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Advanced Structured Materials
Dambarudhar Mohanta Purushottam Chakraborty Editors
Nanoscale Matter and Principles for Sensing and Labeling Applications
Advanced Structured Materials Volume 206
Series Editors Andreas Öchsner, Faculty of Mechanical and Systems Engineering, Esslingen University of Applied Sciences, Esslingen, Germany Lucas F. M. da Silva, Department of Mechanical Engineering, Faculty of Engineering, University of Porto, Porto, Portugal Holm Altenbach , Faculty of Mechanical Engineering, Otto von Guericke University Magdeburg, Magdeburg, Sachsen-Anhalt, Germany
Common engineering materials are reaching their limits in many applications, and new developments are required to meet the increasing demands on engineering materials. The performance of materials can be improved by combining different materials to achieve better properties than with a single constituent, or by shaping the material or constituents into a specific structure. The interaction between material and structure can occur at different length scales, such as the micro, meso, or macro scale, and offers potential applications in very different fields. This book series addresses the fundamental relationships between materials and their structure on overall properties (e.g., mechanical, thermal, chemical, electrical, or magnetic properties, etc.). Experimental data and procedures are presented, as well as methods for modeling structures and materials using numerical and analytical approaches. In addition, the series shows how these materials engineering and design processes are implemented and how new technologies can be used to optimize materials and processes. Advanced Structured Materials is indexed in Google Scholar and Scopus.
Dambarudhar Mohanta · Purushottam Chakraborty Editors
Nanoscale Matter and Principles for Sensing and Labeling Applications
Editors Dambarudhar Mohanta Department of Physics Tezpur University Sonitpur, Assam, India
Purushottam Chakraborty Surface Physics and Materials Science Saha Institute of Nuclear Physics Kolkata, West Bengal, India
ISSN 1869-8433 ISSN 1869-8441 (electronic) Advanced Structured Materials ISBN 978-981-99-7847-2 ISBN 978-981-99-7848-9 (eBook) https://doi.org/10.1007/978-981-99-7848-9 © The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024 This work is subject to copyright. All rights are solely and exclusively licensed by the Publisher, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission or information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. The publisher, the authors, and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained herein or for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. This Springer imprint is published by the registered company Springer Nature Singapore Pte Ltd. The registered company address is: 152 Beach Road, #21-01/04 Gateway East, Singapore 189721, Singapore Paper in this product is recyclable.
Foreword
“This unique book brings together a wide range of important topics on nanoscale materials for sensing. With a focus on presenting some of the latest research results, it will be of interest to graduate students and researchers who are seeking to understand the way that the chemical, physical, electrical, magnetic, and structural properties of materials and surfaces influence their performance as sensors.” Andrew Kirk Professor, Department of Electrical and Computer Engineering McGill University, Canada
“Sensing and labeling using the materials and ideas at nanoscale is an important and versatile modern area to which this volume brings a rather unique approach. It will be valuable for the scientists at different stages in their career, from graduate students to senior and practising scientists. The chapters are diversified but contemporary which will allow the readers to comprehend both the underlying ideas and technology aspects of the fast-growing field of nanoscale in sensing research.” Ashutosh Sharma Institute Chair Professor, IIT Kanpur President, INSA, New Delhi, India Former Secretary to Government of India and Head DST New Delhi, India
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“I am glad that Springer has taken the responsibility to publish the collection of chapters entitled “Nanoscale Matter and Principles for Sensing and Labelling Applications” edited by Prof. D. Mohanta and Prof. P. Chakraborty. It is enough to give the flavour of sensing and labelling applications. I congratulate the authors.” C. N. R. Rao, FRS Linus Pauling Professor JNCSR, Bengaluru, India
