Solkane 404A Thermodynamics

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SOLVAY FLUOR

SOLKANE® - INFORMATION SERVICE

Solkane® 404A Thermodynamics

SOLVAY FLUOR Technical Service - Refrigerants Product Bulletin no.: T/09.04/02/E

P.O. Box 220 30002 Hannover Hans-Boeckler-Allee 20 30173 Hannover / Germany

Phone Fax E-Mail Internet:

+49/511/857-2653 +49/511/857-2166 [email protected] www.solvay-fluor.com

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CONTENTS 1

UNITS AND SYMBOLS ............................................................................................. 3

2

INTRODUCTION ....................................................................................................... 5

3

THERMOPHYSICAL VALUES .................................................................................... 6 3.1 PHYSICAL DATA ....................................................................................................... 6 3.2 BASIS OF THERMODYNAMIC CALCULATION ................................................................... 7 3.3 TRANSPORT PROPERTIES .......................................................................................... 10 3.3.1 Dynamic Viscosity of Saturated Liquid ...................................................... 10 3.3.2 Dynamic Viscosity of Saturated and Superheated Vapour ....................... 11 3.3.3 Thermal Conductivity of Saturated Liquid................................................. 13 3.3.4 Thermal Conductivity of Saturated Vapour .............................................. 14 3.3.5 Surface Tension .......................................................................................... 15 3.3.6 Specific Heat Capacity of Saturated Liquid ............................................... 16

4

COMPATIBILITY OF MATERIALS ........................................................................... 17 4.1 ELASTOMERES ........................................................................................................ 17 4.2 THERMOPLASTICS ................................................................................................... 17 4.3 METALS ................................................................................................................ 17

5

REFRIGERANT OILS................................................................................................ 18

6

FLAMMABILITY ..................................................................................................... 20

7

TOXICITY ............................................................................................................... 20

8

VAPOUR TABLE, WET VAPOUR RANGE SOLKANE® 404A................................... 21

9

VAPOUR TABLE, SUPERHEATED RANGE SOLKANE® 404A ................................. 25

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1 Units and Symbols Symbol

Unit

A, B C D

[-] [-] [kJ/(kgK)]

E, F, G I J K L M N O P R b c e h k p r s t t v η λ ρ σ

Meaning/Definition

Parameters of the Wagner equation Parameter of the equation for density of boiling liquid Parameter of the equation for specific heat capacity in an ideal gas state [-] Parameter of the Martin-Hou equation [-] Parameter of the equation for dynamic viscosity of vapour [-] Parameter for the boiling liquid enthalpy equation [kJ/(kgK)] Parameter for the boiling liquid entropy equation [Pa s /K] Parameter of the equation for dynamic viscosity of liquid [W/(m K)] parameter of the equation for thermal conductivity of the saturated liquid [W/(m K)] Parameter of the equation for thermal conductivity of the saturated vapour [N/(m K)] Parameter of the equation for surface tension [kJ/(kg K)] parameter of the equation for specific heat capacity of the saturated liquid 3 [bar m /(kg K)] Gas constant [m3/kg)] Parameter of the Martin-Hou equation [kJ/(kg K)] Specific heat capacity [kJ/kg] Specific exergy [kJ/kg] Specific enthalpy [-] Parameter of the Martin-Hou equation [bar] Pressure [kJ/kg] Enthalpy of vaporisation [kJ/(kg K)] Specific entropy [°C] Temperature [K] Temperature [m3/kg] Specific volume [Pa s] Dynamic viscosity [W/(m K)] Thermal conductivity [kg/m3] Density [N/m] Surface tension

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Indices

´ ´´ c r i u p v 0

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Liquid Vapour critical value reduced value run index ambient conditions Isobar Isochor ideal gas

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2 Introduction The refrigerant Solkane®404A is a long-term replacement for R502 and R22 in low temperature refrigeration. As R502 consists of 48.8% R22 and 51.2% R115 by weight, its production has been stopped since several years in developed countries1 because of its content of R115, a chlorofluorocarbon (CFC) with an ozone depletion potential (ODP) of 0.6. The ozone depletion potential of the hydrochlorofluorocarbon (HCFC) R22 is reduced to a fraction of the ODPs of chlorofluorocarbons. R22 is therefore regarded as an intermediate solution. The use of HCFCs will be gradually reduced and these products will finally be banned. By 2030 the production of HCFCs will be phased out in developed countries1. Accelerated phase out scenarios may apply in selected countries especially in Europe. Solkane®404A is a near-azeotrope blend with a temperature glide of approx. 0.8 K. It consists of 44 % R125 (CF3CHF2), 52 % R143a (CF3CH3) and 4 % R134a (CF3CH2F) by weight. The hydrofluorocarbons (HFC) R125, R143a and R134a contain only carbon, fluorine and hydrogen. They do not contribute to the depletion of the stratospheric ozone layer. The global warming potential is significantly reduced compared to the CFCs. Solkane®404A can be used in new equipment and also in retrofitted R502 equipment. Solkane®404A is non-flammable. Its toxicity is low and comparable to that of R502. The environmental behaviour and the handling of Solkane®404A are described in the material safety data sheet2 and in the environmental compatibility brochure3.

1

In the sence of Montreal Protocol (1995 Vienna meeting) Order by Fax : +49 (0) 511 857 2146 3 see Thermodynamics Solkane 507 2

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3 Thermophysical Values 3.1 Physical Data Chemical name

[-]

Pentafluoroethane/ 1,1,1-Trifluoroethane 1,1,1,2-Tetrafluoroethane

1

Chemical formula

[-]

CF3CHF2 /CF3CH3 /CF3CH2 F

CAS No.

[-]

Molecular weight

[kg/kmol]

97.6

Boiling point1

[°C]

-46.6

Temperature glide

[K]

0.8

Freezing point1

[°C]

-101

Critical temperature

[°C]

72.1

Critical pressure

[bar]

37.4

Saturated liquid density2

[kg/m3]

1045

Saturated vapour density2

[kg/m3]

65.35

Vapour pressure2

[bar]

12.45

Enthalpy of vaporization2

[kJ/kg]

140.1

Liquid thermal conductivity2

[W/m K]

0.066

Surface tension of liquid2

[N/m]

Specific heat capacity of liquid2

[kJ/(kgK)]

1.541

Specific heat capacity of vapour2

[kJ/(kgK)]

1.200

Liquid viscosity2

[Pa s]

0.1245 x10-3

Saturated vapour viscocity2

[Pa s]

12.097 x10-6

Flammability limit in air1

[Vol.-%]

None3

150743-07-0

4.437 x10-3

at 1.013 bar

2 at 25oC and saturated conditions 3 according to DIN 51649 and UL 2128

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3.2 Basis of Thermodynamic Calculation The thermodynamic calculation equations have been adapted to ISO/DIS 17584, as at 12/2003. They fulfil this standard with the exception of the thermal capacities in a saturated state of 0.65 < TR < 0.95 and in an overheated state of 0.05MPa < p < 2.5MPa and Tmax = 475K. The Wagner equation

(

)

ln p R = A1 (1 − TR ) + A2 (1 − TR ) 1 + A3 (1 − TR ) 2 + A4 (1 − TR ) 3 + A5 (1 − TR ) B4 + A6 TR

where TR =

B

B

B

(1)

T p and p R = Tc pc

was chosen to describe the bubble and dew pressures. The constants and values for the critical pressure pc and the critical pressure Tc are as follows:

A1 A2 A3 A4 A5 A6 B1 B2 B3 B4 Tc pc

Boiling line [-] -7.60299407 [-] 3.731263605 [-] -7.79162519 [-] 11.51536845 [-] -9.44588683 [-] 0.001223648 [-] 1.5 [-] 2.0 [-] 2.5 [-] 3 [K] 345.29 [bar] 37.35

Dew line -7.81307914 4.859254488 -11.0987729 16.29371703 -12.3673965 -0.00055455 1.5 2.0 2.5 3

The density of the boiling liquid is described by the equation

ρ ′R = 1 + C1 (1 − TR ) 3 + C2 (1 − TR ) 3 + C3 (1 − TR ) + C4 (1 − TR ) 1

where ρ ′R =

2

4

(2)

3

ρ′ . ρc

The constants and the value for the critical density are: C1 C2 C3

[-] [-] [-]

1.680265 1.410642 -1.222830

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C4 ρc

[-] [kg/m3]

0.953230 488.46

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The specific heat capacity under ideal gas conditions is represented by the equation c p 0 = D1 + D2T + D3T 2 + D4T 3 + D5 T

(3)

The coefficients are: D1 D2 D3

[kJ/(kg K)] [kJ/(kg K2)] [kJ/kg]

2.58689E-01 2.24187E-03 -2.13810E-07

D4 D5

[kJ/(kg K3)] [kJ/kg]

-1.18590E-09 -4.18094E+00

The equation of state according to Martin-Hou is p=

RT E1 + F1T + G1e − kTR E 2 + F2T + G2 e − kTR E3 E 4 + F4T + G4 e − kTR + + + 4 + z z2 z3 z z5

and is a good representation of the pvT relationship for Solkane® 404A. coefficients of the equation are: E1 E2 E3 E4 F1 B R

[-] [-] [-] [-] [-] [m3/kg] [bar m3/(kgK)]

-1.29414E-03 6.22058E-07 -5.30396E-11 -8.56937E-12 1.89444E-06 -3.26856E-04 8.51861E-04

F2 F4 G1 G2 G4 k

[-] [-] [-] [-] [-] [-]

