Nanoscale Matter and Principles for Sensing and Labeling Applications (Advanced Structured Materials, 206) 9819978475, 9789819978472

This book is a compilation of carefully chosen chapters that cover the subjects of nanoscale matter, sensing, and labell

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Table of contents :
Foreword
Preface
Contents
About the Editors
1 Alkali Containing Molecular Ions in SIMS: A Cutting-Edge Ion-Beam Technique for Materials Quantification in Nanoscale Systems
1.1 Introduction
1.2 Ion Emission Mechanisms
1.3 Matrix Effect: A Bottleneck in Quantitative Analysis
1.3.1 Matrix Effect Compensation
1.4 Composition Analysis Using MCs+-SIMS Approach
1.4.1 Alloy and Superlattice Structures
1.4.2 ZnO and ZnS/ZnO Heterostructured Nanowalls
1.5 Conclusion and Outlook
References
2 Quantum-Dot-Based Fluorescence Sensing
2.1 Quantum Dots and Confinement Effect
2.2 Classification of Quantum Dots
2.3 Synthesis of Quantum Dots
2.4 Quantum-Dot-Based Sensing
2.5 Conclusion and Perspectives
References
3 Nanomaterial for Humidity Sensor Applications
3.1 Introduction
3.1.1 Classification of Nanomaterials
3.1.2 Classification of Sensors
3.2 Types of Humidity Sensors
3.2.1 Humidity Sensing Parameters
3.2.2 Resistive-Type Humidity Sensors
3.2.3 Capacitive Humidity Sensors
3.2.4 Surface Acoustic Wave (SAW) Humidity Sensors
3.2.5 Quartz Crystal Microbalance (QCM) Humidity Sensors
3.2.6 Optical Fiber Humidity Sensors
3.3 Nanomaterials Used for Humidity Sensors
3.4 Synthesis, Characterization, and Sensing Response
3.5 Summary
References
4 Nanomaterial-Based Sensors for the Detection of Explosives
4.1 Introduction
4.2 Classifications of Nanomaterials-Based Sensors for the Detection of Explosives
4.2.1 Metal-Based Nanomaterials as Explosive Sensors
4.2.2 Carbon-Based Nanomaterials as Explosive Sensors
4.2.3 Quantum Dots (QDs) for Explosive Sensing
4.2.4 Nanoporous Materials as Explosive Sensors
4.2.5 Hybrid Nanomaterials-Based Explosive Sensors
4.3 Polymeric Nanocomposites for Explosive Detection
4.4 Recently Developed Nanomaterial-Based Explosive Sensors
4.5 Conclusions and Future Prospects
References
5 Advances in Few-Layered Nanoscale Transition Metal Dichalcogenides in Sensing Application
5.1 Introduction
5.2 Chemical Sensors Based on Layered Semiconducting TMDCs
5.2.1 Electrically Transduced Chemical Sensor (ETCS)
5.2.2 Optically Transduced Chemical Sensor
5.2.3 Chemical Sensing Parameters
5.2.4 Heavy Metal Ion Sensing
5.3 Photosensors
5.3.1 Electrical Transduction Mechanisms in Photosensors
5.3.2 Photosensor Parameters
5.3.3 Layered Semiconducting TMDC-Based Photosensors
5.3.4 Scope in Dosimetry
5.4 Summary and Outlook
References
6 Light Scattering by One-Dimensional ZnO Nanorods and Their Applications in Optical Sensing
6.1 Introduction
6.2 Zinc Oxide: Physical and Chemical Properties
6.2.1 One-Dimensional ZnO Nanorods
6.3 Light Scattering by ZnO Nanorods: An Approximate Approach
6.3.1 Side Coupling Through Scattering of Nanorods
6.3.2 Sensing Mechanism by Scattering
6.3.3 Loss Mechanism
6.3.4 Estimation of the Scattering Cross Section
6.4 Optical Sensing Using the Light Scattering by ZnO Nanorods
6.4.1 Humidity Sensing
6.4.2 Chemical Vapor Sensing
6.4.3 Biomarker and Biological Sensing
6.5 Conclusions and Outlook
References
7 Recent Advances in 1D and 2D ZnO Nanostructure-Based Photosensors
7.1 Introduction
7.1.1 Working Mechanism and Various Parameters of UV Photodetectors
7.1.2 Current Scenario of Semiconductor-Based UV Photodetectors
7.2 1D ZnO Nanostructures-Based Photosensor
7.2.1 Pristine 1D ZnO Nanostructures and Their Photo-Sensing Applications