Preface
Ever since the dawn of human civilization, there has been an intrinsic human instinct to know about nature and its surroundings through sensory organs, such as eyes for sight, ears for sound, nose for smell, tongue for taste, and skin for touch. All fundamentally express the sensing actions; form and intensity of which largely depend on the genetic and epigenetic factors of individuals that are essentially governed by biophysical and physicochemical courses of nature. On the other hand, men, through creative thinking and analytical skill, can make testbeds and components for detecting and sensing species of interest. Remarkable advancement in novel materials and, at the same time, innovative scientific approaches have helped solve the existing problems and to confront obstreperous challenges. Although energy, environment, health, and hygiene are the main issues of common interest, interdisciplinary pathways may appear to bridge the gaps making science and society go hand in hand in the pursuit of happy and harmonious living. The growth of biological cells through self-regulated gradual mass accumulation has essentially triggered the desire of scientists to replicate the phenomenon by the manipulation of individual atoms and molecules in laboratories. The bottom-up approach adopted in physical or chemical methods essentially deals with the atomby-atom self-assembled growth of nanostructured matters of various size, shape, and morphology. Because of large surface-to-volume ratios, the atoms and molecules in nanoscale materials behave entirely in a different manner exhibiting unusual properties, resulting in appreciably lower consumption of both materials and energy in devices. Concomitantly, innovative experimental methods are being developed to design, develop, and characterize new nanomaterials with improved quality and performances. This volume is merely a handpicked collection of articles unfolding our knowledge and existing challenges in nanoscience and nanotechnology, primarily focusing on principles and scope of sensing and labeling phenomena in various technologically important fields. Obviously, a pertinent question may arise: what is the need of such a book when such a topic is not new and for being regarded as a prime topic of most advanced research? To answer this in one sentence, this volume is an exclusive assortment of new articles describing the current developments and challenges in the frontline areas vii
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of nanosystem-based sensing. Additionally, two more relevant reasons are invoked: first, the edited volume can help the beginners, graduate students, and researchers who look for a comprehensive guidebook on basic and state-of-the art research related to sensing-based nanoscale materials and phenomena. Second, it can be a reference manual for the practicing scientists and experts who are already into the sensing business. Despite numerous books available on sensing based on the principles of nanotechnology, this book is unique, and also because it covers a wide range of key materials and applications with proper weightage to the necessary theoretical concepts. The chapters are carefully chosen from the contributions of the experts in their domain areas and compiled in the most appropriate manner. Out of 28 chapters, one can easily find that sensing and detection employing optical, chemical, optoelectronic, plasmonic, and secondary ion mass-spectrometry (SIMS) methods form the basis of the entire volume. To name a few: quantumdot or nanoparticle-based sensing fluorescence, humidity, organic medium, heavy metals, explosives, etc., form the core of the book. Carbon dots, rare-earth oxides and compounds, metal-organic framework, reinforced polymer, guest-host interaction as well as physics of bioconjugation and bio-functionality have strengthened the scope of sensing phenomena to a greater extent. Applications in flexible and wearable chemical sensing, as well as sensing of foodborne pathogen, macrolide, antibiotic residue, etc., are certainly noteworthy. A perfect balance between diversity in content and insightful depth is intended for readers, enabling them to refresh their knowledge in sensing and related phenomena. Both nanoscale matter and nanoscale principles are at the verge of sensing at large which, in fact, justify the title of the book. Each chapter, unique in itself, is prepared and edited