclear copper(II) complex with Schiff-base. . .

1272

Structure [Cu2(L)(NO3)2]; CH3

CH3 N

N HN N H2

Cu O

O

O O

Cu

N

N

O

O

NH N H2

O O H2L ¼ Schiff-base derived from 4,6-diacetylresorcinol and diethylenetriamine CH3 CH3

N

N HN

OH

NH

OH

N H2

N H2

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.68/mol 1.81/Cu

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks Octahedral

Reference

1273

Symbols and Abbreviations Short form T χg χM pm μeff Gouy ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Gouy method or Pascal method paramagnetic Curie constant (Weiss constant)

Reference A.A.A. Emara, Spectrochim. Acta A 77, 117 (2010)

Magnetic properties of dinuclear copper(II) complex with 1,10-phenanthroline as 4,6-dimethyl-1,2,3-triazolo[4,5-d] pyrimidin-5,7-dionato salt

Substance Di-μ-hydroxo(diaqua)-bis(1,10-phenanthroline)dicopper(II) 4,6,-dimethyl1,2,-triazolo[4,5-d]pyrimidin-5,7-dione decahydrate; [Cu2(OH)2(H2O)2(phen2)](dmax)2.10H2O

Gross Formula C36H54Cu2N14O18

Properties Molar magnetic moment and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_463

1274

Data

1275

Structure [Cu2(OH)2(H2O)2(phen2)](dmax)2.10H2O;

phen ¼ 1,10-phenanthroline;

N

N

Hdmax ¼ 4,6,-dimethyl1,2,3-triazolo[4,5-d] pyrimidin-5,7-dione O H3C N N

O HN

N

CH3

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.10

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 2.60

Method Faraday

Remarks High-spin distorted octahedral configuration

1276

Magnetic properties of dinuclear copper(II) complex. . .

Symbols and Abbreviations Short form Faraday T χg χM pm μeff ΘP

Full form Faraday method temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference C.R. Maldonado, M. Quiros, J.M. Salos, Inorg. Chem. Commun. 13, 399 (2010)

Magnetic properties of dinuclear mixed ligand copper(II) complex with diester and dinitrogen base ligands

Substance Aqua-bis(ethylacetoacetato)dinitrato)-bis(1,10-phenanthroline)dicopper(II) monohydrate; [Cu2(eaa)2(phen)2(NO3)2(H2O)].H2O

Gross Formula C36H38Cu2N6O14

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_464

1277

Magnetic properties of dinuclear mixed ligand copper(II) complex. . .

1278

Structure [Cu2(eaa)2(phen)2(NO3)2(H2O)].H2O;

Heaa ¼ ethylacetoacetate; H3C C

O

C

O

H2C C2H5O phen ¼ 1,10-phenanthroline

N

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 3.07/Cu

ΘP [K] –

Method Johnson Matthey

Remarks Dinuclear, octahedral geometry around each Cu(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference

1279

Reference A.A.A. Emara, A.A.A. Abu-Hussein, A.A. Taha, N.H. Mahmoud, Spectrochim. Acta A 77, 594 (2010)

Magnetic properties of dinuclear mixed ligand copper(II) complex with diester and dinitrogen base ligands

Substance Aqaua-bis(diethylmalonato)dinitrato-bis(1,10-phenantholine)dicopper(II); [Cu2(dem)2(phen)2(NO3)2(H2O)]

Gross Formula C38H44Cu2N6O15

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_465

1280

Reference

1281

Structure Hdem ¼ diethylmalonate; C2H5O

[Cu2(dem)2(phen)2(NO3)2(H2O)];

C

O

C

O

H2C C2H5O phen ¼ 1,10-phenanthroline

N

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.43/Cu

ΘP [K] –

Method Johnson Matthey

Remarks Octahedral geometry around each Cu(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Johnson Matthey

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Johnson Matthey balance

Reference A.A.A. Emara, A.A.A. Abu-Hussein, A.A. Taha, N.H. Mahmoud, Spectrochim. Acta A 77, 594 (2010)

Magnetic properties of dinuclear copper(II) complex with tetra [(1-hydroxyiminomethylnaphthalen2-yloxy)methyl)]ethene

Substance Dinuclear copper(II) complex with tetra[{1-hydroxyiminemethylnaphthalen2-yloxy)methyl)]ethene; [Cu2(H2L)(ClO4)2]

Gross Formula C50H38Cl2Cu2N4O16

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_466

1282

Structure

1283

Structure [Cu2(H2L)(ClO4)2];

ClO4

O

O H

O

Cu N

N

H O

O

O N

Cu

O

N

ClO4

O

H4L ¼ acyclic tetraoxime ligand ¼ tetra(1-hydroxyiminomethyl-naphthalen2-yloxy)methyl)]ethene

HO N O HO N

O

O

N OH O

N

OH

Magnetic properties of dinuclear copper(II) complex. . .

1284

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.98

ΘP [K] –

Method –

Remarks Square-pyramidal geometry around each Cu(II)

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference K. Serbest, K. Karaoglu, M. Erman, M. Er, I. Degirmencioglu, Spectrochim. Acta A 77, 643 (2010)

Magnetic properties of binuclear copper(II) complex with binucleating Schiff-base ligand with a phenylene spaer

Substance Binuclear copper(II) complex with binucleating Schiff-base ligand with a phenylene spaer; [Cu2(L)].3H2O

Gross Formula C16H24Cu2N4O9

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_467

1285

1286

Magnetic properties of binuclear copper(II) complex with. . .

Structure [Cu2(L)].3H2O;

H2L ¼ Schiff-base ligand obtained from glycyl-glycine and o-phthaladehyde

HC N

NH O

O

CH N

O

HN HO

OH

O

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.58

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Gouy

Remarks Square-planar geometry around each Cu(II)

Reference

1287

Additional Remark (i) Antiferromagnetic interactions indicated

Symbols and Abbreviations Short form T χg χM Gouy pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) Gouy method or Pascal method effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference B. Geeta, K. Shravankumar, P.M. Reddy, E. Ravikrishna, M. Sarangapani, K.K. Reddy, V. Ravinder, Spectrochim. Acta A 77, 911 (2010)

Magnetic properties of imidazolatebridged hetero-dinuclear copper(II)-zinc(II) complex with macrocyclic ligand

Substance μ-Imidazolato[3,6,9,16,19,22-hexaaza-6,19-bis(1H-imidazol-4-ylmethyl)tricycle [22,2,2,2]triaconta-1,11,13,24,27,29-hexaene]copper(II)-zinc(II) perchlorate tetrahydrate; [CuZnL(im)](ClO4)3.4H2O

Gross Formula C35H57Cl3CuN12O16Zn

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_468

1288

Data

1289

Structure [CuZnL(im)](ClO4)3.4H2O;

L ¼ macrocyclic ligand derived from N-(2-aminoethyl)N-(1H-imidazol-4-ylmethyl)-ethane-1,2-diamine and trephthaldehyde

HN

NH

N

N

N H

HN

N

im ¼ 1-imidazole

N

NH

HN

NH

N

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.70

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Binuclear, coordination geometry around each metal centre being distorted trigonal-bipyramidal

1290

Magnetic properties of imidazolate-bridged hetero-dinuclear. . .