(4) The

3.10589E-11 1.75766E-14 -2.59156E-02 -1.67442E-05 7.17681E-10 5.475

with z = v − b . The equation for specific heat capacity under ideal gas conditions (3) and the thermal equation of state (4) form the basis of the specific enthalpy and entropy calculation. E E E E T2 T3 + D3 + D4 ln T + 1 + 22 + 33 + 44 z 2z 2 3 3z 4z G G  G ⋅ (1 + k ⋅ TR ) ⋅  1 + 22 + 44  4z   z 2z

h = H 0 + ( pv - RT ) + D1T + D2 + e -k ⋅TR

(5)

and

T 2 D4  zp  − s = S 0 + R ln 1  + D1 ⋅ ln T + D2T + D3 2 T  RT  G G  F F  k G F -  1 + 22 + 44  + e -k ⋅TR  1 + 22 + 44  4 z  Tc 4z   z 2z  z 2z

(6)

with z = v − b and p1=1,013bar. For the boiling liquid, enthalpy and entropy are calculated with the following equations :

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h ' = J 1 + J 2 (1 − TR ) + J 3 (1 − TR ) + J 4 (1 − TR ) 2

3

+ J 5 (1 − TR ) + J 6 (1 − TR ) 4

5

s ' = 1 + K 1t + K 2 t 2 + K 3t 3 + K 4 t 4

(7)

(8)

The temperature t for the calculation of the entropy is in °C and the parameters for both integrated formulas are : J1 [-] 325.5684358 J6 [-] -13610.9110 2 J2 [-] -892.994422 K1 [kJ/(kgK )] 0.004956173 J3 [-] 2768.458005 K2 [kJ/(kgK3)] 2.40679e-6 J4 [-] -9807.73400 K3 [kJ/(kgK4)] 7.86992e-8 J5 [-] 18427.02151 K4 [kJ/(kgK5)] -5.2699e-10

If neither the kinetic nor the potential energies are taken into account, the specific exergy may be found by the following equation: e = h − hu − Tu ( s − su )

(9)

where the subscript u indicates ambient conditions. The saturation pressure of the substance at Tu = 290 K serves as the reference pressure. The integration constants hu and su are found by letting

h’(t = 0°C)= 200.0 kJ/kg s’(t = 0°C)= 1.000 kJ/(kgK) H0 = 250.492 S0 = -0.269

to be

hu su

= =

224.02 kJ/kg 1.0832 kJ/(kg K)

so the specific exergy is e = 0 according to existing agreements.

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3.3 Transport Properties 3.3.1 Dynamic Viscosity of Saturated Liquid The viscosity of the saturated liquid of Solkane®404A was measured within the temperature range of -50 to 60 °C. The following regression equation is valid for the liquid phase:

 η′  ln − 3  = L0 + L1t + L2t 2 + L3t 3  10 

(10)

with t in °C and η’ in 10-3 Pa s. The coefficients are:

L0 = L1 =

-1.73999 -0.013554

L2 = L3 =

[Pa s] [Pa s/K]

-4.7589e-6 -1.0953e-7

[Pa s/K2] [Pa s/K3]

Saturated liquid viscosity η’ in 10-3 Pa s 0,4

0,3

0,2

0,1

0 -50

-40

-30

-20

-10

0

10

20

30

40

50

60

Temperature t in °C Figure 1:

Dynamic viscosity of the saturated liquid

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3.3.2 Dynamic Viscosity of Saturated and Superheated Vapour The viscosity of the saturated and superheated vapour of Solkane®404A was measured in a temperature range of -50 to 50°C. The data can be represented by the following equations

η = η 0 + ∆η

(11)

with

(MT )2 1

η0 = 2.6696 × 10 × −2

σ Ωη T 2

*

,

T* =

kT

ε

and

Ω(T * ) = exp[0.45667 − 0.53955(ln (T * ) + 0.187265(ln T * ) 2 − 0.03629(ln T * ) 3 + 0.00241(ln T * ) 4 ] (12 a-c) ∆η = T

2.2 R

zc =

pcVc RTc

[ln(1.65 + ρ )] 0.8 R0

and

1.6

ρ R0 =

  1− 0.78 ⋅ρr 0  e  Tc  − 1( F ⋅ z c ⋅ ζ ) −1    

ρ − ρ0 and F = 1 for R404A as a light polar agent. (12 d-f) ρc

In equation (12) the constants are as follows . R the universal gas constant = 8314 ρc the critical density = 484.50 ρ0 the density at 1.013bar and temperature as defined by T Tc the critical temperature = 345.25

[J kmol-1 K-1] [kg/m3] [kg/m3] [K]

The constants of equation (11) where determined to be

ζ = σ = ε/k =

42429.18 [1/(Pa s)] 0.4968 [nm] 279.31 [K]

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Saturated vapor viscosity η'' in 10-6 Pa s 20

15

10

5

0 -50

-40

-30

-20

-10

0

10

20

30

40

50

60

Temperature t in °C Figure 2:

Dynamic viscosity of saturated vapour

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3.3.3 Thermal Conductivity of Saturated Liquid The thermal conductivity of saturated liquid can be expressed with the regression equation

λ ′ = M 0 + M 1t

(13)

where t is in °C and λ’ in 10-3W/(mK). The coefficients of the equation are:

M0 =

76.009

[10-3W/(mK)]

M1 = -0.4024 [10-3W/(mK2)]

Thermal conductivity of saturated liquid λ’ in 10-3 W/(mK) 100

80

60

40

20

0 -50

-40

-30

-20

-10

0

10

20

30

40

50

60

Temperature t in °C Figure 3:

Thermal conductivity of saturated liquid

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3.3.4 Thermal Conductivity of Saturated Vapour The thermal conductivity of saturated vapour can be expressed using the regression equation

λ ′′ = N 0 + N1t + N 2 t 2 + N 3t 3 + N 4 t 4

(14)

where t is in °C and λ’’ in 10-3 W/(m K). The coefficients of the equation are as follows:

N0 = N1 = N2 =

12.709 0.09932 6.2261e-4

[10-3W/(mK)] [10-3W/(mK2] [10-3W/(mK3)]

N3 = N4 =

[10-3W/(m K4)] [10-3W/(m K5)]

1.0683e-5 5.7339e-8

Thermal conductivity of saturated vapour λ’’ in 10-3 W/(mK) 30

20

10

0 -50

-40

-30

-20

-10

0

10

20

30

40

50

60

Temperature t in °C Figure 4:

Thermal conductivity of saturated vapour

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3.3.5 Surface Tension The surface tension of the liquid can be expressed using the regression equation

σ = O0 + O1t + O2 t 2 + O3t 3

(15)

where t is in °C and σ in 10-3N/m. The coefficients of the equation are:

[10-3N/m] [10-3N/(mK)]

O0 = 7.5370 O1 = -0.1290

O2 = O3 =

1.6168e-4 1.5624e-6

[10-3N/(mK2)] [10-3N/(mK3)]

Surface tension σ in 10-3 N/m 16

12

8

4

0 -50

-40

-30

-20

-10

0

10

20

30

40

50

60

Temperature t in °C Figure 5:

Surface tension

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3.3.6 Specific Heat Capacity of Saturated Liquid The specific heat capacity of saturated liquid can be expressed using the equation

c′p = P0 + P1 (1 − TR ) + P2 (1 − TR ) 19

where TR =

29

+ P3 (1 − TR )

39

+ P4 (1 − TR )

69

(16)

T , c ′p is in kJ/(kg K) and T is in K. The coefficients of the equation are as Tc

follows:

P0 = P1 = P2 =

272.7746241 [kJ/(kgK)] -1137.19404 [kJ/(kgK)] 1666.232657 [kJ/(kgK)]

P3 = P4 =

-872.727122 [kJ/(kgK)] 72.38836018 [kJ/(kgK)]

Specific heat capacity of saturated liquid cp’ in kJ/(kgK) 3

2

1

0 -50

-40

-30

-20

-10

0

10

20

30

40

50

60

Temperature t in °C Figure 6:

Specific heat capacity of saturated liquid

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4 Compatibility of Materials 4.1 Elastomeres The compatibility of the elastomeres that are normally used in refrigeration systems with Solkane®404A is generally good. Cold extraction tests that where carried out on CR (chlorbutadiene rubber or Neoprene®), NBR (acrylonitrilebutadienerubber) and HNBR (hydrated acrylnitrilbutadiene rubber) showed only slight swelling and yielded negligible amounts of extract. Fluorinated rubbers (FKM and FPM) are not recommended because of their considerable swelling and blistering when used with Solkane®404A or with other HFC refrigerants. Ethylenepropylenediene rubber is only to be recommended where the presence of mineral oil in the refrigeration cycle can be excluded. The effect of the lubricant that is used must not be ignored. Recommendations made by the lubricant and compressor manufacturers must be followed.

4.2 Thermoplastics Experience with CFC and HCFC has shown that only a limited number of plastics are resistant to fluorinated refrigerants. Polytetrafluoroethylene, polyacetale and polyamide might be taken into account for the use with Solkane®404A. It is again vital to take the effect of the lubricant into account.

4.3 Metals Solkane®404A is generally used in conjunction with lubricants (Ester oils, PAG-oils) in refrigeration technology. In combination both materials are compatible with the metals and alloys usually found in machines and apparatus. Only zinc, magnesium, lead and aluminium alloys with more than 2% magnesium by mass should be avoided. The water content of refrigeration oil depending on oil type should especially be taken into account. Values of not more than 50 ppm are to be aimed at.

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5 Refrigerant Oils Like all fluorinated hydrocarbons, Solkane®404A is immiscible with mineral oils. Ester oils (POE) are normally used as lubricants. The solubility of these oils in Solkane®404A is a function of temperature and composition. The following diagrams show the solubility properties of various lubricants with Solkane®404A. Highly viscous lubricants tend to give large miscibility gaps. The precise miscibility gaps of the individual oils can be obtained from the lubricant manufacturers.