7.2.2 Doped 1D ZnO Nanostructures and Their Photo-Sensing Applications
7.2.3 ZnO-Based Heterojunction Nanostructures and Their Photo-Sensing Application
7.2.4 Schottky Junction-Based ZnO Nanostructures and Its Photo-Sensing Application
7.3 2D ZnO Nanostructures-Based Photosensor
7.4 Conclusion and Future Scope
References
8 Recent Strategies for Development of ZnO-Based Efficient UV-Photodetectors
8.1 Introduction
8.2 UV-Photodetection with Nanostructures
8.3 Strategies for Efficient UV-Photodetection
8.3.1 Microstructure and Surface Modification
8.3.2 Electronic Structure Modification
8.3.3 Hybrid or Composite Formation
8.3.4 Exploiting Piezo-Phototronic Effects
8.4 Conclusion and Future Prospect
References
9 Sensing Nanomaterials Based on Host–Guest Interactions
9.1 Introduction
9.2 Macrocyclic Cavitands
9.3 Nanosensor Employing Diverse Host–Guest Interactions
9.3.1 Nanosensors Using Cyclodextrin Hosts
9.3.2 Nanosensors Using Cucurbituril Hosts
9.3.3 Nanosensors Using Macrocyclic Arene Hosts
9.3.4 Nanosensors Using Pillararene Hosts
9.4 Conclusion and Future Directions
References
10 Perovskite Nanomaterials as Advanced Optical Sensor
10.1 Introduction
10.2 Synthetic Strategies of Perovskite Nanocrystals
10.2.1 Hot Injection Method (HI)
10.2.2 Ligand-Assisted Re-Precipitation Method (LARP)
10.2.3 Emulsion Synthesis
10.2.4 Microwave and Ultrasonic Method
10.3 Optical Sensor and Its Mechanism
10.3.1 Static Quenching
10.3.2 Dynamic Quenching
10.4 Optical Sensing Applications of Perovskite Nanocrystals
10.4.1 Metal Ion Sensing
10.4.2 Detection of Volatile Organic Compounds
10.4.3 Gas Sensing
10.4.4 Humidity and Thermal Sensing
10.4.5 Explosive Detection
10.5 Conclusion and Future Challenges
References
11 Metal–Organic Frameworks and Their Composites for Sensing Applications
11.1 Introduction
11.1.1 Rigid Frameworks
11.1.2 Dynamic or Flexible Frameworks
11.1.3 Lewis Acid Frameworks
11.1.4 Surface Functionalized MOFs
11.1.5 Electrically Conducting MOFs
11.2 MOF-Based Electrochemical Sensors
11.3 MOF-Based Gas Sensors
11.4 MOF-Based Optical Sensors
11.5 MOF-Based Biosensors
11.6 MOF-Based SERS Sensors
11.7 Conclusion and Future Prospects
References
12 Electroactive Polymer-Based Nanostructures and Nanocomposites for Sensing Applications
12.1 Introduction
12.2 Sensor as the Key
12.2.1 Various Types of Sensors
12.3 Electroactive Polymer for Sensing
12.3.1 Conductive Polymer-Based Sensors
12.3.2 NO2 Gas Sensor
12.3.3 Humidity Sensor
12.3.4 Pressure Sensor
12.4 Conclusion and Outlook
References
13 Nano-Reinforced Polymers and Polymer Nanocomposites
13.1 Introduction
13.2 Synthesis of Polymer Nanocomposites
13.2.1 Ultrasonication-Assisted Solution Mixing
13.2.2 Shear Mixing
13.2.3 Three Roll Milling
13.2.4 Ball Milling
13.2.5 Double-Screw Extrusion
13.3 Characterization of Polymer Nanocomposites
13.4 Properties of Polymer Nanocomposites
13.4.1 Mechanical Properties
13.4.2 Rheological Properties
13.4.3 Thermal Stability
13.4.4 Magnetic and Electric Properties
13.5 Simulation of Polymer Nanocomposites
13.5.1 Quantum Mechanical Simulation
13.5.2 MC Simulation
13.5.3 MD Simulation
13.5.4 Mesoscopic Simulation
13.5.5 Continuum Simulation
13.6 Some of Applications of Polymer Nanocomposites
13.6.1 Application of Biodegradable Polymer Nanocomposites in Electronics Industry
13.6.2 Application of Polymer Nanocomposites in Photodetectors
13.6.3 Application of Polymer Nanocomposites in Pressure Sensors
13.6.4 Application of Polymer Nanocomposites in Energy Storage Devices
13.7 Summary and Future Outlook
References
14 Carbon Dots and Their Sensing Behavior in Organic Medium
14.1 Introduction
14.2 Synthesis Method
14.2.1 Top-Down
14.2.2 Bottom-Up