Additional Remark (i) χ M data in agreement with one spin system

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference Q. Yuan, K. Cai, Z.-P. Qi, Z.-S. Bai, Z. Su, W.-Y. Sun, J. Inorg. Biochem. 103, 1156 (2009)

Magnetic properties of copper(II) complex with pyrimidine derived Schiff-base ligand

Substance Dinitratotricopper(II) complex with 2-S-methyl-6-methyl-4-formyl pyrimidineN(4)-ethylthiosemicarbazone, co-crystallizing with its mononuclear analogue; [Cu2(L)2(NO3)2][Cu(L)(NO3)]

Gross Formula C30H42Cu3N18O9S6

Properties Product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_469

1291

Magnetic properties of copper(II) complex with pyrimidine. . .

1292

Structure [Cu2(L)2(NO3)2][Cu(L)(NO3)]; N N

Cu

N

O3N S H3 C S HN N CH2CH3

CH2CH3

N

NH S CH3 S NO3 N Cu N

N N H3 C

N

N

N

Cu

S

CH2CH3 H N

NO3

S

HL ¼ 2-S-methyl-6-methyl-4-formyl pyrimidine-N(4)-ethylthiosemicarbazone CH3

H

N H3CS

N H

N

H N

N C2H5 S

Data T [K] RT 7.3 2.0

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 0.860 0.962 0.833

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.78

Method SQUID

Remarks Square-pyramidal (binuclear species) and square-planar mononuclear species

Reference

1293

Fig. 1 [Cu2(L)2(NO3)2] [Cu(L)(NO3)2]. Temperature dependence of χ MT. The solid line represents the best-fit curve

Additional Remarks (i) Plot of χ MT versus T is shown in Fig. 1 (ii) Magnetic behavior indicated ferromagnetic coupling (iii) χ M data analyzed by Curie-Weiss and Bleaney-Bowers expressions, best-fit parameters being: J ¼ +7.6 cm1 Θ ¼ 0.78 K g ¼ 2.14

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie temperature

Reference S. Gupta, S. Pal, A.K. Barik, A. Hazra, S. Roy, T.N. Mandal, S.-M. Peng, G.-H. Lee, M.S. El-Fallah, J. Tercero, S.K. Kar, Polyhedron 27, 2519 (2008)

Magnetic properties of m-hydroxom-propionato bridged trinuclear copper(II) complex with N-(pyrid-2-ylmethyl) benzenesulfonylamide

Substance μ-Hydroxo-μ-propionato bridged trinuclear copper(II) complex with N-(pyrid2-ylmethyl)benzenesulfonylamide; [Cu3(μ-OH)2(μ-propionato)2(L)2]

Gross Formula C30H34Cu3N4O10S2

Properties Product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_470

1294

Data

1295

Structure [Cu3(μ-OH)2(μ-propionato)2(L)2];

HL ¼ N-(pyrid-2-ylmethyl) benzenesulfonylamide N NH O

S O

Data T [K] RT 15 2.0

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 1.6 2.3 2.2

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.15

Method SQUID

Remarks (a) Polymeric compound consisting of trinuclear units (b) Terminal Cu(II) ions have a distorted squarepyramidal geometry (c) Central Cu(II) has a regular square-planar geometry

1296

Magnetic properties of m-hydroxo-m-propionato bridged trinuclear. . .

Additional Remarks (i) Magnetic behavior indicated ferromagnetic coupling (ii) χ M data analyzed as that of a single linear trinuclear copper(II) unit (iii) The results of typical fits are: J ¼ 76 cm1 g ¼ 2.16 θ ¼ 0.15 K

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie temperature

Reference J.L. Garcia-Gimenez, G. Alzuet, M. Gonzalez-Alvarez, M. Liu-Gonzalez, A. Castineiras, J. Borras, J. Inorg. Biochem. 103, 243 (2009)

Magnetic properties of m-hydroxom-propionato bridged trinuclear copper(II) complex with N-(pyrid-2-ylmethyl)p-toluenesulfonylamide

Substance μ-Hydroxo-μ-propionato bridged trinuclear copper(II) complex with N-(pyrid2-ylmethyl)-p-toluenesulfonyl-amide; [Cu3(μ-OH)2(μ-propionato)2(L)2(dmf)2]

Gross Formula C38H52Cu3N6O12S2

Properties Product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_471

1297

Magnetic properties of m-hydroxo-m-propionato bridged trinuclear. . .

1298

Structure [Cu3(μ-OH)2(μ-propionato)2(L)2(dmf)2];

HL ¼ N-(pyrid-2-ylmethyl)-p-tolenesulfonylamide;

dmf ¼ dimethylformamide H3C O N

N

H3C

C

H

NH O

S

CH3

O

Data T [K] RT 15 2.0

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 1.4 2.1 2.0

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.012

Method SQUID

Remarks Trinuclear, terminal Cu(II) ions have a distorted squarepyramidal geometry, while central Cu(II) is with distorted octahedral geometry

Reference

1299

Additional Remarks (i) Magnetic behavior indicated ferromagnetic coupling (ii) χ M data analyzed as that of a single linear trinuclear copper(II) unit (iii) The results of typical fits are: J ¼ 54 cm1 g ¼ 2.12 θ ¼ 0.012 K

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie temperature

Reference J.L. Garcia-Gimenez, G. Alzuet, M. Gonzalez-Alvarez, M. Liu-Gonzalez, A. Castineiras, J. Borras, J. Inorg. Biochem. 103, 243 (2009)

Magnetic properties of m-hydroxom-propionato bridged trinuclear copper(II) complex with N-(pyrid-2-ylmethyl) naphthalenesulfonylamide

Substance μ-Hydroxo-μ-propionato bridged trinuclear copper(II) complex with N-(pyrid2-ylmethyl)naphthalenesulfonyl-amide; [Cu3(μ-OH)2(μ-propionato)2(L)2(dmf)2]

Gross Formula C41H43Cu3N5O11S2

Properties Product of molar magnetic susceptibility with temperature, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_472

1300

Data

1301

Structure [Cu3(μ-OH)2(μ-propionato)2(L)2(dmf)2];

HL ¼ N-(pyrid-2-ylmethyl) naphthalene-sulfonylamide; N NH O

S O

dmf ¼ dimethylformamide H3C O N

C

H3C

H

Data T [K] RT 15 2.0

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 1.3 1.9 1.6

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] 0.59

Method SQUID

Remarks (a) Crystal structure consists of two different trinuclear entities (b) Central Cu(II) ion presents a regular squareplanar geometry (c) The terminal Cu(II) ions present a distorted squarepyramidal geometry

Magnetic properties of m-hydroxo-m-propionato. . .