Figure 7:

Miscibility behaviour of Solkane®404A and ester oil A

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Figure 8:

Miscibility behaviour of Solkane®404A and ester oil B

Figure 9:

Miscibility behaviour of Solkane®404A and ester oil C

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6 Flammability The explosion limits of R143a are 7.1 - 20.9 % by volume in air. R125 and R134a have no explosion limits. When blended 46/52/4 percent by weight the outcoming mixture has no explosion limits. According to UL 2182 Solkane®404A is non-flammable.

7 Toxicity The toxicity of R125 and R134a was extensively tested within the scope of the PAFT programme (Programme for Alternative Fluorocarbon Toxicity Testing). PAFT recommended an occupational exposure limit of 1000 ppm for both products. For R143a various manufacturers recommend a maximum exposure limit of 500 ppm related to an eight-hour working day. The toxicity of Solkane®404A can therefore be regarded as low and comparable to the toxicity of R502.

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8 Vapour Table, Wet Vapour Range Solkane®404A p´ p´´ v´ v´´ h´ h´´ r s´ s´´ ρ' ρ´´ 3 3 3 3 [°C] [bar] [bar] [dm /kg] [dm /kg] [kg/dm ] [kg/m ] [kJ/kg] [kJ/kg] [kJ/kg] [kJ/kg·K] [kJ/kg·K] t

-60 -59 -58 -57 -56 -55 -54 -53 -52 -51

0.508 0.537 0.567 0.598 0.631 0.665 0.700 0.737 0.775 0.815

0.484 0.512 0.541 0.571 0.603 0.636 0.670 0.706 0.743 0.782

0.742 0.743 0.745 0.747 0.748 0.750 0.751 0.753 0.755 0.757

364.71 346.19 328.78 312.43 297.05 282.57 268.94 256.09 243.99 232.57

1.348 1.345 1.342 1.340 1.337 1.334 1.331 1.328 1.325 1.322

2.74 2.89 3.04 3.20 3.37 3.54 3.72 3.90 4.10 4.30

123.10 124.29 125.48 126.68 127.88 129.08 130.28 131.48 132.69 133.90

330.92 331.54 332.15 332.76 333.37 333.98 334.59 335.20 335.81 336.41

207.83 207.25 206.66 206.08 205.49 204.90 204.31 203.71 203.11 202.51

0.6838 0.6894 0.6951 0.7007 0.7063 0.7119 0.7174 0.7230 0.7286 0.7341

1.6644 1.6626 1.6608 1.6590 1.6573 1.6557 1.6540 1.6525 1.6509 1.6494

-50 -49 -48 -47 -46 -45 -44 -43 -42 -41

0.857 0.900 0.945 0.992 1.041 1.091 1.143 1.198 1.254 1.312

0.823 0.865 0.909 0.955 1.002 1.051 1.102 1.155 1.211 1.268

0.758 0.760 0.762 0.764 0.765 0.767 0.769 0.771 0.773 0.774

221.79 211.61 201.99 192.89 184.29 176.15 168.44 161.14 154.22 147.66

1.319 1.316 1.313 1.310 1.307 1.304 1.301 1.297 1.294 1.291

4.51 4.73 4.95 5.18 5.43 5.68 5.94 6.21 6.48 6.77

135.11 136.33 137.55 138.77 139.99 141.22 142.45 143.69 144.92 146.16

337.02 337.62 338.23 338.83 339.43 340.03 340.63 341.23 341.83 342.43

201.91 201.30 200.68 200.06 199.44 198.81 198.18 197.55 196.91 196.26

0.7396 0.7451 0.7507 0.7561 0.7616 0.7671 0.7725 0.7780 0.7834 0.7888

1.6480 1.6465 1.6452 1.6438 1.6425 1.6412 1.6399 1.6387 1.6375 1.6364

-40 -39 -38 -37 -36 -35 -34 -33 -32 -31

1.373 1.435 1.500 1.567 1.636 1.708 1.782 1.858 1.937 2.019

1.327 1.388 1.451 1.517 1.585 1.656 1.728 1.803 1.881 1.961

0.776 0.778 0.780 0.782 0.784 0.786 0.788 0.790 0.792 0.794

141.43 135.52 129.90 124.57 119.50 114.68 110.09 105.73 101.57 97.61

1.288 1.285 1.282 1.279 1.276 1.272 1.269 1.266 1.263 1.260

7.07 7.38 7.70 8.03 8.37 8.72 9.08 9.46 9.85 10.24

147.41 148.66 149.91 151.16 152.42 153.69 154.95 156.22 157.50 158.77

343.02 343.62 344.21 344.80 345.39 345.98 346.56 347.15 347.73 348.31

195.61 194.96 194.30 193.64 192.97 192.29 191.61 190.93 190.24 189.54

0.7942 0.7996 0.8050 0.8103 0.8157 0.8210 0.8263 0.8316 0.8369 0.8422

1.6352 1.6341 1.6330 1.6320 1.6310 1.6300 1.6290 1.6280 1.6271 1.6262

-30 -29 -28 -27 -26 -25 -24 -23 -22 -21

2.103 2.190 2.280 2.372 2.468 2.566 2.667 2.771 2.879 2.989

2.044 2.130 2.218 2.309 2.403 2.500 2.599 2.702 2.808 2.917

0.796 0.798 0.800 0.802 0.804 0.807 0.809 0.811 0.813 0.815

93.83 90.23 86.80 83.53 80.40 77.41 74.56 71.83 69.22 66.73

1.256 1.253 1.250 1.247 1.243 1.240 1.237 1.233 1.230 1.226

10.66 11.08 11.52 11.97 12.44 12.92 13.41 13.92 14.45 14.99

160.06 161.34 162.63 163.92 165.22 166.51 167.82 169.12 170.43 171.74

348.89 349.47 350.05 350.62 351.20 351.77 352.33 352.90 353.47 354.03

188.84 188.13 187.42 186.70 185.98 185.25 184.52 183.78 183.03 182.28

0.8475 0.8527 0.8579 0.8632 0.8684 0.8736 0.8788 0.8839 0.8891 0.8942

1.6253 1.6244 1.6236 1.6228 1.6219 1.6212 1.6204 1.6196 1.6189 1.6182

SFD-AK T/09.04/02/E

21

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Wet Vapour Range Solkane®404A t

p´ p´´ v´ 3/kg] [bar] [bar] [dm [°C]

v´´ [dm3/kg]

h´ h´´ r s´ s´´ ρ' ρ´´ [kg/dm3] [kg/m3] [kJ/kg] [kJ/kg] [kJ/kg] [kJ/kg·K] [kJ/kg·K]