14.3 Hydrophilicity
14.4 Origin of Fluorescence
14.5 Sensing Mechanism
14.5.1 Static Quenching
14.5.2 Dynamic Quenching
14.6 Sensing Applications
14.6.1 Cations
14.6.2 Anions
14.6.3 Small Molecules
14.7 Detection of TNP in Organic Medium
14.7.1 Synthesis of Hydrophobic CDs
14.7.2 Sensing Protocol
14.7.3 Sensing Behavior
14.7.4 Stability of the Sensor
14.7.5 Selectivity of the Sensor
14.7.6 PL Quenching Mechanism
14.8 Conclusion and Outlook
References
15 An Overview of Carbon-Based Nanomaterials and Their Derivatives for Different Sensing Applications
15.1 Introduction
15.2 Carbonaceous Nanomaterials for Sensing
15.2.1 Graphene-Based Sensing Applications: A 2D Sensing Platform
15.2.2 Carbon Nanotube-Based Sensing Applications: A 1D Sensing Platform
15.2.3 Fullerene Based Sensing Platform: A 0D Sensing Platform
15.2.4 Nanoflower for Sensing Applications: A 3D Sensing Platform
15.2.5 Carbon Dots as Sensing Platforms: A 0D Sensing Platform
15.3 Working Principle of Carbon-Based Sensing Interface
15.4 Carbon-Based Nanomaterials for Biomedical Applications
15.4.1 Carbon Nanotubes (CNTs) as Biosensors
15.4.2 Graphene Oxide as Biosensor
15.4.3 Graphene Quantum Dots (GQDs) as Biosensor
15.5 Carbon-Based Nanomaterials for Agricultural Applications
15.5.1 Carbon Nanotubes (CNTs) Sensing in Agriculture
15.5.2 Graphene Oxide (GO) in Agricultural Sensing
15.6 Limitations and Challenges of Carbonaceous Nanomaterials in Sensing
15.7 Conclusion and Outlook
References
16 Development of Carbon Dots and Nanohybrids for Biosensing and Bioimaging Relevance
16.1 Introduction
16.2 Preparation of CDs and Doped CDs
16.2.1 Synthesis of CDs by Top-Down Approach
16.2.2 CD by Bottom-Up Approach
16.2.3 Doped CD-Based Nanohybrids
16.3 Physical and Chemical Properties of CDs
16.4 Applications
16.4.1 Nano Sensing Applications
16.4.2 Biosensing and Biospecificity
16.4.3 Bioimaging
16.5 Conclusions and Future Prospective
References
17 Flexible and Wearable Chemical Sensor Based on Graphene Derivatives
17.1 Introduction
17.2 Traditional Flexible and Wearable Chemical Sensors
17.3 Role of Nanomaterials in Flexible and Wearable Chemical Sensors
17.3.1 Advantage of Graphene—The Miracle Material
17.4 Different Derivatives of Graphene for Flexible and Wearable Chemical Sensors
17.4.1 Pristine Graphene
17.4.2 Chemically Modified Graphene
17.4.3 Graphene Composites
17.5 Gas Sensing Mechanism of Graphene–Based Sensors
17.6 Future Scope and Conclusion
References
18 Pulsed Laser-Mediated Phototherapeutic Mechanisms for Biomedical Applications
18.1 Introduction
18.2 Plasmonics
18.2.1 Bulk Plasmons and Surface Plasmons (SPs)
18.2.2 Localised Surface Plasmon Resonance (LSPR)
18.2.3 Electromagnetic (EM) Wave Absorption and Scattering in Plasmonics
18.3 Pulsed Laser-Induced Phototherapy Mechanisms
18.3.1 Photothermal Mechanisms
18.3.2 Photoacoustic Mechanisms
18.3.3 LSPR in Photothermal and Photoacoustic Mechanisms
18.4 Tuning LSPR by Controlling Size, Shape, and Refractive Index
18.4.1 Size Dependence of MNPs on LSPR
18.4.2 Effect of Shape of Plasmonic MNPs on LSPR
18.4.3 Dependence of Dielectric Constants on LSPR
18.5 Applications of Pulsed Laser-Induced Therapy Using Plasmonics
18.6 Conclusion and Outlook
References
19 Plasmonic Nanostructures for the Detection of Foodborne Pathogens
19.1 Introduction
19.2 The Fundamental Properties of Plasmonic Nanostructures
19.3 Fabrication of Plasmonic Nanostructures
19.4 Types of (Bio) Sensors
19.4.1 Surface Plasmon Resonance Optical Sensor
19.4.2 Surface-Enhanced Raman Spectroscopy Sensor
19.4.3 Electrochemical (Bio) Sensors
19.5 Conclusions and Future Perspective
References