1302

Additional Remarks (i) (ii) (iii) (iv)

Temperature dependence of χ MT is shown in Fig. 1 Magnetic behavior indicated ferromagnetic coupling χ M data analyzed as that of a single linear trinuclear copper(II) unit the results of typical fits are: J ¼ 48 cm1 g ¼ 2.09 θ ¼ 0.59 K

Fig. 1 [Cu3(μ-OH)2 (μ-propionato)2(L)2(dmf)2]. Temperature dependence of χ MT. The solid line represents the fitted function

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor Curie temperature

Reference J.L. Garcia-Gimenez, G. Alzuet, M. Gonzalez-Alvarez, M. Liu-Gonzalez, A. Castineiras, J. Borras, J. Inorg. Biochem. 103, 243 (2009)

Magnetic properties of trinuclear copper(II) complex with 1,5-bis(di-2-pyridylketone) carbohydrazone

Substance Trinuclear copper(II) complex with 1,5-bis(di-2-pyridylketone)carbohydrazone; [Cu3(HL)Cl2]Cl3.2H2O

Gross Formula C23H21Cl5Cu3N8O3

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_473

1303

Magnetic properties of trinuclear copper(II) complex with 1,5-bis(di. . .

1304

Structure [Cu3(HL)Cl2]Cl3.2H2O; N N N

N

Cu NH

N O

Cu

Cl3.2H2O

N N

Cu

Cl Cl H2L ¼ 1,5-bis(di-2-pyridylketone)carbohydrazone N

N N N

H N

NH

N

OH

N

Data T [K] RT 5.0

χg [106 emu/g] – –

χM [106 emu/mol] – –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] 2.19 0.31

ΘP [K] –

Method –

Remarks Trinuclear

Reference

1305

Additional Remark (i) Strong antiferromagnetic interactions between Cu(II) centers

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference E. Manoj, M.R. Kurup, R.P. John, M. Nethaji, A. Punnoose, Inorg. Chem. Commun. 12, 952 (2009)

Magnetic properties of copper(II) complex formed by one pot reaction of 2,6-pyridinedicarboxylic acid and ethylenediamine with metal ion

Substance Ethylenediammonium-diaqua-bis(ethylenediamine)copper(II) di[bis(2,6-pyridinedicarboxylato]cuprate(II) dihydrate; [enH2][Cu(en)2(H2O)2][Cu(L)2]2.2H2O

Gross Formula C26H46Cu3N10O20

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_474

1306

Reference

1307

Structure [enH2][Cu(en)2(H2O)2][Cu(L)2]2.2H2O; NH3 2+ NH3

H2O H 2 H2 N N Cu N N H H2 OH2 2

2+

O O O Cu N O O

O

N O

O

en ¼ ethylenediammonium

2H2O 2

H2L ¼ 2,6-pyridinedicarboxylic acid OH OH N O O

NH3 NH3

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.65

ΘP [K] –

Method –

Remarks Cu(II) being hexacoordinated in cation as well as in anion

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference B. Das, J.B. Baruah, Inorg. Chem. Commun. 13, 350 (2010)

Magnetic properties of tetranuclear pyrophosphate bridged copper(II) complex with 2,20 -dipyridylamine

Substance Tetranuclear pyrophosphate bridged copper(II) complex with 2,20 -dipyridylamine; [Cu4(hdpa)4(μ-P2O7)2].11H2O

Gross Formula C40H58Cu4N12O25P4

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_475

1308

Data

1309

Structure [Cu4(hdpa)4(μ-P2O7)2].11H2O;

hdpa ¼ 2,20 -pyridylamine

N

N H

N

Data T [K] RT 22 95

χg [106 emu/g] – – –

χM [106 emu/mol] – – 8.6  103

pm or μeff [μB] 3.27 0.68

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 3D network

1310

Magnetic properties of tetranuclear pyrophosphate bridged copper(II). . .

Additional Remarks (i) Plots of χ M versus T and μeff versus T are shown in Fig. 1 (ii) Magnetic behavior shows dominant antiferromagnetic interaction (iii) Least-squares fitting leads to the following parameters: J12 ¼ 18.92 cm1 J13 ¼ 45.93 cm1 J14 ¼ 23.21 cm1 g ¼ 2.08 Fig. 1 [Cu4(hdpa)4 (μ-P2O7)2].11H2O. Temperature dependence of χ M and μeff. The solid lines represent the best-fit curve

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference J.-Y. Xu, J.-L. Tian, Q.-W. Zhang, J. Zhao, S.-P. Yan, D.-Z. Liao, Inorg. Chem. Commun. 11, 69 (2008)

Magnetic properties of tetranuclear copper(II) acetato complex with pyrazol3-yl-substituted nitronyl nitroxide

Substance Tetranuclear copper(II) acetato complex with pyrazol-3-yl-substituted nitronyl nitroxide; [Cu4(OH)2(OAc)4(dmf)2(L)2]

Gross Formula C34H56Cu4N10O16

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_476

1311

1312

Magnetic properties of tetranuclear copper(II) acetato complex. . .

Structure [Cu4(OH)2(OAc)4(dmf)2(L)2];

HL ¼ pyrazol-3-yl-substituted nitronyl nitroxide O N H N

N

O

NH

dmf ¼ dimethylformamide H3C O N

H3C

C

H

Data T [K] 100–2.0

χg [106 emu/g] –

χM [106 emu/mol] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

pm or μeff [μB] ~2.41

ΘP [K] –

Method SQUID

Remarks Tetranuclear

Reference

1313

Additional Remarks (i) Temperature dependence of μeff is shown in Fig. 1 (ii) Effective values of exchange interactions are: JCuCu ¼ 938 cm1 JRCu ¼ 60 cm1 J’CuCu ¼ ~11 cm1 gCu ¼ ~2.0 Fig. 1 [Cu4(OH)2(OAc)4 (dmf)2(L)2]. Temperature dependence of μeff

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference E.V. Tretyakov, S.E. Tolstikov, E.V. Gorelik, M.V. Fedin, G.V. Romansenko, A.-S. Bogomyakov, V.I. Ovcharenko, Polyhedron 27, 739 (2008)

Magnetic properties of phenoxo-bridged tetranuclear copper(II) complex having 2-hydroxy-N-(2-pyridylmethyl)benzamide

Substance Phenoxo-bridged tetranuclear copper(II) complex having 2-hydroxyN-(2-pyridylmethyl)benzamide; [Cu4(L)4]

Gross Formula C52H40Cu4N8O8

Properties Molar magnetic moment

Structure [Cu4(L)4];

HL ¼ 2-hydroxy-N-(2-pyridylmethyl)benzamide

N

H N O

OH

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_477

1314

Reference

1315

Data T [K] –

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.83/Cu

ΘP [K] –

Method Evans

Remarks Tetranucler Cu(II) cluster with a distorted cubane structure, each Cu(II) centre having squareplanar geometry

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Evans

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Evans balance

Reference Z. Wang, D.R. Powell, R.P. Houser, Inorg. Chem. Commun. 12, 511 (2009)

Magnetic properties of heterotetranuclear Cu3Mn complex with N,N0 -o-phenylenebis(3-ethoxysalicylaldimine)

Substance Heterotetranuclear Cu3Mn complex with N,N0 -o-phenylenebis(3-ethoxysalicylaldimine); {[CuLMn(H2O)3][CuL]2}(ClO4)2.H2O.CH3COCH3

Gross Formula C75H80Cl2Cu3MnN6O25

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_478

1316

Data

1317

Structure {[CuLMn(H2O)3][CuL]2}(ClO4)2.H2O.CH3COCH3; H2L ¼ N,N0 -o-phenylenebis(3-ethoxysalicylaldimine)

O N

OH

N

OH O

Data T [K] 300 22–10 2.0

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 5.52 3.95 3.62

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Tetranuclear

1318

Magnetic properties of heterotetranuclear Cu3Mn complex. . .