-20 -19 -18 -17 -16 -15 -14 -13 -12 -11

3.103 3.220 3.340 3.464 3.591 3.721 3.856 3.994 4.135 4.280

3.029 3.145 3.263 3.386 3.511 3.640 3.773 3.909 4.049 4.193

0.818 0.820 0.822 0.825 0.827 0.829 0.832 0.834 0.837 0.839

64.34 62.06 59.87 57.77 55.77 53.84 51.99 50.22 48.53 46.90

1.223 1.220 1.216 1.213 1.209 1.206 1.202 1.199 1.195 1.192

15.54 16.11 16.70 17.31 17.93 18.57 19.23 19.91 20.61 21.32

173.06 174.38 175.70 177.03 178.36 179.69 181.03 182.37 183.71 185.06

354.59 355.15 355.70 356.25 356.80 357.35 357.90 358.44 358.98 359.52

181.53 180.76 180.00 179.22 178.44 177.66 176.87 176.07 175.27 174.46

0.8994 0.9045 0.9096 0.9147 0.9198 0.9249 0.9299 0.9350 0.9401 0.9451

1.6175 1.6168 1.6162 1.6155 1.6149 1.6142 1.6136 1.6130 1.6125 1.6119

-10 -9 -8 -7 -6 -5 -4 -3 -2 -1

4.430 4.583 4.740 4.901 5.066 5.235 5.409 5.586 5.768 5.955

4.341 4.492 4.647 4.807 4.970 5.138 5.310 5.486 5.667 5.852

0.842 0.844 0.847 0.849 0.852 0.855 0.858 0.860 0.863 0.866

45.33 43.83 42.38 40.99 39.66 38.37 37.14 35.95 34.80 33.70

1.188 1.185 1.181 1.177 1.174 1.170 1.166 1.162 1.159 1.155

22.06 22.82 23.60 24.40 25.22 26.06 26.93 27.82 28.73 29.67

186.41 187.76 189.12 190.48 191.84 193.21 194.58 195.95 197.32 198.70

360.05 360.58 361.11 361.64 362.16 362.68 363.19 363.70 364.21 364.72

173.64 172.82 171.99 171.16 170.32 169.47 168.62 167.76 166.89 166.01

0.9501 0.9551 0.9602 0.9652 0.9702 0.9751 0.9801 0.9851 0.9901 0.9950

1.6113 1.6108 1.6102 1.6097 1.6092 1.6087 1.6082 1.6077 1.6072 1.6067

0 1 2 3 4 5 6 7 8 9

6.146 6.342 6.542 6.747 6.957 7.171 7.391 7.615 7.845 8.080

6.041 6.235 6.434 6.637 6.846 7.059 7.277 7.500 7.728 7.961

0.869 0.872 0.875 0.878 0.881 0.884 0.887 0.890 0.893 0.897

32.64 31.62 30.63 29.68 28.77 27.88 27.03 26.21 25.41 24.65

1.151 1.147 1.143 1.139 1.135 1.132 1.128 1.124 1.119 1.115

30.64 31.63 32.64 33.69 34.76 35.86 36.99 38.15 39.35 40.57

200.00 201.47 202.86 204.25 205.65 207.05 208.46 209.86 211.28 212.69

365.22 365.71 366.21 366.70 367.18 367.66 368.14 368.61 369.08 369.54

165.22 164.24 163.35 162.44 161.53 160.61 159.68 158.75 157.80 156.85

1.0000 1.0050 1.0099 1.0148 1.0198 1.0247 1.0297 1.0346 1.0395 1.0445

1.6062 1.6058 1.6053 1.6049 1.6044 1.6040 1.6035 1.6031 1.6027 1.6022

10 11 12 13 14 15 16 17 18 19

8.320 8.565 8.815 9.071 9.333 9.600 9.873 10.15 10.44 10.73

8.199 8.443 8.692 8.946 9.206 9.472 9.743 10.02 10.30 10.59

0.900 0.903 0.907 0.910 0.914 0.917 0.921 0.925 0.928 0.932

23.91 23.19 22.50 21.83 21.18 20.56 19.95 19.37 18.80 18.25

1.111 1.107 1.103 1.099 1.095 1.090 1.086 1.082 1.077 1.073

41.83 43.12 44.45 45.81 47.20 48.64 50.11 51.63 53.18 54.78

214.11 215.54 216.97 218.40 219.84 221.28 222.73 224.19 225.65 227.11

370.00 370.45 370.90 371.34 371.78 372.21 372.63 373.05 373.46 373.87

155.89 154.91 153.93 152.94 151.94 150.92 149.90 148.86 147.82 146.76

1.0494 1.0543 1.0593 1.0642 1.0692 1.0741 1.0790 1.0840 1.0889 1.0939

1.6018 1.6014 1.6009 1.6005 1.6000 1.5996 1.5992 1.5987 1.5983 1.5978

SFD-AK T/09.04/02/E

22

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Wet Vapour Range Solkane®404A T

p´ p´´ v´ 3/kg] [bar] [bar] [dm [°C]

v´´ [dm3/kg]

h´ h´´ r s´ s´´ ρ' ρ´´ [kg/dm3] [kg/m3] [kJ/kg] [kJ/kg] [kJ/kg] [kJ/kg·K] [kJ/kg·K]

20 21 22 23 24 25 26 27 28 29

11.02 11.32 11.63 11.95 12.27 12.60 12.93 13.27 13.62 13.97

10.89 11.19 11.50 11.81 12.13 12.45 12.79 13.13 13.47 13.83

0.936 0.940 0.944 0.948 0.953 0.957 0.961 0.966 0.970 0.975

17.72 17.21 16.71 16.23 15.76 15.30 14.86 14.43 14.02 13.62

1.068 1.064 1.059 1.054 1.050 1.045 1.040 1.035 1.030 1.025

56.43 58.11 59.85 61.63 63.46 65.35 67.28 69.28 71.33 73.44

228.59 230.06 231.55 233.04 234.54 236.05 237.56 239.08 240.62 242.16

374.27 374.66 375.05 375.42 375.79 376.15 376.51 376.85 377.19 377.51

145.68 144.60 143.50 142.38 141.25 140.11 138.95 137.77 136.57 135.36

1.0989 1.1038 1.1088 1.1138 1.1188 1.1238 1.1289 1.1339 1.1389 1.1440

1.5973 1.5969 1.5964 1.5959 1.5954 1.5949 1.5944 1.5939 1.5933 1.5928

30 31 32 33 34 35 36 37 38 39

14.33 14.70 15.07 15.46 15.84 16.24 16.64 17.06 17.47 17.90

14.19 14.55 14.93 15.31 15.69 16.09 16.49 16.90 17.32 17.75

0.980 0.985 0.990 0.995 1.000 1.006 1.011 1.017 1.023 1.029

13.23 12.85 12.48 12.12 11.77 11.43 11.10 10.78 10.47 10.17

1.020 1.015 1.010 1.005 1.000 0.994 0.989 0.983 0.978 0.972

75.61 77.84 80.14 82.52 84.96 87.48 90.08 92.75 95.52 98.37

243.70 245.26 246.83 248.41 250.00 251.60 253.22 254.85 256.48 258.14

377.83 378.14 378.43 378.72 378.99 379.25 379.50 379.74 379.96 380.17

134.13 132.87 131.60 130.31 128.99 127.65 126.29 124.90 123.48 122.03

1.1491 1.1542 1.1593 1.1644 1.1695 1.1747 1.1799 1.1851 1.1903 1.1955

1.5922 1.5916 1.5910 1.5904 1.5897 1.5890 1.5883 1.5876 1.5869 1.5861

40 41 42 43 44 45 46 47 48 49

18.34 18.78 19.23 19.69 20.15 20.63 21.11 21.60 22.11 22.62

18.18 18.62 19.07 19.53 20.00 20.47 20.96 21.45 21.95 22.46

1.035 1.042 1.048 1.055 1.062 1.069 1.077 1.085 1.093 1.101

9.87 9.58 9.30 9.03 8.76 8.50 8.24 8.00 7.75 7.52

0.966 0.960 0.954 0.948 0.942 0.935 0.929 0.922 0.915 0.908

101.32 104.37 107.52 110.78 114.16 117.66 121.29 125.06 128.97 133.04

259.81 261.49 263.18 264.90 266.63 268.37 270.14 271.92 273.73 275.55

380.37 380.54 380.71 380.85 380.98 381.08 381.17 381.23 381.27 381.29

120.56 119.06 117.52 115.95 114.35 112.71 111.03 109.31 107.55 105.74

1.2008 1.2061 1.2114 1.2167 1.2221 1.2275 1.2329 1.2384 1.2439 1.2494

1.5852 1.5844 1.5835 1.5826 1.5816 1.5806 1.5795 1.5784 1.5772 1.5759

50 51 52 53 54 55 56 57 58 59

23.13 23.66 24.20 24.75 25.30 25.87 26.45 27.03 27.63 28.24

22.98 23.51 24.04 24.59 25.15 25.72 26.30 26.88 27.48 28.09

1.110 1.119 1.129 1.139 1.149 1.160 1.172 1.184 1.197 1.211

7.28 7.06 6.84 6.62 6.40 6.19 5.99 5.79 5.59 5.39

0.901 0.894 0.886 0.878 0.870 0.862 0.853 0.845 0.835 0.826

137.27 141.69 146.29 151.11 156.15 161.44 166.99 172.85 179.03 185.58

277.39 279.26 281.15 283.06 285.00 286.96 288.95 290.97 293.01 295.08

381.28 381.24 381.17 381.07 380.93 380.76 380.54 380.27 379.95 379.58

103.89 101.98 100.02 98.01 95.93 93.79 91.59 89.31 86.94 84.50

1.2549 1.2605 1.2661 1.2718 1.2775 1.2832 1.2890 1.2948 1.3007 1.3066

1.5746 1.5732 1.5717 1.5702 1.5685 1.5668 1.5649 1.5629 1.5607 1.5584

SFD-AK T/09.04/02/E

23

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Wet Vapour Range Solkane®404A T

p´ p´´ v´ 3/kg] [bar] [bar] [dm [°C] 60 61 62 63 64 65 66 67 68

28.86 29.49 30.13 30.78 31.44 32.12 32.81 33.52 34.23

28.71 29.34 29.99 30.64 31.31 31.99 32.69 33.40 34.12

SFD-AK T/09.04/02/E

1.226 1.242 1.259 1.278 1.299 1.323 1.349 1.379 1.415

v´´ [dm3/kg]

5.19 5.00 4.81 4.62 4.42 4.23 4.03 3.83 3.62

h´ h´´ r s´ s´´ ρ' ρ´´ [kg/dm3] [kg/m3] [kJ/kg] [kJ/kg] [kJ/kg] [kJ/kg·K] [kJ/kg·K] 0.816 0.805 0.794 0.782 0.770 0.756 0.741 0.725 0.707

192.55 199.99 207.99 216.63 226.04 236.39 247.95 261.10 276.49

297.19 299.32 301.49 303.69 305.92 308.19 310.50 312.85 315.23

379.14 378.62 378.02 377.32 376.50 375.53 374.38 372.99 371.26

81.95 79.30 76.53 73.63 70.58 67.34 63.88 60.14 56.03

1.3125 1.3185 1.3246 1.3307 1.3368 1.3430 1.3492 1.3555 1.3619

1.5559 1.5532 1.5503 1.5471 1.5435 1.5395 1.5350 1.5298 1.5236

24

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

9 Vapour Table, Superheated Range Solkane®404A 0.82bar t °°C -50 -45 -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35

v

°°C -48 -45 -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35

°°C -46 -45 -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35

1.10bar s

kJ/kgK

221.79 227.54 233.25 238.90 244.52 250.10 255.64 261.16 266.64 272.11 277.55 282.97 288.37 293.76 299.13 304.49 309.84 315.17

1.6480 1.6648 1.6814 1.6978 1.7141 1.7301 1.7460 1.7618 1.7773 1.7928 1.8081 1.8233 1.8383 1.8533 1.8681 1.8828 1.8974 1.9119

v

337.02 340.82 344.65 348.52 352.43 356.37 360.35 364.37 368.44 372.54 376.68 380.86 385.09 389.36 393.66 398.01 402.41 406.84

-48.00°C h

s

dm3/kg kJ/kg

kJ/kgK

201.99 205.14 210.36 215.53 220.66 225.75 230.81 235.83 240.83 245.81 250.76 255.69 260.61 265.51 270.39 275.26 280.12 284.96

1.6452 1.6553 1.6720 1.6885 1.7048 1.7209 1.7369 1.7526 1.7683 1.7837 1.7991 1.8143 1.8294 1.8443 1.8592 1.8739 1.8886 1.9031

1.00 bar t

h

dm3/kg kJ/kg

0.91 bar t

-50.00°C

v

338.23 340.52 344.38 348.27 352.19 356.15 360.14 364.18 368.25 372.36 376.52 380.71 384.94 389.22 393.53 397.89 402.29 406.73