with extreme care and dedication keeping the interest of the readers of prime importance. It was never an easy task to bring a good number of expert authors, reviewers, and colleagues into the same platform and, especially, when it comes to the documentation of their specialized knowledge. Although words of the book have limitations, but the scope is not. Undoubtedly, starting from inviting manuscripts to reviewing and editing is a Herculean task that involves the participation and support of many. Nevertheless, unfailing effort and goodwill among academia play a big role in making differences even in the time of adversity. One of the purposes was to utilize the Corona pandemic period, and this book is a thriving effort in this context. At the same time, our fellowfeeling will remain forever with those colleagues and family friends who came strong and proved fit to counter the tragedy that mankind has witnessed recently. We do express our heartfelt thanks to all the reviewers who scrupulously reviewed and potentially enriched the quality of chapters by their constructive criticisms and thoughtful comments. Last but not the least, we express our earnest thankfulness and utmost gratitude to those distinguished experts who have generously reviewed the overall volume with their enlightening words. We sincerely hope, the book will create enthusiasm among young researchers and aspirants, particularly those pursuing research in materials science and nanobiotechnology. Keeping aside the application strategies, the overlapping of biotechnology and nanotechnology has also been highlighted in view of generating fundamental interest. We, the editors, are thankful to the publishers and concerned parties for
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giving permission to the authors to reproduce the figures and textual facts in the relevant chapters. While every effort has been made to make the book simple, clear and flawless as much as possible, some errors may remain inadvertently. The suggestions in this regard will be appreciated. Tezpur, Sonitpur, India Kolkata, India
Dambarudhar Mohanta Purushottam Chakraborty
Contents
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Alkali Containing Molecular Ions in SIMS: A Cutting-Edge Ion-Beam Technique for Materials Quantification in Nanoscale Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Purushottam Chakraborty
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Quantum-Dot-Based Fluorescence Sensing . . . . . . . . . . . . . . . . . . . . . . T. K. Nideep, M. Ramya, and M. Kailasnath
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Nanomaterial for Humidity Sensor Applications . . . . . . . . . . . . . . . . . Y. T. Ravikiran, CH. V. V. Ramana, S. K. Alla, M. Prashantkumar, B. Arundhati, D. K. Mishra, and Sabu Thomas
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Nanomaterial-Based Sensors for the Detection of Explosives . . . . . . Nasrin Sultana, Samiran Upadhyaya, and Neelotpal Sen Sarma
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Advances in Few-Layered Nanoscale Transition Metal Dichalcogenides in Sensing Application . . . . . . . . . . . . . . . . . . . . . . . . . Ashamoni Neog, Hemanga Jyoti Sarmah, Dambarudhar Mohanta, and Rajib Biswas
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Light Scattering by One-Dimensional ZnO Nanorods and Their Applications in Optical Sensing . . . . . . . . . . . . . . . . . . . . . . . 117 Tanujjal Bora and Waleed S. Mohammed
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Recent Advances in 1D and 2D ZnO Nanostructure-Based Photosensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Trinayana Deka, Nikhil S. K., Pujita Ningthoukhongjam, Suma Das, and Ranjith G. Nair
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Recent Strategies for Development of ZnO-Based Efficient UV-Photodetectors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Sayan Bayan
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Sensing Nanomaterials Based on Host–Guest Interactions . . . . . . . . 181 Mahesh Pattabiraman, Elamparuthi Ramasamy, and Vijayakumar Ramalingam