Additional Remarks (i) χ M and χ MT versus T plot is shown in Fig. 1 (ii) lest-squares fitting of the χ M data through proper equation leads to: J ¼ 15.9 cm1 zJ’ ¼ 0.032 cm1 (interdimer exchange interaction parameter) g ¼ 2.086 Fig. 1 {[CuLMn(H2O)3] [CuL]2}(ClO4)2.H2O. CH3COCH3. Temperature dependence of χ M (●) and χ MT (▼). The solid lines represent the stimulated curves

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

Reference M. Nayak, S. Hazra, P. Lemoine, R. Koner, C.R. Lucas, S. Mohanta, Polyhedron 27, 1201 (2008)

Magnetic properties of heterotetranuclear Cu3Co complex with N,N0 -o-phenylenebis(3-ethoxysalicylaldimine)

Substance Heterotetranuclear Cu3Co complex with N,N0 -o-phenylenebis(3-ethoxysalicylaldimine); {[CuLCo(H2O)3][CuL]2}(ClO4)2.H2O.CH3COCH3

Gross Formula C75H80Cl2CoCu3N6O25

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_479

1319

1320

Magnetic properties of heterotetranuclear Cu3Co complex. . .

Structure {[CuLCo(H2O)3][CuL]2}(ClO4)2.H2O.CH3COCH3; H2L ¼ N,N0 -o-phenylenebis(3-ethoxysalicylaldimine)

O N

OH

N

OH O

Data T [K] 300 90 2.0

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 3.77 3.12 1.03

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Tetranuclear

Reference

1321

Additional Remarks (i) χ M and χ MT versus T plot is shown in Fig. 1 (ii) lest-squares fitting of the χ M data through proper equation leads to: J ¼ 15.8 cm1 zJ’ ¼ 1.09 cm1 (interdimer exchange interaction parameter) g ¼ 2.416 Fig. 1 {[CuLCo(H2O)3] [CuL]2}(ClO4)2.H2O. CH3COCH3. Temperature dependence of χ M (●) and χ MT (▼). The solid lines represent the stimulated curves

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

Reference M. Nayak, S. Hazra, P. Lemoine, R. Koner, C.R. Lucas, S. Mohanta, Polyhedron 27, 1201 (2008)

Magnetic properties of ion-pair complex containing substituted pentadecanecopper(II) cation and hexacyanoferrate anion

Substance Tris[(6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane)copper(II)] bis(hexacyanoferrate(III)) octahydrate; [Cu(L)]3[Fe(CN)6]2.8H2O

Gross Formula C51H97Cu3Fe2N27O14

Properties Molar magnetic moment and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_480

1322

Data

1323

Structure [Cu(L)]3[Fe(CN)6]2.8H2O;

L ¼ 6,13-dimethyl-6-nitro-1,4,8,11-tetraazabicyclo[11.1.1]pentadecane NH H3C

NH

CH2 N

NH

NO2 CH3

Data T [K] RT 3 K, Curie-Weiss law obeyed, with θ ¼ 1.12 K (iii) Weak ferromagnetic interactions indicated between Cu(II) and low-spin Fe(III) Fig. 1 [Cu(L)]3 [Fe(CN)6]2.8H2O. Temperature dependence of μeff and χ M

Symbols and Abbreviations Short form T χg χM pm μeff ΘP χ M1 C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) inverse molar susceptibility Curie temperature

Reference M.J. Cha, J.W. Shin, Y.H. Lee, Y. Kim, B.G. Kim, K.S. Min, Inorg. Chem. Commun. 12, 520 (2009)

Magnetic properties of hexanuclear copper(II) carboxylate complex with 2,20 -bipyridine

Substance Hexanuclear copper(II) propionato complex with 2,20 -bipyridine; [Cu6(bipy)6(μ-O2C.C2H5)7(H2O)2](PF6)5.2H2O

Gross Formula C81H91Cu6F30N12O18P5

Properties Product of molar magnetic susceptibility with temperature

Structure [Cu6(bipy)6(μ-O2C.C2H5)7(H2O)2](PF6)5.2H2O;

bipy ¼ 2,20 -bipyridine N N

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_481

1325

1326

Magnetic properties of hexanuclear copper(II) carboxylate complex. . .

Data T [K] 350 5.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.360 0.005

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Plot of χ MT versus T is shown in Fig. 1 (ii) Antiferromagnetic interactions indicated Fig. 1 [Cu6(bipy)6(μ-O2C. C2H5)7(H2O)2](PF6)5.2H2O. Temperature dependence of χ MT

ΘP [K] –

Method SQUID

Remarks Hexanuclear chain molecule

Reference

1327

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device

Reference J. Boonmak, S. Youngme, T. Chotkhun, C. Engkagul, N. Chaichit, G.A. van Albada, J. Reedijk, Inorg. Chem. Commun. 11, 1231 (2008)

Magnetic properties of heptanuclear CuII7 complex with N,N0 -o-phenylene-bis (3-ethoxysalicylaldimine)

Substance Heptanuclear CuII7 complex with N,N0 -o-phenylenebis(3-ethoxysalicylaldimine); {[CuLCu(H2O)3]2[CuL]3}(ClO4)4.2CH3COCH3

Gross Formula C126H134Cl4Cu7N10O44

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_482

1328

Data

1329

Structure {[CuLCu(H2O)3]2[CuL]3}(ClO4)4.2CH3COCH3;

H2L ¼ N,N0 -o-phenylenebis(3-ethoxysalicylaldimine)

O N

OH

N

OH O

Data T [K] 300 80 8–6

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 2.76 2.43 1.13

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Heptanuclear

1330

Magnetic properties of heptanuclear CuII7 complex with N,N0 -o. . .

Additional Remarks (i) Plot of χ M and χ MT versus T is shown in Fig. 1 (ii) lest-squares fitting of the χ M data through proper equation leads to: J ¼ 22.2 cm1 zJ 0 ¼ 0.12 cm1 (interdimer exchange interaction parameter) g ¼ 2.146

Fig. 1 {[CuLCu (H2O)3]2[CuL]3} (ClO4)4.2CH3COCH3. Temperature dependence of χM (●) and χMT (▼). The solid lines represent the stimulated curves

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ 0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

Reference M. Nayak, S. Hazra, P. Lemoine, R. Koner, C.R. Lucas, S. Mohanta, Polyhedron 27, 1201 (2008)

Magnetic properties of carbonato and hydroxide bridged octanuclear copper(II) complex with 1,10-phenanthroline

Substance Carbonato and hydroxide bridged octanuclear copper(II) complex with 1,10-phenanthroline; [Cu8(phen)12(μ-OH)(μ-CO3)2](CF3SO3)8.2dmf.0.5H2O

Gross Formula C157H100Cu8N25O35.5F24S8

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_483

1331

Magnetic properties of carbonato and hydroxide bridged. . .