-46.00°C h

s

dm3/kg kJ/kg

kJ/kgK

184.29 185.26 190.05 194.79 199.48 204.14 208.76 213.36 217.92 222.46 226.98 231.48 235.96 240.43 244.88 249.31 253.73 258.15

1.6425 1.6459 1.6627 1.6793 1.6956 1.7118 1.7278 1.7437 1.7593 1.7749 1.7902 1.8055 1.8206 1.8356 1.8505 1.8652 1.8799 1.8944

339.43 340.20 344.08 347.99 351.93 355.90 359.92 363.96 368.05 372.17 376.34 380.54 384.78 389.06 393.39 397.75 402.15 406.60

SFD-AK T/09.04/02/E

t °°C -44 -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40

v

°°C -42 -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40

°°C -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45

1.45bar s

kJ/kgK

168.44 171.97 176.32 180.64 184.91 189.15 193.36 197.54 201.70 205.83 209.94 214.04 218.12 222.18 226.23 230.26 234.29 238.31

1.6399 1.6535 1.6701 1.6866 1.7028 1.7189 1.7348 1.7505 1.7661 1.7815 1.7968 1.8120 1.8270 1.8419 1.8567 1.8714 1.8859 1.9004

v

340.63 343.76 347.69 351.65 355.64 359.67 363.73 367.83 371.97 376.14 380.35 384.61 388.90 393.23 397.60 402.01 406.47 410.96

-42.00°C h

s

dm3/kg kJ/kg

kJ/kgK

154.22 155.84 159.86 163.83 167.77 171.67 175.53 179.37 183.18 186.97 190.74 194.49 198.23 201.94 205.65 209.34 213.02 216.69

1.6375 1.6443 1.6611 1.6776 1.6940 1.7101 1.7261 1.7419 1.7575 1.7730 1.7883 1.8035 1.8185 1.8335 1.8483 1.8630 1.8776 1.8920

1.33 bar t

h

dm3/kg kJ/kg

1.21 bar t

-44.00°C

v

341.83 343.41 347.36 351.34 355.35 359.40 363.48 367.59 371.74 375.93 380.16 384.42 388.72 393.06 397.44 401.86 406.32 410.82

-40.00°C h

s

dm3/kg kJ/kg

kJ/kgK

141.43 145.15 148.82 152.45 156.04 159.60 163.13 166.64 170.12 173.59 177.03 180.46 183.87 187.26 190.65 194.02 197.39 200.74

1.6352 1.6521 1.6688 1.6852 1.7014 1.7174 1.7333 1.7490 1.7645 1.7799 1.7951 1.8102 1.8252 1.8400 1.8547 1.8693 1.8839 1.8983

343.02 347.00 351.01 355.05 359.11 363.21 367.34 371.50 375.70 379.94 384.22 388.53 392.88 397.27 401.70 406.16 410.67 415.21

t °°C -38 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45

v

°°C -36 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45

°°C -34 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50

1.88bar s

kJ/kgK

129.90 131.97 135.37 138.73 142.05 145.34 148.60 151.83 155.04 158.23 161.39 164.55 167.68 170.81 173.91 177.01 180.10 183.18

1.6330 1.6432 1.6600 1.6765 1.6928 1.7089 1.7248 1.7406 1.7561 1.7716 1.7868 1.8020 1.8170 1.8319 1.8466 1.8613 1.8758 1.8902

v

344.21 346.62 350.65 354.71 358.80 362.91 367.06 371.24 375.46 379.71 384.00 388.32 392.68 397.08 401.52 405.99 410.51 415.06

-36.00°C h

s

dm3/kg kJ/kg

kJ/kgK

119.50 120.14 123.30 126.41 129.49 132.54 135.55 138.54 141.50 144.45 147.37 150.27 153.16 156.04 158.90 161.76 164.60 167.43

1.6310 1.6344 1.6512 1.6679 1.6843 1.7005 1.7165 1.7323 1.7479 1.7634 1.7787 1.7939 1.8089 1.8238 1.8386 1.8533 1.8679 1.8823

1.73 bar t

h

dm3/kg kJ/kg

1.59 bar t

-38.00°C

v

345.39 346.20 350.26 354.35 358.46 362.60 366.76 370.96 375.20 379.46 383.76 388.10 392.47 396.88 401.33 405.81 410.33 414.89

-34.00°C h

s

dm3/kg kJ/kg

kJ/kgK

110.09 112.44 115.34 118.20 121.03 123.83 126.59 129.34 132.06 134.76 137.45 140.12 142.77 145.41 148.04 150.66 153.27 155.87

1.6290 1.6426 1.6593 1.6758 1.6921 1.7082 1.7241 1.7398 1.7553 1.7707 1.7859 1.8010 1.8159 1.8308 1.8455 1.8600 1.8745 1.8889

346.56 349.84 353.96 358.09 362.25 366.44 370.66 374.91 379.19 383.51 387.86 392.24 396.66 401.12 405.62 410.15 414.72 419.32

t °°C -32 -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50

v

°°C -30 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55

°°C -28 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55

s kJ/kgK

101.57 102.66 105.37 108.04 110.66 113.26 115.83 118.38 120.90 123.41 125.89 128.36 130.82 133.26 135.69 138.11 140.52 142.92

1.6271 1.6339 1.6508 1.6674 1.6838 1.7000 1.7159 1.7317 1.7473 1.7627 1.7780 1.7931 1.8081 1.8230 1.8377 1.8523 1.8668 1.8812

v

347.73 349.39 353.53 357.70 361.88 366.10 370.34 374.61 378.91 383.24 387.60 392.00 396.43 400.90 405.41 409.95 414.53 419.14

-30.00°C h

s

dm3/kg kJ/kg

kJ/kgK

93.83 96.37 98.86 101.31 103.73 106.13 108.49 110.84 113.16 115.47 117.76 120.04 122.30 124.55 126.79 129.02 131.24 133.45

1.6253 1.6423 1.6590 1.6755 1.6918 1.7078 1.7237 1.7394 1.7549 1.7702 1.7854 1.8004 1.8153 1.8301 1.8447 1.8593 1.8737 1.8880

2.22 bar t

h

dm3/kg kJ/kg

2.04 bar t

-32.00°C

v

348.89 353.07 357.27 361.49 365.72 369.99 374.28 378.60 382.94 387.32 391.74 396.18 400.66 405.18 409.73 414.32 418.95 423.61

-28.00°C h

s

dm3/kg kJ/kg

kJ/kgK

86.80 88.22 90.56 92.85 95.11 97.35 99.56 101.74 103.91 106.05 108.18 110.29 112.39 114.48 116.56 118.63 120.69 122.74

1.6236 1.6338 1.6507 1.6673 1.6837 1.6998 1.7158 1.7315 1.7471 1.7625 1.7777 1.7928 1.8078 1.8226 1.8373 1.8518 1.8663 1.8806

350.05 352.58 356.81 361.06 365.32 369.61 373.92 378.26 382.63 387.03 391.46 395.92 400.41 404.94 409.50 414.10 418.74 423.41

25

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Superheated Range Solkane®404A 2.40 bar t °°C -26 -25 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55

v

-26.00°C h

s

dm3/kg kJ/kg

kJ/kgK

80.40 80.84 83.03 85.19 87.31 89.40 91.46 93.50 95.52 97.52 99.50 101.47 103.43 105.37 107.30 109.22 111.13 113.03

1.6219 1.6254 1.6424 1.6592 1.6756 1.6919 1.7079 1.7237 1.7394 1.7548 1.7701 1.7853 1.8003 1.8151 1.8299 1.8445 1.8589 1.8733

351.20 352.05 356.32 360.60 364.89 369.21 373.54 377.91 382.29 386.71 391.16 395.63 400.14 404.68 409.26 413.87 418.51 423.19

2.60 bar - 24.00°C t °°C -24 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60

v

h

s

dm3/kg kJ/kg

kJ/kgK

74.56 76.21 78.23 80.22 82.18 84.12 86.03 87.91 89.78 91.63 93.47 95.29 97.10 98.90 100.68 102.46 104.23 105.99

1.6204 1.6341 1.6510 1.6676 1.6840 1.7001 1.7160 1.7317 1.7473 1.7626 1.7778 1.7929 1.8078 1.8225 1.8372 1.8517 1.8661 1.8804

352.33 355.78 360.10 364.43 368.77 373.14 377.52 381.93 386.37 390.83 395.33 399.85 404.41 409.00 413.62 418.27 422.97 427.69

2.81 bar - 22.00°C t °°C -22 -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60

v

h

t °°C -20 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65

v

-20.00°C h

s

dm3/kg kJ/kg

kJ/kgK

64.34 66.15 67.92 69.66 71.37 73.05 74.71 76.35 77.98 79.58 81.17 82.75 84.32 85.88 87.42 88.96 90.49 92.02

1.6175 1.6347 1.6516 1.6682 1.6846 1.7007 1.7166 1.7323 1.7478 1.7631 1.7783 1.7933 1.8082 1.8229 1.8375 1.8520 1.8663 1.8806

354.59 358.99 363.40 367.81 372.23 376.68 381.14 385.62 390.12 394.65 399.21 403.80 408.42 413.07 417.75 422.46 427.21 431.99

3.26 bar - 18.00°C t °°C -18 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65

v

h

s

dm3/kg kJ/kg

kJ/kgK

59.87 60.89 62.57 64.21 65.83 67.41 68.98 70.52 72.04 73.55 75.04 76.52 77.99 79.45 80.90 82.33 83.76 85.19

1.6162 1.6266 1.6436 1.6604 1.6769 1.6931 1.7091 1.7249 1.7405 1.7559 1.7711 1.7862 1.8011 1.8158 1.8305 1.8450 1.8594 1.8737

355.70 358.37 362.82 367.27 371.73 376.21 380.69 385.20 389.73 394.28 398.86 403.47 408.10 412.77 417.46 422.19 426.95 431.74