10 Perovskite Nanomaterials as Advanced Optical Sensor . . . . . . . . . . . . 203 Shahnaz Ahmed, Suman Lahkar, and Swapan K. Dolui 11 Metal–Organic Frameworks and Their Composites for Sensing Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225 Rituraj Dutta and Kakoli Doloi 12 Electroactive Polymer-Based Nanostructures and Nanocomposites for Sensing Applications . . . . . . . . . . . . . . . . . . . . 243 Bitupon Boruah, Sandeepan Borah, and Madhuryya Deka 13 Nano-Reinforced Polymers and Polymer Nanocomposites . . . . . . . . . 267 Mehdi Sahihi and Fahmi Bedoui 14 Carbon Dots and Their Sensing Behavior in Organic Medium . . . . . 289 Kiranjyoti Mohan, Anindita Bora, and Swapan Kumar Dolui 15 An Overview of Carbon-Based Nanomaterials and Their Derivatives for Different Sensing Applications . . . . . . . . . . . . . . . . . . . 305 Kunal Biswas and Yugal Kishore Mohanta 16 Development of Carbon Dots and Nanohybrids for Biosensing and Bioimaging Relevance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327 Vijay Bhooshan Kumar and Dambarudhar Mohanta 17 Flexible and Wearable Chemical Sensor Based on Graphene Derivatives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349 Hemen Kalita, Anurag Kashyap, Rajesh Ghosh, and Biswajit Dehingia 18 Pulsed Laser-Mediated Phototherapeutic Mechanisms for Biomedical Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 369 L. Sophia Jacquline, Pooja Naik, and Junaid Masud Laskar 19 Plasmonic Nanostructures for the Detection of Foodborne Pathogens . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 389 Htet Htet Kyaw, Myo Tay Zar Myint, and Salim H. Al-Harthi 20 Morphology-Dependent Biosensing of Metallic Nanoparticles . . . . . 407 Barnika Chakraborty, Rachana Yadwade, and Balaprasad Ankamwar
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21 Structural and Optical Phenomena of Thermally Treated Fullerene-Based Nanocomposites with Metal Nanoparticles for Sensing Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 429 Amena Salim, Ritu Vishnoi, Vikesh Chaudhary, Himanshu Dixit, Umesh K. Dwivedi, Pushpendra Kumar, Sunita Bishnoi, Sanjeev Aggarwal, G. D. Sharma, K. Venkataratnam Kamma, and R. Singhal 22 Surface Plasmon Resonance (SPR) Biosensors for Antibiotic Residue Detection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 447 Le Thi Thanh Hiep, Khajohnpat Teerasitwaratorn, and Tanujjal Bora 23 Advances in Luminescence-Based Biosensing with Quantum Dots . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 469 Debasmita Sinha Ghosh and Abhijit Saha 24 Recent Advances in Rare-Earth Based Persistent Luminescent Probes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 491 Aftab Ansari and Dambarudhar Mohanta 25 Nanomaterial-Based Sensors for Macrolide Sensing . . . . . . . . . . . . . . 513 Noha Hasaneen, Pratishtha Khurana, Rama Pulicharla, Pouya Rezai, and Satinder Kaur Brar 26 The Physics of Biofunctionality in Nanoconfined Systems . . . . . . . . . 537 Alokmay Datta 27 Development of Rapidly Quenched Amorphous-Nanostructured Materials for Sensor Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 551 Somnath Das, Rajat Kumar Roy, Dev Kumar Mahato, and Ashis Kumar Panda 28 Magnetic Nanostructures for Transport Control and Sensing Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 563 Dipti R. Sahu
About the Editors
Dambarudhar Mohanta is Professor at the Department of Physics, Tezpur University, Assam, India, which he joined as Lecturer in 1998. Earlier, he worked as UGC/CSIR-NET JRF at the Department of Physics, Utkal University, Bhubaneswar, Odisha, for about a year. He obtained his Master’s degree in Physics from Maharaja Purna Chandra College, Utkal University, and Ph.D. from Tezpur University, respectively, in 1994 and 2004. After his Ph.D., he availed the Summer Teacher Fellowship and worked at Physical Research Laboratory, Ahmedabad, and at S. N. Bose National Centre for Basic Sciences, Kolkata, respectively, in 2003 and 2006. A long term association with Inter University Accelerator Centre (IUAC), New Delhi has also helped him pursue distinct and diverse research avenues. He received the BOYSCAST Fellowship from DSTSERB, New Delhi, during 2006–2007 and worked at the Department of Computer and Electrical Engineering, University of Wisconsin-Madison, USA. He has visited several countries on academic pursuits and presented conference papers at National Institute for Nuclear Physics, Italy (2003), National University of Singapore (2009), and Aristotle University, Thessaloniki, Greece (2011). He was awarded Indo-US Research Fellowship during 2011–2012 to work in the School of Engineering and Applied Sciences, Harvard University, USA. With a student, one of his articles published in the Bulletin of Materials Science bagged the Material Research Society of India (MRSI) best paper award for the year 2012. He is a life member of MRSI, Indian Physics Association (IPA), Indian xv