1332

Structure [Cu8(phen)12(μ-OH)(μ-CO3)2](CF3SO3)8.2dmf.0.5H2O; phen ¼ 1, 10-phenanthroline; dmf ¼ dimethylformamide H3C O N C H H 3C N N

Data T [K] 300 5.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.355 0.556

pm or μeff [μB] –

ΘP [K] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Plot of χ MT versus T is shown in Fig. 1 (ii) Strong ferromagnetic exchange coupling observed, with: J(μ-OH) ¼ +154 cm1 and +135 cm1

Fig. 1 [Cu8(phen)12(μ-OH) (μ-CO3)2](CF3SO3)8. 2dmf.0.5H2O. Temperature dependence of χ MT

Method –

Remarks octanuclear

Reference

1333

Symbols and Abbreviations Short form T χg χM pm μeff ΘP J

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) exchange energy

Reference S. Youngme, N. Wannarit, T. Remsungnen, C. Pakawatchai, N. Chaichit, C. Engkagul, G.A. Van Albada, J. Reedijk, Inorg. Chem. Commun. 11, 427 (2008)

Magnetic properties of paradodecatungstate derivative of trinuclear copper(II) azido complex with 2-pyrazine carboxylic acid

Substance Paradodecatungstate derivative of trinuclear copper(II) azido complex with 2-pyrazine carboxylic acid; H4{[Cu3(HL)2(H2O)4](H2W12O42)}.13H2O

Gross Formula C10H48Cu3N4O63W12

Properties Molar magnetic moment, product of molar magnetic susceptibility with temperature and Weiss constant

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_484

1334

Additional Remarks

1335

Structure H4{[Cu3(HL)2(H2O)4](H2W12O42)}.13H2O;

HL ¼ 2-pyrazine carboxylic acid O N OH N

Data T [K] 300 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 1.30 0.39

pm or μeff [μB] 3.23

ΘP [K] 42.1

Method –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Temperature dependence of χ M1 and χ MT is shown in Fig. 1 (ii) Curie-Weiss law obeyed (300–134 K), with: C ¼ 1.52 cm3 K mol1 θ ¼ 42.1 K Fig. 1 H4{[Cu3(HL)2 (H2O)4] (H2W12O42)}. 13H2O. Temperature dependence of χ M1 and χ MT. The solid lines represent fits to the data

Remarks 3D architecture

1336

Magnetic properties of paradodecatungstate derivative of. . .

Symbols and Abbreviations Short form T χg χM pm μeff ΘP χ M1 θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) inverse molar susceptibility Curie constant Curie temperature

Reference Y. Chen, J. Peng, H.-J. Pang, A.-X. Tian, P.-P. Zhang, D. Chen, M. Zhu, Y. Wang, H. Ma, Inorg. Chem. Commun. 12, 1242 (2009)

Magnetic properties of anionic 4-terpyridone based copper(II) azide supramolecule containing dinuclearmononuclear co-crystals

Substance 4-Terpyridone based copper(II) azide supramolecule containing dinuclearmononuclear co-crystals; [Cu2(L)2(μ1,1-N3)2].2[Cu(L)(N3)(H2O)].6H2O

Gross Formula C60H56Cu4N24O12

Properties Product of molar magnetic susceptibility with temperature, molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_485

1337

Magnetic properties of anionic 4-terpyridone based copper(II). . .

1338

Structure [Cu2(L)2(μ1,1-N3)2].2[Cu(L)(N3)(H2O)].6H2O;

HL ¼ 4-terpyridone OH

N N

N

χg [106 emu/g] – – –

χ MT [cm3 K mol1] 1.65 1.85 1.65

Data T [K] 300 15.0 2.0

pm or μeff [μB] 1.82/Cu

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks a) 3D supramolecule, dinuclearmononuclear species co-crystallizing together b) Metal ions in distorted squarepyramidal geometry

Symbols and Abbreviations

1339

Additional Remarks (i) χ MT versus T plot is shown in Fig. 1 (ii) Ferromagnetic interactions indicated (iii) Least-squares fitting of the experimental data leads to: J ¼ 15.0 cm1 zJ 0 ¼ 0.082 cm1 (interdimer exchange interactions parameter) g ¼ 2.06

Fig. 1 [Cu2(L)2(μ1,1-N3)2].2 [Cu(L)(N3) (H2O)].6H2O. Temperature dependence of χ MT. The solid line represents the stimulated curve

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ 0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

1340

Magnetic properties of anionic 4-terpyridone based copper(II). . .

Reference C.-Y. Liao, M. Nayak, H.-H. Wei, S. Mohanta, Polyhedron 27, 2693 (2008)

Magnetic properties of copper(II) azido cluster with Schiff-base derived from 2,6-diformyl-4-methylphenol and tris(hydroxymethyl)aminomethane

Substance Copper(II) azido cluster with Schiff-base derived from 2,6-diformyl-4-methylphenol and tris(hydroxymethyl)- aminomethane; {[(H5L)Cu2(μ-N3)]2[Cu(N3)4].2CH3OH}n

Gross Formula C36H56Cu5N22O16

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_486

1341

Magnetic properties of copper(II) azido cluster with Schiff-base. . .

1342

Structure {[(H5L)Cu2(μ-N3)]2[Cu(N3)4].2CH3OH}n; H7L ¼ Schiff-base obtained from 2,6-diformyl-4-methyl-phenol and tris(hydroxymethyl)aminomethane CH3

N

HO OH

OH

OH

N HO

OH OH

Data T [K] RT 2.0

χg [106 emu/g] – –

χM [106 emu/mol] – –

pm or μeff [μB] 3.98 1.82

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Double-stranded ladder like structure

Reference

1343

Additional Remarks (i) Temperature dependence of μeff and χ M is shown in Fig. 1 (ii) Two antiferromagnetically coupled Cu(II) ions within each dinuclear unit; bestfit parameters are: J1 ¼ 113.5 cm1 J2 ¼ 0 cm1 g ¼ 2.14 ϱ ¼ 0.005% (molar fraction of paramagnetic impurity) Fig. 1 {[(H5L)Cu2(μ-N3)]2 [Cu(N3)4].2CH3OH}n. Temperature dependence of μeff and χ M. The solid lines represent fits to the data

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID ϱ g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device molar fraction of paramagnetic impurity Lande factor

Reference S.S. Tandon, S.D. Bunge, N. Patel, L.K. Thompson, Inorg. Chem. Commun. 12, 1077 (2009)

Magnetic properties of dicyanamide bridged polymeric copper(II) complex with di(2-pyridylmethyl)amine

Substance catena-poly-{μ1,5-Dicyanamido[di(2-pyridylmethyl)amine]copper(II) perchlorate}; {[Cu(dpa)(μ1,5-dca)]ClO4}n

Gross Formula C14H13ClCuN6O4

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_487

1344

Data

1345

Structure {[Cu(dpa)(μ1,5-dca)]ClO4}n;

dpa ¼ di(2-pyridylmethyl)amine N

H

N

N

dca ¼ dicyanamide anion N N C

N

C

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.89

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 1D-infinite chain compound, distorted square-pyramidal geometry around Cu(II)

1346

Magnetic properties of dicyanamide bridged polymeric copper(II). . .