20 Morphology-Dependent Biosensing of Metallic Nanoparticles
20.1 Introduction
20.2 Plasmonic Properties of Metallic Nanoparticles
20.3 Advantages of Biosensors
20.4 Plasmonic Metal Nanoparticles and Their Characteristics
20.4.1 Gold (Au)
20.4.2 Silver (Ag)
20.4.3 Copper (Cu)
20.5 Conclusions and Outlook
References
21 Structural and Optical Phenomena of Thermally Treated Fullerene-Based Nanocomposites with Metal Nanoparticles for Sensing Applications
21.1 Introduction
21.2 Synthesis of Metal-Matrix-Based Nanocomposites
21.2.1 Annealing Studies in Cu-Fullerene Nanocomposite
21.2.2 Annealing Studies in Ag-Fullerene Nanocomposite
21.2.3 Annealing Studies in Au-Fullerene Nanocomposites
21.3 Conclusion and Outlook
References
22 Surface Plasmon Resonance (SPR) Biosensors for Antibiotic Residue Detection
22.1 Introduction
22.2 Pharmaceutical Residues in the Environment
22.2.1 Effects of Antibiotic Residues on Living Organisms
22.2.2 Common Antibiotic Residue Detection Methods
22.2.3 Biosensors and Their Types
22.3 Theory of Surface Plasmons
22.3.1 Plasmons and Surface Plasmon Resonance (SPR)
22.3.2 Localized Surface Plasmon Resonance (LSPR)
22.4 SPR Biosensors for Antibiotic Detection
22.5 Conclusions and Outlook
References
23 Advances in Luminescence-Based Biosensing with Quantum Dots
23.1 Introduction
23.2 Advantages of Quantum Dots
23.3 Quantum Dot-Based Fluorescent Biosensor
23.3.1 Quantum Dot-Based Sensing Through Fluorescence Quenching Analysis
23.3.2 QD Biosensors Based on FRET Technique
23.4 QD Biosensors Based on Bioluminescence Resonance Energy Transfer (BRET)
23.5 Concluding Remarks
References
24 Recent Advances in Rare-Earth Based Persistent Luminescent Probes
24.1 Introduction
24.2 Background
24.2.1 Down Conversion RENPs (DC-RENPS)
24.2.2 UP Conversion RENPs (UC-RENPS)
24.2.3 Persistence Luminescence RENPs (PerL RENPs)
24.3 Conclusion and Outlook
References
25 Nanomaterial-Based Sensors for Macrolide Sensing
25.1 Introduction
25.2 Methods of Detection: Conventional Methods Versus Nanomaterials-Based Methods
25.3 Applications for Macrolides Sensing Using Nanomaterials
25.3.1 Optical Sensors with Nanomaterials for Macrolides Detection
25.3.2 Electrochemical Sensors with Nanomaterials for Macrolides Detection
25.4 Challenges and Prospects
25.5 Conclusions
References
26 The Physics of Biofunctionality in Nanoconfined Systems
26.1 Physics of Confinement
26.2 Physics Under Nanoconfinement
26.3 Biofunctionality
26.4 Biofunctionality Under Nanoconfinement
26.5 Concluding Remarks
References
27 Development of Rapidly Quenched Amorphous-Nanostructured Materials for Sensor Applications
27.1 Introduction
27.2 Magnetostrictive Sensor (MsS) Technology
27.2.1 Preparation of MsS Sensor Material
27.2.2 Magnetic Property Considerations
27.2.3 MsS Transducer Methodology
27.2.4 Configuration of Transducer-Sensing System
27.2.5 MsS Measurement System and Application
27.3 Giant Magneto-Impedance (GMI)-Based Technology
27.3.1 Preparation of Microwires
27.3.2 Measurement of GMI Behavior
27.3.3 Scope of GMI Sensor
27.4 Conclusion and Future Outlook
References
28 Magnetic Nanostructures for Transport Control and Sensing Applications
28.1 Introduction
28.2 Magneto-Transport Phenomena
28.2.1 Giant Magnetoresistance (GMR)
28.2.2 Tunnelling Magnetoresistance (TMR)
28.2.3 Spin-Torque Transfer (STT)
28.3 Magnetic Nanostructures and Materials
28.4 Magnetic Nanomaterials
28.4.1 FeCo Nanoparticles
28.4.2 CMR Nanomaterials
28.4.3 Co/Pt Multilayer
28.4.4 CoFe/Bi/Co Multilayers
28.4.5 Magnetic Tunnel Junctions (MTJ)
28.5 Conclusion and Future Prospective
References
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Advanced Structured Materials