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Physical Society (IPS), Orissa Physical Society (OPS) and a regular member of American Physical Society (APS), MRS, Optical Society of America (OSA), and Optical Society of India (OSI). With more than 140 papers, including review articles, papers in proceedings, book chapters, and technical reports, he has supervised fifteen PhD theses and many Masters’ projects. His current research interest includes optoelectronic features of nanoscale semiconductors and rare-earth oxides, 2D materials, radiation-induced phenomena, nano-bio interface, electrochemical and biosensing, biophotonics, and soft matter physics. Purushottam Chakraborty is a former Senior Professor of Physics at the Surface Physics and Materials Science Division, Saha Institute of Nuclear Physics, Kolkata, India, and a former Adjunct Professor of Physics, University of Pretoria, South Africa. With more than 150 research articles including reviews, monographs, and invited book chapters, he is Editor of the books, Ion Beam Analysis of Surfaces and Interfaces of Condensed Matter Systems, Photonic Materials, Encyclopaedia of Materials: Electronics, and Low-dimensional Materials, Systems and Applications. He also is a regular contributor to the Journal of Physics. A leading expert on materials analysis using ion beams, Prof. Chakraborty was awarded the “Most Eminent Mass Spectrometrist of India” and conferred with the gold medal by the Department of Atomic Energy, the Government of India, for his outstanding contributions in secondary ion mass spectrometry (SIMS). He received the “Premchand Roychand Scholarship” and the “Mouat Medal” of the University of Calcutta. His research areas include atomic collisions in solids, ion-beam modifications and analysis, low-dimensional materials, X-UV optics, nonlinear optics, photonics, etc. He is an elected Fellow of the West Bengal Academy of Science and Technology and the Indian Chemical Society. He indigenously fabricated an RF-quadrupole mass spectrometer for the first time in India. His “MCsn+ molecular-ion based SIMS” is considered to be innovative for compositional analysis of nanostructured materials. His work on the fabrication of “layered synthetic microstructures (LSM)” is recognized as a pioneering contribution in the realization of optical
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devices for the extreme ultraviolet to soft X-rays. His works on “ion beam synthesis of metal-glass nanocomposites” have led to the remarkable achievements in the development of novel photonic materials. Professor Chakraborty worked at FOM-Institute for Atomic and Molecular Physics, the Netherlands; International Centre for Theoretical Physics (ICTP) and Padova University, in Italy; Laval University, Canada; Osaka Electro-Communication University, Japan; University of Pretoria, South Africa; Pontifical Catholic University of Rio de Janeiro, Brazil; etc. He delivered lectures at Imperial College, London, UK; Maria Curie-Skłodowska University and Polish Academy of Science in Poland; Vanderbilt University, IBM T. J. Watson Research Centre, Furman University, Yale University, and Rutgers University, in the USA; Bielefeld University, Friedrich Schiller University, and Kaiserslautern University, in Germany; University of Western Australia; Newcastle University, UK; Chinese Academy of Science, Kyoto University, and Spring8, in Japan; Witwatersrand University, iThemba Labs for Accelerator Science, Nelson Mandela Metropolitan University in South Africa; Asian Institute of Technology in Thailand, Tata Institute of Fundamental Research (TIFR), several Indian Institute of Technology, Tezpur University, Lucknow University, University of Delhi, International School of Photonics, etc. in India.
Chapter 1
Alkali Containing Molecular Ions in SIMS: A Cutting-Edge Ion-Beam Technique for Materials Quantification in Nanoscale Systems Purushottam Chakraborty
Abstract Secondary Ion Mass Spectrometry (SIMS) is an extremely powerful and sensitive ion-beam technique for detection and quantification in materials. Extent of secondary ions of a specific species in a sample sturdily depends on instantaneous local surface chemistry of that sample causing a strong variation in ionization cross section of the emitted species. This is so-called “Matrix Effect”, which makes the SIMS technique challenging for quantitative analysis of materials, even though the technique has highest detection sensitivity (