3.51 bar - 16.00°C s

dm3/kg kJ/kg

kJ/kgK

69.22 70.00 71.91 73.78 75.63 77.44 79.23 81.00 82.75 84.48 86.20 87.90 89.59 91.26 92.93 94.59 96.24 97.88

1.6189 1.6258 1.6429 1.6596 1.6761 1.6923 1.7083 1.7241 1.7397 1.7552 1.7704 1.7855 1.8005 1.8153 1.8300 1.8446 1.8590 1.8733

353.47 355.21 359.57 363.93 368.31 372.70 377.11 381.55 386.01 390.49 395.00 399.54 404.11 408.72 413.35 418.02 422.72 427.46

3.03 bar

SFD-AK T/09.04/02/E

t °°C -16 -15 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65

v

h

t °°C -14 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70

v

-14.00°C h

s

dm3/kg kJ/kg

kJ/kgK

51.99 53.21 54.69 56.13 57.55 58.95 60.32 61.67 63.01 64.33 65.64 66.93 68.22 69.49 70.75 72.01 73.26 74.50

1.6136 1.6276 1.6447 1.6614 1.6779 1.6942 1.7101 1.7259 1.7415 1.7568 1.7720 1.7871 1.8020 1.8167 1.8313 1.8458 1.8601 1.8744

357.90 361.54 366.08 370.62 375.16 379.72 384.28 388.87 393.47 398.09 402.73 407.41 412.10 416.83 421.58 426.37 431.19 436.03

4.05 bar - 12.00°C t °°C -12 -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70

v

h

s

dm3/kg kJ/kg

kJ/kgK

48.53 49.10 50.51 51.89 53.24 54.56 55.86 57.14 58.40 59.65 60.88 62.10 63.31 64.50 65.69 66.87 68.04 69.21

1.6125 1.6195 1.6368 1.6537 1.6704 1.6867 1.7028 1.7187 1.7343 1.7498 1.7651 1.7802 1.7951 1.8099 1.8246 1.8391 1.8535 1.8677

358.98 360.82 365.42 370.00 374.59 379.18 383.78 388.39 393.02 397.66 402.33 407.02 411.74 416.48 421.25 426.05 430.88 435.74

4.34 bar - 10.00°C s

dm3/kg kJ/kg

kJ/kgK

55.77 56.09 57.68 59.24 60.76 62.26 63.74 65.19 66.63 68.05 69.45 70.84 72.21 73.58 74.94 76.28 77.62 78.95

1.6149 1.6184 1.6356 1.6525 1.6692 1.6855 1.7016 1.7175 1.7332 1.7486 1.7639 1.7791 1.7940 1.8089 1.8236 1.8381 1.8526 1.8669

356.80 357.70 362.20 366.70 371.20 375.70 380.22 384.76 389.31 393.89 398.49 403.11 407.76 412.45 417.16 421.90 426.67 431.47

3.77 bar

t °°C -10 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75

v

h

t °°C -8 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75

v

-8.00°C h

s

dm3/kg kJ/kg

kJ/kgK

42.38 43.15 44.41 45.64 46.83 48.01 49.16 50.29 51.40 52.51 53.59 54.67 55.73 56.79 57.83 58.87 59.90 60.93

1.6102 1.6208 1.6382 1.6552 1.6718 1.6882 1.7043 1.7201 1.7358 1.7512 1.7665 1.7815 1.7965 1.8112 1.8258 1.8403 1.8547 1.8689

361.11 363.94 368.63 373.31 377.99 382.66 387.34 392.03 396.73 401.45 406.19 410.94 415.73 420.53 425.36 430.22 435.11 440.03

4.97 bar -6.00°C t °°C -6 -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75

v

h

s

dm3/kg kJ/kg

KJ/kgK

39.66 39.90 41.11 42.28 43.43 44.54 45.64 46.72 47.78 48.82 49.85 50.87 51.87 52.87 53.86 54.84 55.81 56.77

1.6092 1.6128 1.6303 1.6475 1.6643 1.6808 1.6971 1.7131 1.7288 1.7443 1.7597 1.7748 1.7898 1.8046 1.8193 1.8338 1.8482 1.8625

362.16 363.11 367.87 372.60 377.33 382.04 386.76 391.48 396.22 400.96 405.73 410.51 415.31 420.14 424.99 429.87 434.77 439.70

5.31 bar - 4.00°C s

dm3/kg kJ/kg

kJ/kgK

45.33 46.68 47.99 49.28 50.53 51.77 52.98 54.17 55.35 56.51 57.66 58.80 59.93 61.05 62.16 63.26 64.36 65.44

1.6113 1.6288 1.6460 1.6628 1.6793 1.6955 1.7115 1.7272 1.7428 1.7581 1.7733 1.7883 1.8032 1.8179 1.8324 1.8469 1.8612 1.8754

360.05 364.70 369.34 373.97 378.60 383.24 387.88 392.54 397.21 401.90 406.62 411.35 416.12 420.90 425.72 430.56 435.44 440.34

4.65 bar

t °°C -4 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80

v

h

s

dm3/kg kJ/kg

kJ/kgK

37.14 38.06 39.19 40.29 41.35 42.40 43.43 44.43 45.42 46.40 47.37 48.32 49.26 50.20 51.12 52.04 52.95 53.86

1.6082 1.6224 1.6398 1.6568 1.6735 1.6899 1.7060 1.7218 1.7375 1.7529 1.7681 1.7832 1.7981 1.8128 1.8274 1.8418 1.8561 1.8703

363.19 367.05 371.85 376.62 381.39 386.15 390.91 395.67 400.45 405.24 410.05 414.87 419.72 424.59 429.49 434.41 439.35 444.33

26

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Superheated Range Solkane®404A 5.67 bar t °°C -2 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80

v

°°C 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85

°°C 2 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85

s kJ/kgK

34.80 35.25 36.33 37.39 38.41 39.41 40.39 41.35 42.29 43.22 44.14 45.04 45.94 46.82 47.70 48.57 49.43 50.29

1.6072 1.6144 1.6320 1.6493 1.6661 1.6827 1.6989 1.7149 1.7306 1.7461 1.7614 1.7766 1.7915 1.8063 1.8210 1.8355 1.8498 1.8640

v

364.21 366.17 371.03 375.87 380.68 385.49 390.29 395.09 399.90 404.72 409.56 414.41 419.28 424.17 429.08 434.02 438.99 443.98

0.00°C h

kJ/kgK

32.64 33.69 34.70 35.69 36.65 37.58 38.50 39.40 40.29 41.16 42.02 42.87 43.71 44.54 45.36 46.18 46.99 47.79

1.6062 1.6242 1.6416 1.6587 1.6754 1.6918 1.7079 1.7238 1.7394 1.7548 1.7700 1.7850 1.7999 1.8146 1.8291 1.8436 1.8578 1.8720

v

365.22 370.16 375.06 379.93 384.79 389.63 394.48 399.32 404.18 409.04 413.92 418.81 423.72 428.66 433.62 438.60 443.60 448.64

2.00°C h

t °°C 4 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85

v

t °°C 6 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90

kJ/kgK

30.63 31.24 32.22 33.17 34.09 34.99 35.87 36.73 37.57 38.41 39.23 40.03 40.83 41.62 42.40 43.18 43.94 44.71

1.6053 1.6162 1.6339 1.6512 1.6681 1.6847 1.7009 1.7169 1.7326 1.7481 1.7634 1.7786 1.7935 1.8083 1.8229 1.8373 1.8517 1.8659

SFD-AK T/09.04/02/E

t °°C 8 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90

4.0°C h

8.20 bar s

dm3/kg kJ/kg

kJ/kgK

28.77 28.96 29.91 30.83 31.72 32.59 33.43 34.25 35.06 35.86 36.64 37.41 38.17 38.92 39.66 40.40 41.13 41.85

1.6044 1.6081 1.6261 1.6436 1.6607 1.6775 1.6939 1.7100 1.7259 1.7415 1.7569 1.7721 1.7871 1.8019 1.8166 1.8311 1.8455 1.8598

v

367.18 368.20 373.26 378.26 383.24 388.19 393.12 398.05 402.98 407.91 412.84 417.79 422.75 427.73 432.73 437.75 442.79 447.86

6.00°C h

kJ/kgK

27.03 27.77 28.66 29.52 30.35 31.17 31.96 32.73 33.49 34.24 34.98 35.70 36.42 37.12 37.82 38.52 39.20 39.88

1.6035 1.6182 1.6360 1.6533 1.6703 1.6868 1.7031 1.7191 1.7349 1.7504 1.7656 1.7807 1.7956 1.8104 1.8250 1.8394 1.8537 1.8679

v

368.14 372.25 377.34 382.38 387.39 392.38 397.35 402.32 407.29 412.26 417.24 422.23 427.23 432.25 437.29 442.36 447.44 452.55

8.00°C h

°°C 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

v

t °°C 12 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

kJ/kgK

25.41 25.77 26.64 27.47 28.28 29.06 29.83 30.57 31.30 32.02 32.72 33.41 34.10 34.77 35.44 36.10 36.75 37.40

1.6027 1.6101 1.6282 1.6458 1.6630 1.6797 1.6962 1.7123 1.7282 1.7438 1.7592 1.7744 1.7894 1.8042 1.8188 1.8333 1.8477 1.8619

t °°C 14 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

10.0°C

t

dm3/kg kJ/kg

kJ/kgK

23.91 24.76 25.57 26.35 27.11 27.84 28.56 29.26 29.95 30.62 31.29 31.94 32.59 33.22 33.85 34.47 35.09 35.70

1.6018 1.6203 1.6382 1.6556 1.6726 1.6892 1.7055 1.7215 1.7372 1.7527 1.7680 1.7831 1.7980 1.8127 1.8273 1.8417 1.8559 1.8701