Dambarudhar Mohanta Purushottam Chakraborty   Editors

Nanoscale Matter and Principles for Sensing and Labeling Applications

Advanced Structured Materials Volume 206

Series Editors Andreas Öchsner, Faculty of Mechanical and Systems Engineering, Esslingen University of Applied Sciences, Esslingen, Germany Lucas F. M. da Silva, Department of Mechanical Engineering, Faculty of Engineering, University of Porto, Porto, Portugal Holm Altenbach , Faculty of Mechanical Engineering, Otto von Guericke University Magdeburg, Magdeburg, Sachsen-Anhalt, Germany

Common engineering materials are reaching their limits in many applications, and new developments are required to meet the increasing demands on engineering materials. The performance of materials can be improved by combining different materials to achieve better properties than with a single constituent, or by shaping the material or constituents into a specific structure. The interaction between material and structure can occur at different length scales, such as the micro, meso, or macro scale, and offers potential applications in very different fields. This book series addresses the fundamental relationships between materials and their structure on overall properties (e.g., mechanical, thermal, chemical, electrical, or magnetic properties, etc.). Experimental data and procedures are presented, as well as methods for modeling structures and materials using numerical and analytical approaches. In addition, the series shows how these materials engineering and design processes are implemented and how new technologies can be used to optimize materials and processes. Advanced Structured Materials is indexed in Google Scholar and Scopus.

Dambarudhar Mohanta · Purushottam Chakraborty Editors

Nanoscale Matter and Principles for Sensing and Labeling Applications

Editors Dambarudhar Mohanta Department of Physics Tezpur University Sonitpur, Assam, India

Purushottam Chakraborty Surface Physics and Materials Science Saha Institute of Nuclear Physics Kolkata, West Bengal, India

ISSN 1869-8433 ISSN 1869-8441 (electronic) Advanced Structured Materials ISBN 978-981-99-7847-2 ISBN 978-981-99-7848-9 (eBook) https://doi.org/10.1007/978-981-99-7848-9 © The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024 This work is subject to copyright. All rights are solely and exclusively licensed by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors, and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Singapore Pte Ltd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore Paper in this product is recyclable.

Foreword

“This unique book brings together a wide range of important topics on nanoscale materials for sensing. With a focus on presenting some of the latest research results, it will be of interest to graduate students and researchers who are seeking to understand the way that the chemical, physical, electrical, magnetic, and structural properties of materials and surfaces influence their performance as sensors.” Andrew Kirk Professor, Department of Electrical and Computer Engineering McGill University, Canada

“Sensing and labeling using the materials and ideas at nanoscale is an important and versatile modern area to which this volume brings a rather unique approach. It will be valuable for the scientists at different stages in their career, from graduate students to senior and practising scientists. The chapters are diversified but contemporary which will allow the readers to comprehend both the underlying ideas and technology aspects of the fast-growing field of nanoscale in sensing research.” Ashutosh Sharma Institute Chair Professor, IIT Kanpur President, INSA, New Delhi, India Former Secretary to Government of India and Head DST New Delhi, India

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Foreword

“I am glad that Springer has taken the responsibility to publish the collection of chapters entitled “Nanoscale Matter and Principles for Sensing and Labelling Applications” edited by Prof. D. Mohanta and Prof. P. Chakraborty. It is enough to give the flavour of sensing and labelling applications. I congratulate the authors.” C. N. R. Rao, FRS Linus Pauling Professor JNCSR, Bengaluru, India

Preface

Ever since the dawn of human civilization, there has been an intrinsic human instinct to know about nature and its surroundings through sensory organs, such as eyes for sight, ears for sound, nose for smell, tongue for taste, and skin for touch. All fundamentally express the sensing actions; form and intensity of which largely depend on the genetic and epigenetic factors of individuals that are essentially governed by biophysical and physicochemical courses of nature. On the other hand, men, through creative thinking and analytical skill, can make testbeds and components for detecting and sensing species of interest. Remarkable advancement in novel materials and, at the same time, innovative scientific approaches have helped solve the existing problems and to confront obstreperous challenges. Although energy, environment, health, and hygiene are the main issues of common interest, interdisciplinary pathways may appear to bridge the gaps making science and society go hand in hand in the pursuit of happy and harmonious living. The growth of biological cells through self-regulated gradual mass accumulation has essentially triggered the desire of scientists to replicate the phenomenon by the manipulation of individual atoms and molecules in laboratories. The bottom-up approach adopted in physical or chemical methods essentially deals with the atomby-atom self-assembled growth of nanostructured matters of various size, shape, and morphology. Because of large surface-to-volume ratios, the atoms and molecules in nanoscale materials behave entirely in a different manner exhibiting unusual properties, resulting in appreciably lower consumption of both materials and energy in devices. Concomitantly, innovative experimental methods are being developed to design, develop, and characterize new nanomaterials with improved quality and performances. This volume is merely a handpicked collection of articles unfolding our knowledge and existing challenges in nanoscience and nanotechnology, primarily focusing on principles and scope of sensing and labeling phenomena in various technologically important fields. Obviously, a pertinent question may arise: what is the need of such a book when such a topic is not new and for being regarded as a prime topic of most advanced research? To answer this in one sentence, this volume is an exclusive assortment of new articles describing the current developments and challenges in the frontline areas vii