Additional Remarks (i) Temperature dependence of μeff and χ A is shown in Fig. 1 (ii) χ M data analyzed through Boner-Fischer model and yielded: J ¼ 0.31 cm1 g ¼ 2.09 (iii) Weak antiferromagnetic coupling indicated Fig. 1 {[Cu(dpa)(μ1,5-dca)] ClO4}n. Temperature dependence of χ A and μeff. The solid lines represent the best-fit values as described in the text

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference S.S. Massoud, F.R. Louka, M. Mikuriya, H. Ishida, F.A. Mautner, Inorg. Chem. Commun. 12, 420 (2009)

Magnetic properties of copper(II) polymer with alternating m1,3-squarato and binucleating polypyridylamine bridges

Substance Copper(II) polymer with alternating μ1,3-squarato and binucleating polypyridylamine bridges; {[Cu2(L)(μ-1,3-C4O4)(ClO4)2].1.33H2O}n

Gross Formula C36H34.65Cl2Cu2N6O13.33

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_488

1347

1348

Magnetic properties of copper(II) polymer with. . .

Structure {[Cu2(L)(μ-1,3-C4O4)(ClO4)2].1.33H2O}n;

L ¼ 1,3-bis[bis(2-pyridylmethyl)aminomethyl]benzene

N

N N N

N N

C4 O2 4 ¼ 3,4-dihydroxycyclobut-3-en-1,2-dionate anion O O

O

O

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 2.65

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K]

Method SQUID

Remarks 1D coordination polymer, coordination geometry around Cu(II) is square-pyramidal

Reference

1349

Additional Remarks (i) Plot of χ M and μeff versus T is shown in Fig. 1 (ii) Magnetic behavior indicated antiferromagnetic coupling between Cu(II) ions (iii) Best-fit parameters are: J ¼ 6.3 cm1 g ¼ 2.18 ϱ ¼ 4.1% (molar fraction of paramagnetic impurity)

Fig. 1 {[Cu2(L)(μ-1,3-C4O4) (ClO4)2].1.33H2O}n. Temperature dependence of χ M (●) and μeff (○). The solid line represents the calculated curve fit

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID ϱ g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device molar fraction of paramagnetic impurity Lande factor

Reference T. LeGuet, F.A. Mautner, S. Demeshko, F. Meyer, R.S. Perkins, S.S. Massoud, Inorg. Chem. Commun. 12, 321 (2009)

Magnetic properties of copper(II) complex with 5,6-diphenyl-3(2-pyridyl)-1,2,4-triazine

Substance catena-poly{[Aqua{5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine}]sulphatocopper(II) monohydrate}; [Cu(SO4)(dppt)(H2O)]n.nH2O

Gross Formula C20H18CuN4O6S

Properties Product of molar magnetic susceptibility with temperature, molar magnetic moment, Weiss constant and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_489

1350

Data

1351

Structure [Cu(SO4)(dppt)(H2O)]n.nH2O;

dppt ¼ 5,6-diphenyl-3-(2-pyridyl)-1,2,4triazine C6H5

N

C6H5

N

N N

Data T [K] 300 1.8

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.415 0.425

pm or μeff [μB] 1.82

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] +0.04

Method SQUID

Remarks Polymeric, geometry around copper(II) ions may be described as distorted tetragonalbipyramid

1352

Magnetic properties of copper(II) complex. . .

Additional Remark (i) Temperature dependence of χ M1 and χ MT is shown in Fig. 1 (ii) Curie-Weiss behavior indicated weak ferromagnetic interactions with: C ¼ 0.415 cm3 K mol1 θ ¼ +0.04 K (iii) χ M data analyzed through Bleaney-Bowers expression (using dimer model) and yielded: 2J ¼ +0.2 cm1 zJ 0 ¼ 0 (interdimer exchange interaction parameter) Fig. 1 [Cu(SO4)(dppt) (H2O)]n.nH2O. Temperature dependence of χ M1 (●) and χ MT (○)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID χ M1 zJ 0 J θ C

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device inverse molar susceptibility interdimer exchange interaction parameter exchange energy Curie constant Curie temperature

Reference

1353

Reference B. Machura, A. Switlicka, R. Kruszynski, J. Mrozinski, J. Klak, J. Kusz, Polyhedron 27, 2959 (2008)

Magnetic properties of copper(II) complex with vic-dioxime ligand containing 1,8-diamino-3,6-dioxaoctane group

Substance Polymeric copper(II) complex with N,N0 -1,8-diamino-3,6-dioxaoctane)p-tolylglyoxime; [Cu(H2L)]n

Gross Formula C24H30CuN6O6

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_490

1354

Additional Remark

1355

Structure [Cu(H2L)]n; CH3

O N

C

N

C

O

O

N H

H N

O

O C

N

C

N O

H3C

H .2H2O

Cu H

n

H4L ¼ N,N0 -1,8-diamino-3,6-dioxaoctane)-p-tolylglyoxime CH3

HO N

C

N

C

HO

O

N H

O

H N

OH C

N

C

N

OH

H3C

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.84

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remark (i) No antiferromagnetic interactions indicated

ΘP [K] –

Method Faraday

Remarks Square-planar geometry around Cu(II)

1356

Magnetic properties of copper(II) complex with vic-dioxime. . .

Symbols and Abbreviations Short form T χg χM pm μeff Faraday ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Faraday method paramagnetic Curie constant (Weiss constant)

Reference A. Kilic, M. Durgun, E. Tas, I. Yilmaz, Trans. Met. Chem. 33, 29 (2008)

Magnetic properties of 2-nitrobenzoatocopper(II) complex containing N,N-diethylnicotinamide (polymeric)

Substance catena-Poly-[N,N-diethylnicotinamide-tetrakis(2-nitrobenzoato)dicopper(II)]; [Cu2(L)4(denia)]n

Gross Formula C38H30N6Cu2O17

Properties Molar magnetic moment and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_491

1357

1358

Magnetic properties of 2-nitrobenzoatocopper(II) complex. . .