°°C 16 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

v

h

9.74 bar s

370.00 375.28 380.48 385.63 390.74 395.82 400.88 405.93 410.98 416.03 421.08 426.14 431.22 436.30 441.41 446.53 451.68 456.84

12.00°C

t

dm3/kg kJ/kg

kJ/kgK

22.50 22.99 23.79 24.55 25.29 26.00 26.69 27.37 28.03 28.67 29.31 29.94 30.55 31.16 31.76 32.36 32.95 33.53

1.6009 1.6122 1.6304 1.6481 1.6653 1.6821 1.6986 1.7148 1.7307 1.7463 1.7617 1.7768 1.7918 1.8066 1.8212 1.8357 1.8500 1.8642

°°C 18 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

v

h 370.90 374.12 379.42 384.65 389.83 394.98 400.09 405.19 410.28 415.37 420.46 425.55 430.65 435.77 440.90 446.04 451.21 456.39

14.00°C h

16.00°C h

s

dm3/kg kJ/kg

kJ/kgK

19.95 20.57 21.30 22.00 22.67 23.32 23.95 24.57 25.17 25.76 26.33 26.90 27.46 28.01 28.55 29.09 29.62 30.15

1.5992 1.6143 1.6327 1.6505 1.6678 1.6847 1.7012 1.7174 1.7333 1.7489 1.7643 1.7794 1.7944 1.8092 1.8238 1.8382 1.8525 1.8667

372.63 377.05 382.48 387.83 393.12 398.36 403.57 408.76 413.94 419.10 424.27 429.43 434.61 439.79 444.98 450.19 455.42 460.67

v

t

dm3/kg kJ/kg

kJ/kgK

21.18 21.35 22.13 22.87 23.59 24.28 24.95 25.60 26.24 26.86 27.47 28.07 28.66 29.25 29.82 30.39 30.95 31.51

1.6000 1.6039 1.6225 1.6405 1.6580 1.6750 1.6917 1.7080 1.7240 1.7398 1.7553 1.7706 1.7856 1.8005 1.8152 1.8297 1.8441 1.8584

°°C 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105

h

s

dm3/kg kJ/kg

kJ/kgK

18.80 19.10 19.82 20.51 21.17 21.80 22.41 23.01 23.59 24.16 24.71 25.26 25.79 26.32 26.84 27.36 27.87 28.37

1.5983 1.6060 1.6248 1.6429 1.6605 1.6776 1.6943 1.7107 1.7267 1.7425 1.7580 1.7732 1.7883 1.8032 1.8178 1.8324 1.8467 1.8609

10.89 bar s

371.78 372.87 378.28 383.61 388.87 394.08 399.26 404.41 409.55 414.67 419.80 424.93 430.06 435.20 440.36 445.53 450.71 455.92

v

10.30 bar 18.00°C s

9.21 bar s

dm3/kg kJ/kg 369.08 371.17 376.35 381.46 386.54 391.58 396.61 401.62 406.63 411.64 416.65 421.67 426.70 431.75 436.81 441.89 447.00 452.12

t

8.69 bar s

dm3/kg kJ/kg

7.73 bar s

dm3/kg kJ/kg 366.21 369.22 374.19 379.13 384.04 388.93 393.82 398.71 403.59 408.49 413.40 418.32 423.25 428.21 433.19 438.19 443.21 448.26

6.85 bar

7.28 bar s

dm3/kg kJ/kg

6.43 bar t

h

dm3/kg kJ/kg

6.04 bar t

-2.00°C

v

373.46 375.72 381.27 386.72 392.09 397.41 402.69 407.93 413.15 418.37 423.57 428.77 433.98 439.19 444.41 449.65 454.90 460.16

20.00°C h

s

dm3/kg kJ/kg

kJ/kgK

17.72 18.44 19.11 19.76 20.37 20.97 21.55 22.11 22.66 23.20 23.72 24.24 24.75 25.25 25.74 26.23 26.71 27.19

1.5973 1.6166 1.6351 1.6530 1.6704 1.6873 1.7039 1.7201 1.7360 1.7516 1.7670 1.7822 1.7971 1.8119 1.8265 1.8409 1.8552 1.8693

374.27 379.96 385.53 391.00 396.40 401.74 407.05 412.33 417.58 422.83 428.07 433.31 438.56 443.81 449.07 454.35 459.63 464.94

27

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Superheated Range Solkane®404A 11.5 bar 22.00°C t °°C 22 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105

v

h

13.47 bar 28.00°C s

t

dm3/kg kJ/kg

kJ/kgK

16.71 17.13 17.80 18.43 19.04 19.62 20.18 20.73 21.26 21.78 22.29 22.79 23.27 23.76 24.23 24.70 25.16 25.62

1.5964 1.6082 1.6271 1.6454 1.6631 1.6803 1.6970 1.7134 1.7295 1.7453 1.7608 1.7760 1.7911 1.8059 1.8206 1.8351 1.8494 1.8636

°°C 28 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110

375.05 378.54 384.24 389.82 395.31 400.73 406.11 411.45 416.76 422.05 427.34 432.61 437.89 443.18 448.47 453.77 459.08 464.41

12.13 bar 24.00°C

v

h

15.69 bar 34.00°C

s

t

dm3/kg kJ/kg

kJ/kgK

14.02 14.28 14.91 15.49 16.04 16.57 17.08 17.57 18.04 18.51 18.96 19.40 19.83 20.26 20.67 21.08 21.49 21.89

1.5933 1.6015 1.6212 1.6401 1.6582 1.6758 1.6929 1.7095 1.7258 1.7418 1.7574 1.7728 1.7880 1.8029 1.8177 1.8322 1.8466 1.8608

°°C 34 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115

377.19 379.66 385.69 391.54 397.27 402.90 408.46 413.97 419.43 424.86 430.28 435.68 441.07 446.46 451.85 457.24 462.65 468.07

v

h

18.18 bar 40.00°C

s

t

dm3/kg kJ/kg

kJ/kgK

11.77 11.90 12.49 13.04 13.55 14.04 14.50 14.94 15.37 15.79 16.19 16.59 16.97 17.35 17.72 18.09 18.45 18.80

1.5897 1.5940 1.6148 1.6344 1.6531 1.6712 1.6886 1.7056 1.7221 1.7383 1.7541 1.7697 1.7850 1.8000 1.8148 1.8295 1.8439 1.8582

°°C 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125

378.99 380.32 386.77 392.96 398.97 404.84 410.61 416.30 421.93 427.52 433.08 438.61 444.12 449.62 455.12 460.62 466.12 471.63

v

h

s

dm3/kg kJ/kg

kJ/kgK

9.87 10.45 10.98 11.46 11.91 12.34 12.75 13.14 13.52 13.89 14.24 14.59 14.93 15.26 15.58 15.90 16.22 16.53

1.5852 1.6075 1.6281 1.6476 1.6662 1.6842 1.7015 1.7183 1.7348 1.7508 1.7665 1.7820 1.7972 1.8121 1.8268 1.8414 1.8557 1.8699

380.37 387.38 394.00 400.35 406.51 412.52 418.43 424.25 430.01 435.72 441.39 447.03 452.66 458.27 463.88 469.48 475.09 480.70

14.19 bar 30.00°C

16.49 bar 36.00°C

t

v

h

s

t

v

h

s

t

v

h

s

t

v

h

s

°C 24 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105

dm3/kg 15.76 15.90 16.56 17.19 17.78 18.35 18.90 19.44 19.95 20.45 20.94 21.43 21.90 22.36 22.82 23.27 23.71 24.15

kJ/kg 375.79 376.99 382.84 388.55 394.14 399.66 405.11 410.51 415.88 421.23 426.56 431.88 437.19 442.51 447.83 453.16 458.50 463.85

kJ/kgK 1.5954 1.5994 1.6189 1.6376 1.6556 1.6731 1.6901 1.7067 1.7229 1.7388 1.7545 1.7699 1.7850 1.8000 1.8147 1.8293 1.8437 1.8580

°C 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115

dm3/kg 13.23 13.85 14.44 14.99 15.51 16.01 16.48 16.95 17.40 17.84 18.26 18.68 19.09 19.50 19.89 20.28 20.67 21.05

kJ/kg 377.83 384.07 390.08 395.94 401.68 407.33 412.92 418.45 423.94 429.41 434.86 440.29 445.72 451.14 456.57 462.00 467.45 472.90

kJ/kgK 1.5922 1.6126 1.6320 1.6505 1.6684 1.6858 1.7027 1.7192 1.7353 1.7511 1.7666 1.7819 1.7970 1.8118 1.8265 1.8409 1.8552 1.8694

°C 36 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120

dm3/kg 11.10 11.58 12.14 12.65 13.13 13.59 14.03 14.45 14.86 15.25 15.63 16.01 16.37 16.73 17.09 17.43 17.78 18.11

kJ/kg 379.50 384.86 391.27 397.45 403.46 409.34 415.12 420.84 426.49 432.11 437.69 443.26 448.80 454.34 459.87 465.41 470.94 476.49

kJ/kgK 1.5883 1.6056 1.6259 1.6451 1.6636 1.6814 1.6986 1.7154 1.7317 1.7478 1.7635 1.7789 1.7941 1.8090 1.8237 1.8383 1.8526 1.8668

°C 42 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125

dm3/kg 9.30 9.66 10.20 10.69 11.14 11.56 11.97 12.35 12.73 13.08 13.43 13.77 14.10 14.42 14.74 15.05 15.35 15.65

kJ/kg 380.71 385.10 392.03 398.60 404.93 411.08 417.10 423.02 428.86 434.64 440.38 446.08 451.75 457.41 463.06 468.70 474.33 479.97

kJ/kgK 1.5835 1.5974 1.6190 1.6392 1.6583 1.6766 1.6943 1.7114 1.7281 1.7443 1.7602 1.7758 1.7912 1.8062 1.8210 1.8357 1.8501 1.8644