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Preface

of nanosystem-based sensing. Additionally, two more relevant reasons are invoked: first, the edited volume can help the beginners, graduate students, and researchers who look for a comprehensive guidebook on basic and state-of-the art research related to sensing-based nanoscale materials and phenomena. Second, it can be a reference manual for the practicing scientists and experts who are already into the sensing business. Despite numerous books available on sensing based on the principles of nanotechnology, this book is unique, and also because it covers a wide range of key materials and applications with proper weightage to the necessary theoretical concepts. The chapters are carefully chosen from the contributions of the experts in their domain areas and compiled in the most appropriate manner. Out of 28 chapters, one can easily find that sensing and detection employing optical, chemical, optoelectronic, plasmonic, and secondary ion mass-spectrometry (SIMS) methods form the basis of the entire volume. To name a few: quantumdot or nanoparticle-based sensing fluorescence, humidity, organic medium, heavy metals, explosives, etc., form the core of the book. Carbon dots, rare-earth oxides and compounds, metal-organic framework, reinforced polymer, guest-host interaction as well as physics of bioconjugation and bio-functionality have strengthened the scope of sensing phenomena to a greater extent. Applications in flexible and wearable chemical sensing, as well as sensing of foodborne pathogen, macrolide, antibiotic residue, etc., are certainly noteworthy. A perfect balance between diversity in content and insightful depth is intended for readers, enabling them to refresh their knowledge in sensing and related phenomena. Both nanoscale matter and nanoscale principles are at the verge of sensing at large which, in fact, justify the title of the book. Each chapter, unique in itself, is prepared and edited with extreme care and dedication keeping the interest of the readers of prime importance. It was never an easy task to bring a good number of expert authors, reviewers, and colleagues into the same platform and, especially, when it comes to the documentation of their specialized knowledge. Although words of the book have limitations, but the scope is not. Undoubtedly, starting from inviting manuscripts to reviewing and editing is a Herculean task that involves the participation and support of many. Nevertheless, unfailing effort and goodwill among academia play a big role in making differences even in the time of adversity. One of the purposes was to utilize the Corona pandemic period, and this book is a thriving effort in this context. At the same time, our fellowfeeling will remain forever with those colleagues and family friends who came strong and proved fit to counter the tragedy that mankind has witnessed recently. We do express our heartfelt thanks to all the reviewers who scrupulously reviewed and potentially enriched the quality of chapters by their constructive criticisms and thoughtful comments. Last but not the least, we express our earnest thankfulness and utmost gratitude to those distinguished experts who have generously reviewed the overall volume with their enlightening words. We sincerely hope, the book will create enthusiasm among young researchers and aspirants, particularly those pursuing research in materials science and nanobiotechnology. Keeping aside the application strategies, the overlapping of biotechnology and nanotechnology has also been highlighted in view of generating fundamental interest. We, the editors, are thankful to the publishers and concerned parties for

Preface

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giving permission to the authors to reproduce the figures and textual facts in the relevant chapters. While every effort has been made to make the book simple, clear and flawless as much as possible, some errors may remain inadvertently. The suggestions in this regard will be appreciated. Tezpur, Sonitpur, India Kolkata, India

Dambarudhar Mohanta Purushottam Chakraborty

Contents

1

Alkali Containing Molecular Ions in SIMS: A Cutting-Edge Ion-Beam Technique for Materials Quantification in Nanoscale Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Purushottam Chakraborty

1

2

Quantum-Dot-Based Fluorescence Sensing . . . . . . . . . . . . . . . . . . . . . . T. K. Nideep, M. Ramya, and M. Kailasnath

19

3

Nanomaterial for Humidity Sensor Applications . . . . . . . . . . . . . . . . . Y. T. Ravikiran, CH. V. V. Ramana, S. K. Alla, M. Prashantkumar, B. Arundhati, D. K. Mishra, and Sabu Thomas

53

4

Nanomaterial-Based Sensors for the Detection of Explosives . . . . . . Nasrin Sultana, Samiran Upadhyaya, and Neelotpal Sen Sarma

73

5

Advances in Few-Layered Nanoscale Transition Metal Dichalcogenides in Sensing Application . . . . . . . . . . . . . . . . . . . . . . . . . Ashamoni Neog, Hemanga Jyoti Sarmah, Dambarudhar Mohanta, and Rajib Biswas

95

6

Light Scattering by One-Dimensional ZnO Nanorods and Their Applications in Optical Sensing . . . . . . . . . . . . . . . . . . . . . . . 117 Tanujjal Bora and Waleed S. Mohammed