Structure [Cu2(L)4(denia]n;

HL ¼ 2-nitrobenzoic acid; O OH NO2 denia ¼ N,N-diethylnicotinamide O N N

CH3 CH3

Data T [K] 300 80

χg [106 emu/g] – –

χM [106 emu/mol] – –

pm or μeff [μB] 1.33 0.08

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks Dimeric unit, zig-zag chain structure, square-pyramidal coordination around each Cu(II)

Reference

1359

Additional Remarks (i) Plots of χ M and χ MT versus T are shown in Fig. 1 (ii) χ M data analyzed through Bleany-Bowers equation (iii) The best-fitting parameters were obtained: 2J ¼ 340 cm1 zJ 0 ¼ 0.1 cm1 (interdimer exchange interaction parameter) g ¼ 2.20 Fig. 1 [Cu2(L)4(denia]n. Temperature dependence of χ M (●) and χ MT (○). The solid line was generated from the best-fit magnetic parameters

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID zJ0 g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device interdimer exchange interaction parameter Lande factor

Reference J. Kavalirova, M. Korabik, P. Stachova, J. Moncol, R. Sillanpaa, T. Lis, D. Miklos, M. Melnik, J. Mrozinski, D. Valigura, Polyhedron 27, 1333 (2008)

Magnetic properties of copper(II)saccharinato complex with piperazine

Substance catena-Poly[aquapiperazinebis(saccharinato)copper(II)]; [Cu(sac)2(ppz)(H2O)]n

Gross Formula C18H20CuN4O7S2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_492

1360

Data

1361

Structure [Cu(sac)2(ppz)(H2O)]n;

sac ¼ saccharinate anion; O N S O

O

ppz ¼ piperazine H N

N H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.76

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Evans

Remarks 1D helical chain structure, distorted trigonal-bipyramidal geometry at each copper centre

1362

Magnetic properties of copper(II)-saccharinato complex with piperazine

Symbols and Abbreviations Short form T χg Evans χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) Evans balance magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference V.T. Yilmaz, S. Guney, C. Kazak, Polyhedron 27, 1381 (2008)

Magnetic properties of polymeric copper(II) complex with Schiff-base derived from salicylaldehyde and β-alanine

Substance Polymeric copper(II) complex with Schiff-base derived from salicylaldehyde and β-alanine; [Cu(L)(H2O)]n

Gross Formula C10H11CuNO4

Properties Molar magnetic moment, product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_493

1363

1364

Magnetic properties of polymeric copper(II) complex with Schiff-base. . .

Structure [Cu(L)(H2O)]n;

H2L ¼ Schiff-base ligand derived from salicylaldehyde and β-alanine N OH

O

HO

Data T [K] 292 83

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.474 0.479

pm or μeff [μB] 1.95 1.96

ΘP [K] –

Method Faraday

Remarks 1D polymeric structure

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Temperature (294-80 K) dependence of χ MT is shown in Fig. 1 (ii) χ M data analysed in terms of an infinite chain of a S ¼ ½ state using Fischer’s and Ising models (iii) Weak ferromagnetic coupling indicated (iv) Best-fit parameters obtained were achieved with: J = +0.6 cm–1 Fischer’s model g = 2.253 –1 J = 1.2 cm Ising’s model g = 2.253 (v) Strong antiferromagnetic interactions indicated

Reference

1365

Fig. 1 [Cu(L)(H2O)]n. Temperature dependence of χ MT

Symbols and Abbreviations Short form T χg χM pm μeff ΘP Faraday g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) Faraday method Lande factor

Reference J. Vaneo, J. Marek, Z. Travnicek, E. Racanska, J. Muselik, O. Svajlenova, J. Inorg. Biochem. 102, 595 (2008)

Magnetic properties of copper(II) complex with vic-dioxime ligand containing 1,8-diamino-3,6-dioxaoctane group

Substance Polymeric copper(II) complex with N,N0 -(1,8-diamino-3,6-dioxaoctane)glyoxime; [Cu(H2L)]n

Gross Formula C10H18CuN6O6

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_494

1366

Data

1367

Structure [Cu(H2L)]n; O N

C

N

C

O

H O

N H

H N

O

H

H

O C

N

C

N

Cu

O

H n

H4L ¼ N,N0 -(1,8-diamino-3,6-dioxaoctane)glyoxime OH N

C

N

C

OH

H N H

O

O

H N H

O C

N

C

N O

H

H

Data T [K] RT

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.81

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method Faraday

Remarks Square-planar geometry around Cu(II)

1368

Magnetic properties of copper(II) complex with vic-dioxime. . .

Additional Remark (i) No antiferromagnetic interactions indicated

Symbols and Abbreviations Short form T χg χM pm μeff Faraday ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment Faraday method paramagnetic Curie constant (Weiss constant)

Reference A. Kilic, M. Durgun, E. Tas, I. Yilmaz, Trans. Met. Chem. 33, 29 (2008)

Magnetic properties of oxalato-bridged copper(II) complex with 4-aminopyridine

Substance μ-Oxalato-bis(4-aminopyridine)copper(II); [Cu(μ-ox)(4-ampy)2]n

Gross Formula C12H12CuN4O4

Properties Product of molar magnetic susceptibility with temperature and exchange energy

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_495

1369

1370

Magnetic properties of oxalato-bridged copper(II) complex with 4-aminopyridine

Structure [Cu(μ-ox)(4-ampy)2]n;

4-ampy ¼ 4-aminopyridine; NH2

N ox2 ¼ oxalate anion O O

O

O

Data T [K] RT 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.409 0.268

pm or μeff [μB] –

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks a) One dimensional zig-zag chain structure b) Aromatic base is bound to metal atom in trans-position

Reference

1371

Additional Remarks (i) Thermal dependence of χ MT is shown in Fig. 1 (ii) Trend of χ MT is indicative of ferromagnetic interactions, with: J ¼ 1.1 cm1 g ¼ 2.10 Fig. 1 [Cu(μ-OX) (4-ampy)2]. Temperature dependence of of χ MT. The solid line represents the best theoretical fit

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference O. Castillo, A. Luque, P. Roman, F. Llort, M. Julve, Inorg. Chem. 40, 5526 (2001)

Magnetic properties of oxalato-bridged copper(II) complex with 3-aminopyridine

Substance μ-Oxalato-bis(3-aminopyridine)copper(II); [Cu(μ-ox)(3-ampy)2]n

Gross Formula C12H12CuN4O4

Properties Product of molar magnetic susceptibility with temperature and exchange energy

Structure [Cu(μ-ox)(3-ampy)2]n;

3-ampy ¼ 3-aminopyridine; NH2

N

ox2 ¼ oxalate anion O O

O

O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_496

1372

Additional Remarks

1373

Data T [K] RT 12

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.394 0.014

pm or μeff [μB] –

ΘP [K] –

Method SQUID

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Thermal dependence of χ MT is shown in Fig. 1 (ii) Antiferromagnetic interactions observed, with: J ¼ 44.5 cm1 g ¼ 2.13 ϱ ¼ 1.4% (molar fraction of paramagnetic impurity) Fig. 1 [Cu(μ-ox) (3-ampy)2]. Temperature dependence of of χ MT. The solid line represents the best theoretical fit

Remarks a) One dimensional zig-zag chain structure b) Aromatic base is bound to metal atom in cis-position

1374

Magnetic properties of oxalato-bridged copper(II) complex with 3-aminopyridine

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID ϱ g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device molar fraction of paramagnetic impurity Lande factor