12.79 bar 26.00°C

14.93 bar 32.00°C

17.32 bar 38.00°C

19.07 bar 42.00°C

20.00 bar 44.00°C

t

v

h

s

t

v

h

s

t

v

h

s

t

v

h

s

°C 26 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110

dm3/kg 14.86 15.39 16.02 16.60 17.16 17.70 18.22 18.72 19.21 19.69 20.15 20.61 21.06 21.50 21.93 22.36 22.78 23.19

kJ/kg 376.51 381.32 387.18 392.89 398.51 404.04 409.52 414.95 420.36 425.73 431.10 436.45 441.81 447.16 452.52 457.89 463.26 468.66

kJ/kgK 1.5944 1.6104 1.6295 1.6479 1.6657 1.6830 1.6998 1.7163 1.7323 1.7481 1.7637 1.7789 1.7940 1.8088 1.8235 1.8380 1.8523 1.8664

°C 32 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115

dm3/kg 12.48 12.85 13.44 13.99 14.50 14.99 15.46 15.92 16.36 16.78 17.20 17.60 18.00 18.39 18.77 19.15 19.52 19.89

kJ/kg 378.43 382.29 388.50 394.51 400.38 406.13 411.80 417.41 422.97 428.49 433.99 439.47 444.94 450.40 455.86 461.33 466.80 472.28

kJ/kgK 1.5910 1.6036 1.6236 1.6426 1.6609 1.6786 1.6957 1.7124 1.7288 1.7447 1.7604 1.7758 1.7910 1.8059 1.8207 1.8352 1.8496 1.8638

°C 38 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120

dm3/kg 10.47 10.71 11.28 11.79 12.28 12.73 13.16 13.58 13.97 14.36 14.73 15.10 15.45 15.80 16.15 16.48 16.81 17.14

kJ/kg 379.96 382.75 389.42 395.80 401.96 407.97 413.87 419.67 425.40 431.09 436.73 442.35 447.94 453.52 459.09 464.66 470.23 475.80

kJ/kgK 1.5869 1.5958 1.6169 1.6368 1.6557 1.6739 1.6915 1.7085 1.7251 1.7413 1.7572 1.7728 1.7881 1.8031 1.8179 1.8326 1.8470 1.8613

°C 44 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125

dm3/kg 8.76 8.88 9.44 9.94 10.40 10.83 11.23 11.61 11.97 12.33 12.67 13.00 13.32 13.63 13.94 14.24 14.54 14.83

kJ/kg 380.98 382.52 389.84 396.68 403.22 409.53 415.68 421.71 427.64 433.50 439.31 445.07 450.80 456.51 462.19 467.87 473.55 479.22

kJ/kgK 1.5816 1.5864 1.6093 1.6303 1.6501 1.6689 1.6869 1.7044 1.7213 1.7378 1.7539 1.7696 1.7851 1.8003 1.8152 1.8299 1.8445 1.8588

SFD-AK T/09.04/02/E

28

Solkane®404A Thermodynamics

SOLVAY FLUOR

Release 1.03

Vapour Table, Superheated Range Solkane®404A 20.96 bar 46.00°C t °°C 46 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130

v

h

t

dm3/kg kJ/kg

kJ/kgK

8.24 8.71 9.23 9.69 10.12 10.52 10.90 11.26 11.61 11.94 12.27 12.58 12.89 13.19 13.48 13.77 14.05 14.33

1.5795 1.5988 1.6209 1.6414 1.6608 1.6793 1.6971 1.7143 1.7311 1.7474 1.7633 1.7789 1.7942 1.8093 1.8242 1.8388 1.8532 1.8674

°°C 52 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

381.17 387.38 394.57 401.36 407.86 414.16 420.31 426.35 432.30 438.18 444.01 449.79 455.55 461.29 467.01 472.72 478.43 484.14

21.95 bar 48.00°C t °°C 48 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130

v

h

t

dm3/kg kJ/kg

kJ/kgK

7.75 8.00 8.54 9.02 9.45 9.85 10.23 10.59 10.93 11.26 11.57 11.88 12.18 12.47 12.76 13.04 13.31 13.58

1.5772 1.5874 1.6109 1.6324 1.6524 1.6714 1.6896 1.7072 1.7242 1.7407 1.7569 1.7727 1.7881 1.8033 1.8183 1.8330 1.8476 1.8619

°°C 54 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

381.27 384.57 392.22 399.32 406.05 412.52 418.82 424.97 431.02 436.98 442.88 448.74 454.55 460.34 466.11 471.86 477.61 483.35

°°C 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

v

h

dm3/kg kJ/kg 7.28 381.28 7.87 389.57 8.36 397.06 8.81 404.07 9.21 410.75 9.59 417.21 9.95 423.50 10.28 429.66 10.61 435.71 10.92 441.70 11.22 447.62 11.51 453.50 11.80 459.34 12.08 465.16 12.35 470.96 12.62 476.74 12.88 482.52 13.14 488.30

v

h

s

dm3/kg kJ/kg

kJ/kgK

6.84 7.20 7.73 8.19 8.60 8.98 9.33 9.67 9.99 10.30 10.59 10.88 11.16 11.43 11.70 11.96 12.21 12.46

1.5717 1.5881 1.6124 1.6343 1.6546 1.6739 1.6922 1.7099 1.7270 1.7436 1.7598 1.7756 1.7912 1.8064 1.8213 1.8361 1.8506 1.8649

381.17 386.52 394.54 401.90 408.83 415.48 421.92 428.20 434.37 440.44 446.44 452.39 458.29 464.16 470.01 475.84 481.66 487.47

25.15 bar 54.00°C

s

22.98 bar 50.00°C t

24.04 bar 52.00°C

s

v

h

s

dm3/kg kJ/kg

kJ/kgK

6.40 6.54 7.11 7.59 8.01 8.39 8.75 9.09 9.40 9.71 10.00 10.28 10.55 10.82 11.08 11.33 11.58 11.82

1.5685 1.5745 1.6011 1.6243 1.6456 1.6655 1.6844 1.7025 1.7199 1.7368 1.7532 1.7692 1.7849 1.8003 1.8154 1.8302 1.8448 1.8593

380.93 382.89 391.68 399.49 406.73 413.61 420.23 426.65 432.94 439.11 445.20 451.22 457.19 463.12 469.02 474.89 480.75 486.60

t 58 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140

v 5.59 5.86 6.43 6.89 7.29 7.66 8.00 8.31 8.61 8.90 9.17 9.43 9.69 9.94 10.18 10.42 10.65 10.87

h

s

379.95 384.33 393.69 401.85 409.35 416.42 423.21 429.78 436.19 442.48 448.68 454.80 460.86 466.87 472.85 478.81 484.74 490.66

1.5607 1.5739 1.6018 1.6257 1.6474 1.6676 1.6867 1.7049 1.7225 1.7394 1.7559 1.7720 1.7877 1.8031 1.8182 1.8331 1.8477 1.8621

28.71 bar 60.00°C t 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145

v 5.19 5.85 6.35 6.77 7.15 7.49 7.80 8.10 8.38 8.65 8.91 9.17 9.41 9.65 9.88 10.10 10.32 10.54

h

s

379.14 390.06 398.95 406.89 414.27 421.28 428.03 434.59 441.00 447.29 453.50 459.64 465.72 471.76 477.77 483.75 489.71 495.66

1.5559 1.5885 1.6146 1.6375 1.6586 1.6783 1.6970 1.7150 1.7323 1.7490 1.7653 1.7812 1.7968 1.8121 1.8271 1.8418 1.8563 1.8707

26.30 bar 56.00°C

s

t

v

h

s

kJ/kgK 1.5746 1.6001 1.6227 1.6436 1.6632 1.6819 1.6998 1.7172 1.7340 1.7503 1.7663 1.7819 1.7973 1.8124 1.8272 1.8418 1.8563 1.8705

°°C 56 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140

dm3/kg 5.99 6.49 7.00 7.44 7.83 8.19 8.53 8.85 9.15 9.43 9.71 9.98 10.24 10.49 10.74 10.98 11.22 11.45

kJ/kg 380.54 388.35 396.78 404.42 411.57 418.40 424.99 431.41 437.70 443.88 449.98 456.02 462.02 467.97 473.90 479.80 485.69 491.57

kJ/kgK 1.5649 1.5885 1.6136 1.6360 1.6567 1.6762 1.6947 1.7125 1.7297 1.7464 1.7627 1.7785 1.7941 1.8093 1.8243 1.8390 1.8535 1.8679

SFD-AK T/09.04/02/E

27.48 bar 58.00°C

29

SOLVAY FLUOR

Solkane®404A Thermodynamics Release 1.03

For further information please contact our technical specialists: Solvay Fluor Postfach 220 D-30002 Hannover Telephone: +49-(0)511-857-2653 Telefax: +49-(0)511-857-2166

Disclaimer: All statements, information and data given herein are believed to be accurate and reliable but are presented without guarantee, warranty or responsibility of any kind, express or implied. Statements or suggestions concerning possible use of our products are made without representation or warranty that any such use is free of patent infringement, and are not recommendations to infringe any patent. The user should not assume that all safety measures are indicated, or that other measures may not be required. The product R404A is sold by Solvay in Europe, Middle East and Africa under a license of (a) DuPont de Nemours' European Patent EP 545942 and EP 399817, and (b) ICI's European Patent EP 509673. The sale conveys to the purchaser a sublicense to use or resell such product in Europe, Middle East and Africa. Such product, if installed in Europe, Middle East and Africa within refrigeration or air-conditioning equipment, can be exported worldwide. No other right or license, express or implied, is granted.

SFD-AK T/09.04/02/E

30