7

Recent Advances in 1D and 2D ZnO Nanostructure-Based Photosensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Trinayana Deka, Nikhil S. K., Pujita Ningthoukhongjam, Suma Das, and Ranjith G. Nair

8

Recent Strategies for Development of ZnO-Based Efficient UV-Photodetectors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Sayan Bayan

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9

Contents

Sensing Nanomaterials Based on Host–Guest Interactions . . . . . . . . 181 Mahesh Pattabiraman, Elamparuthi Ramasamy, and Vijayakumar Ramalingam

10 Perovskite Nanomaterials as Advanced Optical Sensor . . . . . . . . . . . . 203 Shahnaz Ahmed, Suman Lahkar, and Swapan K. Dolui 11 Metal–Organic Frameworks and Their Composites for Sensing Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 Rituraj Dutta and Kakoli Doloi 12 Electroactive Polymer-Based Nanostructures and Nanocomposites for Sensing Applications . . . . . . . . . . . . . . . . . . . . 243 Bitupon Boruah, Sandeepan Borah, and Madhuryya Deka 13 Nano-Reinforced Polymers and Polymer Nanocomposites . . . . . . . . . 267 Mehdi Sahihi and Fahmi Bedoui 14 Carbon Dots and Their Sensing Behavior in Organic Medium . . . . . 289 Kiranjyoti Mohan, Anindita Bora, and Swapan Kumar Dolui 15 An Overview of Carbon-Based Nanomaterials and Their Derivatives for Different Sensing Applications . . . . . . . . . . . . . . . . . . . 305 Kunal Biswas and Yugal Kishore Mohanta 16 Development of Carbon Dots and Nanohybrids for Biosensing and Bioimaging Relevance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327 Vijay Bhooshan Kumar and Dambarudhar Mohanta 17 Flexible and Wearable Chemical Sensor Based on Graphene Derivatives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349 Hemen Kalita, Anurag Kashyap, Rajesh Ghosh, and Biswajit Dehingia 18 Pulsed Laser-Mediated Phototherapeutic Mechanisms for Biomedical Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 369 L. Sophia Jacquline, Pooja Naik, and Junaid Masud Laskar 19 Plasmonic Nanostructures for the Detection of Foodborne Pathogens . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 389 Htet Htet Kyaw, Myo Tay Zar Myint, and Salim H. Al-Harthi 20 Morphology-Dependent Biosensing of Metallic Nanoparticles . . . . . 407 Barnika Chakraborty, Rachana Yadwade, and Balaprasad Ankamwar

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21 Structural and Optical Phenomena of Thermally Treated Fullerene-Based Nanocomposites with Metal Nanoparticles for Sensing Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 429 Amena Salim, Ritu Vishnoi, Vikesh Chaudhary, Himanshu Dixit, Umesh K. Dwivedi, Pushpendra Kumar, Sunita Bishnoi, Sanjeev Aggarwal, G. D. Sharma, K. Venkataratnam Kamma, and R. Singhal 22 Surface Plasmon Resonance (SPR) Biosensors for Antibiotic Residue Detection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447 Le Thi Thanh Hiep, Khajohnpat Teerasitwaratorn, and Tanujjal Bora 23 Advances in Luminescence-Based Biosensing with Quantum Dots . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 469 Debasmita Sinha Ghosh and Abhijit Saha 24 Recent Advances in Rare-Earth Based Persistent Luminescent Probes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 491 Aftab Ansari and Dambarudhar Mohanta 25 Nanomaterial-Based Sensors for Macrolide Sensing . . . . . . . . . . . . . . 513 Noha Hasaneen, Pratishtha Khurana, Rama Pulicharla, Pouya Rezai, and Satinder Kaur Brar 26 The Physics of Biofunctionality in Nanoconfined Systems . . . . . . . . . 537 Alokmay Datta 27 Development of Rapidly Quenched Amorphous-Nanostructured Materials for Sensor Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 551 Somnath Das, Rajat Kumar Roy, Dev Kumar Mahato, and Ashis Kumar Panda 28 Magnetic Nanostructures for Transport Control and Sensing Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 563 Dipti R. Sahu