Reference O. Castillo, A. Luque, P. Roman, F. Llort, M. Julve, Inorg. Chem. 40, 5526 (2001)

Magnetic properties of oxalato-bridged copper(II) complex with 2-aminopyridine

Substance μ-Oxalato-bis(2-aminopyridine)copper(II); [Cu(μ-ox)(2-ampy)2]n

Gross Formula C12H12CuN4O4

Properties Product of molar magnetic susceptibility with temperature and exchange energy

Structure [Cu(μ-ox)(2-ampy)2]n;

2-ampy ¼ 2-aminopyridine;

N

NH2

ox2 ¼ oxalate anion

O

O

O

O

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_497

1375

1376

Magnetic properties of oxalato-bridged copper(II) complex with 2-aminopyridine

Data T [K] RT 2.0

χg [106 emu/g] – –

χ MT [cm3 K mol1] 0.416 0.836

pm or μeff [μB] –

ΘP [K] –

Method SQUID

Remarks a) One dimensional zig-zag chain structure b) Aromatic base is bound to metal atom in cis-position

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Additional Remarks (i) Thermal dependence of χ M is shown in Fig. 1 (ii) Trend of χ MT is indicative of ferromagnetic interactions, with: J ¼ +2.0 cm1 g ¼ 2.16 Fig. 1 [Cu(μ-ox) (2-ampy)2]. Temperature dependence of of χ MT. The solid line represents the best theoretical fit

Reference

1377

Symbols and Abbreviations Short form T χg χM pm μeff ΘP SQUID g

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant) superconducting quantum interference device Lande factor

Reference O. Castillo, A. Luque, P. Roman, F. Llort, M. Julve, Inorg. Chem. 40, 5526 (2001)

Magnetic properties of bimetallic oxide Cu-Mo4 containing p-xylene diphosphonic acid

Substance Bimetallic oxide Cu-Mo4 containing p-xylene diphosphonic acid; {[Cu(bipy)]2Mo4O10(L)2}

Gross Formula C18H16CuMo4N2O11P2

Properties Molar magnetic moment

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_498

1378

Data

1379

Structure {[Cu(bipy)]2Mo4O10(L)2};

bipy ¼ 2,20 -bipyridine;

N

N L ¼ p-xylene diphosphonic acid O OH P OH

HO HO

P O

Data T [K] 300

χg [106 emu/g] –

χM [106 emu/mol] –

pm or μeff [μB] 1.91

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

ΘP [K] –

Method SQUID

Remarks 3D structure constructed from [Mo4O10(O3PrR)]n chains

1380

Magnetic properties of bimetallic oxide Cu-Mo4 containing p-xylene. . .

Symbols and Abbreviations Short form T χg χM pm μeff SQUID ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment superconducting quantum interference device paramagnetic Curie constant (Weiss constant)

Reference S. Jones, H. Liu, K. Schmidtke, C.C. O’Conner, J. Zubieta, Inorg. Chem. Commun. 13, 298 (2010)

Part XII Gd

Magnetic properties of quaternary selenide of barium gadolinium and copper

Substance Barium gadolinium copper selenide; BaGdCuSe3

Gross Formula BaGdCuSe3

Properties Molar magnetic moment

Structure BaGdCuSe3

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_499

1383

1384

Magnetic properties of quaternary selenide of barium gadolinium and copper

Data T χg [10 [K] 300–5.0 –

6

χM emu/g] [10 –

6

pm or μeff ΘP emu/mol] [μB] [K] 7.85 –

Method SQUID

Remarks a) Compound is composed of (GdCuSe3)–1 layers b) The Gd3+ is octahedrally coordinated to six Se atoms c) The Cu(+1) is tetrahedrally coordinated to four Se atoms d) Ba atom is coordinated to a bicapped trigonal prism of eight Se atoms

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff SQUID ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment superconducting quantum interference device paramagnetic Curie constant (Weiss constant)

Reference F.-Q. Huang, K. Mitchell, J.-A. Ibers, Inorg. Chem. 40, 5123 (2001)

Magnetic properties of quaternary selenide of cesium gadolinium and zinc

Substance Cesium gadolinium zinc selenide; CsGdZnSe3

Gross Formula CsGdZnSe3

Properties Molar magnetic moment

Structure CsGdZnSe3

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_500

1385

1386

Magnetic properties of quaternary selenide of cesium gadolinium and zinc

Data T χg [10 [K] 300–5.0 –

6

χM emu/g] [10 –

6

pm or μeff ΘP emu/mol] [μB] [K] Method 7.87 – SQUID

Remarks a) Compound is composed of (GdZnSe3)–1 layers separated by Cs atoms b) The Gd3+ is octahedrally coordinated to six Se atoms c) The zinc is tetrahedrally coordinated to four Se atoms d) Cs atom is coordinated to a bicapped trigonal prism of eight Se atoms

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff SQUID ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment superconducting quantum interference device paramagnetic Curie constant (Weiss constant)

Reference F.-Q. Huang, K. Mitchell, J.-A. Ibers, Inorg. Chem. 40, 5123 (2001)

Part XIII Tb

Magnetic properties of bipyrimidinebridged dinuclear terbium(III) complex containing bulky-β-diketonate terminal ligand

Substance μ-Bipyrimidine-di[tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5octanedionatoterbiumr(III)]; [Tb(fod)3-(μ-bpm)-Tb(fod)3]

Gross Formula C68H66F42N4O12Tb2

Properties Molar magnetic moment and product of molar magnetic susceptibility with temperature

© Springer-Verlag GmbH Germany, part of Springer Nature 2023 R. T. Pardasani, P. Pardasani, Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8, https://doi.org/10.1007/978-3-662-66460-5_501

1389

Magnetic properties of bipyrimidine-bridged dinuclear terbium(III). . .

1390

Structure [Tb(fod)3-(μ-bpm)-Tb(fod)3]; CF3CF2CF2

tBu

N

O

N

Tb

O

tBu

Tb N

N

O O CF2CF2CF2 3

3

Hfod ¼ 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3, 5-octanedione CF3CF2CF2

tBu

O

bpm ¼ bipyrimidine

Tb

O

N

N

N

N

3

Data T [K] RT

χg [106 emu/g] –

χ MT [cm3 K mol1] 25.67

pm or μeff [μB] 20.27

ΘP [K] –

Method –

Remarks Two magnetically isolated Tb(III) ions

T: Temperature χ g: Specific susceptibility χ M: Molar susceptibility pm, μeff: Effective magnetic moment per molecule ΘP: Paramagnetic Curie constant (Weiss constant)

Symbols and Abbreviations Short form T χg χM pm μeff ΘP

Full form temperature magnetic susceptibility per gram (specific susceptibility) magnetic susceptibility per mole (molar susceptibility) effective magnetic moment per molecule effective magnetic moment paramagnetic Curie constant (Weiss constant)

Reference

Reference M. Irfanullah, K. Iftikhar, Inorg. Chem. Commun. 12, 296 (2009)

1391