About the Editors

Dambarudhar Mohanta is Professor at the Department of Physics, Tezpur University, Assam, India, which he joined as Lecturer in 1998. Earlier, he worked as UGC/CSIR-NET JRF at the Department of Physics, Utkal University, Bhubaneswar, Odisha, for about a year. He obtained his Master’s degree in Physics from Maharaja Purna Chandra College, Utkal University, and Ph.D. from Tezpur University, respectively, in 1994 and 2004. After his Ph.D., he availed the Summer Teacher Fellowship and worked at Physical Research Laboratory, Ahmedabad, and at S. N. Bose National Centre for Basic Sciences, Kolkata, respectively, in 2003 and 2006. A long term association with Inter University Accelerator Centre (IUAC), New Delhi has also helped him pursue distinct and diverse research avenues. He received the BOYSCAST Fellowship from DSTSERB, New Delhi, during 2006–2007 and worked at the Department of Computer and Electrical Engineering, University of Wisconsin-Madison, USA. He has visited several countries on academic pursuits and presented conference papers at National Institute for Nuclear Physics, Italy (2003), National University of Singapore (2009), and Aristotle University, Thessaloniki, Greece (2011). He was awarded Indo-US Research Fellowship during 2011–2012 to work in the School of Engineering and Applied Sciences, Harvard University, USA. With a student, one of his articles published in the Bulletin of Materials Science bagged the Material Research Society of India (MRSI) best paper award for the year 2012. He is a life member of MRSI, Indian Physics Association (IPA), Indian xv

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About the Editors

Physical Society (IPS), Orissa Physical Society (OPS) and a regular member of American Physical Society (APS), MRS, Optical Society of America (OSA), and Optical Society of India (OSI). With more than 140 papers, including review articles, papers in proceedings, book chapters, and technical reports, he has supervised fifteen PhD theses and many Masters’ projects. His current research interest includes optoelectronic features of nanoscale semiconductors and rare-earth oxides, 2D materials, radiation-induced phenomena, nano-bio interface, electrochemical and biosensing, biophotonics, and soft matter physics. Purushottam Chakraborty is a former Senior Professor of Physics at the Surface Physics and Materials Science Division, Saha Institute of Nuclear Physics, Kolkata, India, and a former Adjunct Professor of Physics, University of Pretoria, South Africa. With more than 150 research articles including reviews, monographs, and invited book chapters, he is Editor of the books, Ion Beam Analysis of Surfaces and Interfaces of Condensed Matter Systems, Photonic Materials, Encyclopaedia of Materials: Electronics, and Low-dimensional Materials, Systems and Applications. He also is a regular contributor to the Journal of Physics. A leading expert on materials analysis using ion beams, Prof. Chakraborty was awarded the “Most Eminent Mass Spectrometrist of India” and conferred with the gold medal by the Department of Atomic Energy, the Government of India, for his outstanding contributions in secondary ion mass spectrometry (SIMS). He received the “Premchand Roychand Scholarship” and the “Mouat Medal” of the University of Calcutta. His research areas include atomic collisions in solids, ion-beam modifications and analysis, low-dimensional materials, X-UV optics, nonlinear optics, photonics, etc. He is an elected Fellow of the West Bengal Academy of Science and Technology and the Indian Chemical Society. He indigenously fabricated an RF-quadrupole mass spectrometer for the first time in India. His “MCsn+ molecular-ion based SIMS” is considered to be innovative for compositional analysis of nanostructured materials. His work on the fabrication of “layered synthetic microstructures (LSM)” is recognized as a pioneering contribution in the realization of optical

About the Editors

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devices for the extreme ultraviolet to soft X-rays. His works on “ion beam synthesis of metal-glass nanocomposites” have led to the remarkable achievements in the development of novel photonic materials. Professor Chakraborty worked at FOM-Institute for Atomic and Molecular Physics, the Netherlands; International Centre for Theoretical Physics (ICTP) and Padova University, in Italy; Laval University, Canada; Osaka Electro-Communication University, Japan; University of Pretoria, South Africa; Pontifical Catholic University of Rio de Janeiro, Brazil; etc. He delivered lectures at Imperial College, London, UK; Maria Curie-Skłodowska University and Polish Academy of Science in Poland; Vanderbilt University, IBM T. J. Watson Research Centre, Furman University, Yale University, and Rutgers University, in the USA; Bielefeld University, Friedrich Schiller University, and Kaiserslautern University, in Germany; University of Western Australia; Newcastle University, UK; Chinese Academy of Science, Kyoto University, and Spring8, in Japan; Witwatersrand University, iThemba Labs for Accelerator Science, Nelson Mandela Metropolitan University in South Africa; Asian Institute of Technology in Thailand, Tata Institute of Fundamental Research (TIFR), several Indian Institute of Technology, Tezpur University, Lucknow University, University of Delhi, International School of Photonics, etc. in India.

Chapter 1

Alkali Containing Molecular Ions in SIMS: A Cutting-Edge Ion-Beam Technique for Materials Quantification in Nanoscale Systems Purushottam Chakraborty

Abstract Secondary Ion Mass Spectrometry (SIMS) is an extremely powerful and sensitive ion-beam technique for detection and quantification in materials. Extent of secondary ions of a specific species in a sample sturdily depends on instantaneous local surface chemistry of that sample causing a strong variation in ionization cross section of the emitted species. This is so-called “Matrix Effect”, which makes the SIMS technique challenging for quantitative analysis of materials, even though the technique has highest detection sensitivity (