Frontiers of Multifunctional Integrated Nanosystems 1402021739, 9781402021732

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Frontiers of Multifunctional Integrated Nanosystems

NATO Science Series A Series presenting the results of scientific meetings supported under the NATO Science Programme. The Series is published by IOS Press, Amsterdam, and Kluwer Academic Publishers in conjunction with the NATO Scientific Affairs Division Sub-Series I. II. III. IV. V.

Life and Behavioural Sciences Mathematics, Physics and Chemistry Computer and Systems Science Earth and Environmental Sciences Science and Technology Policy

IOS Press Kluwer Academic Publishers IOS Press Kluwer Academic Publishers IOS Press

The NATO Science Series continues the series of books published formerly as the NATO ASI Series. The NATO Science Programme offers support for collaboration in civil science between scientists of countries of the Euro-Atlantic Partnership Council. The types of scientific meeting generally supported are “Advanced Study Institutes” and “Advanced Research Workshops”, although other types of meeting are supported from time to time. The NATO Science Series collects together the results of these meetings. The meetings are co-organized bij scientists from NATO countries and scientists from NATO’s Partner countries – countries of the CIS and Central and Eastern Europe. Advanced Study Institutes are high-level tutorial courses offering in-depth study of latest advances in a field. Advanced Research Workshops are expert meetings aimed at critical assessment of a field, and identification of directions for future action. As a consequence of the restructuring of the NATO Science Programme in 1999, the NATO Science Series has been re-organised and there are currently Five Sub-series as noted above. Please consult the following web sites for information on previous volumes published in the Series, as well as details of earlier Sub-series. http://www.nato.int/science http://www.wkap.nl http://www.iospress.nl http://www.wtv-books.de/nato-pco.htm

Series II: Mathematics, Physics and Chemistry – Vol. 152

Frontiers of Multifunctional Integrated Nanosystems edited by

Eugenia Buzaneva Kiev National Taras Shevchenko University, Ukraine and

Peter Scharff Technische Universität Ilmenau, Institut für Physik/FG Chemie, Germany

KLUWER ACADEMIC PUBLISHERS NEW YORK, BOSTON, DORDRECHT, LONDON, MOSCOW

eBook ISBN: Print ISBN:

1-4020-2173-9 1-4020-2171-2

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TABLE OF CONTENTS Photograph of participants………….…………………………………………….....…. ix Preface……………………………………………………………..………………........xi

Part I. Modeling and computer simulation of characteristics nanosystems Optical properties of small-radius SWNTs within a tight-binding model.....…................1 V.N. Popov The electronic structure of nanotubes and the topological arrangements of carbon atoms....................................................................…................11 I. László Irradiation effect on the electron transport properties of single-walled carbon nanotube.......................................................……….....................19 Yu.I. Prylutskyy, O.V. Ogloblya, M.V. Makarets, O.P. Dmytrenko, M.P. Kulish, E.V. Buzaneva, P. Scharff Calculation of the density profile of liquid located in the multi-walled carbon nanotube........................…....…………………………………………….…......23 D.A. Gavryushenko, V.M. Sysoev, L.Yu. Matzui, O.A. Golub, Yu.I. Prylutskyy, O.V. Ogloblya, P. Scharff, Y. Gogotsi Small metal clusters: ab initio calculated bare clusters and models within fullerene cages …………………………………..............……….…….31 V.S. Gurin

Part II. Nanotechnology of building blocks and integrated nanosystems Nanoparticle reactions on chip………………………………………...…………….....39 J.M. Köhler, Th. Kirner, J. Wagner, A. Csáki, R. Möller, W. Fritzsche Electrochemical charging of nanocarbons: fullerenes, nanotubes, peapods ……….......51 L. Kavan, L. Dunsch Nano-encapsulation of fullerene in dendrimers…………………..…………...…..…....63 Y. Rio, G. Accorsi, N. Armaroli, J.-F. Nierengarten Irradiation-controlled adsorption and organization of biomolecules on surfaces: from the nanometric to the mesoscopic level..........................…………….……....…...71 G. Marletta C. Satriano Oriented immobilization of C-reactive protein on solid surface for biosensor applications………………………………………………………………. ....95 G.K. Zhavnerko, S.J.-Yi, S.-H. Chung, J. S. Yuk, K.-S. Ha

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Mesoporous aluminosilicates as a host and reactor for preparation of ordered metal nanowires..………………………………..……….…………………………....109 A.A. Eliseev, K.S. Napolskii, I.V. Kolesnik, Yu.V. Kolenko, A.V. Lukashin, P. Gornert, Yu.D. Tretyakov Part III. Single and assembled molecules, nanoparticles on surface and interface investigations Scanning probe microscopy of biomacromolecules: instrumentation and experiments……………………………………………………………...……......123 G.A. Kiselev, I.V. Yaminsky Surface science tools and their application to nanosystems like C60 on indium phosphide…………………………………………….……………….……....131 J.A. Schaefer, G. Cherkashinin, S Döring, M. Eremtchenko, S. Krischok, D. Malsch, A. Opitz, T. Stolz, R. Temirov. Polarized Raman spectroscopy of single layer and multilayer Ge/Si(001) quantum dot heterostructures…………………………………………….……..…......139 A.V. Baranov, T.S. Perova, S. Solosin, R.A. Moore, V. Yam, Vinh Le Thanh, D. Bouchier Part IV. Fundamental properties of carbon integrated nanosystems Nanosystems of polymerized fullerenes and carbon-nanotubes………………...…....153 P. Scharff, S. Cui Synthesis and characterization of C60-and C70 polymer phases................…………....167 L. Carta-Abelmann, P.Scharff, C. Siegmund, D. Schneider The nanospace inside single-wall carbon nanotubes………………….………..…......171 H. Kuzmany, R. Pfeiffer, Ch. Kramberger, T. Pichler Mechanical properties of carbon thin films ..............………....….............…..…….....185 S. Tamuleviþius, L.Augulis, Š.Meškinis, V.Grigaliunas Part V. Fundamental properties of silicon integrated nanosystems Thin carbon layers on nanostructured silicon - properties and applications.................197 A. Angelescu, I. Kleps, M. Miu, M. Simion, A. Bragaru, S. Petrescu, C. Paduraru, A. Raducanu 1D periodic structures obtained by deep anisotropic etching of silicon.........………...205 E.V. Astrova, T.S. Perova, V.A. Tolmachev Diode Shottky systems on Al - nanosilicon interface layer – Si…………………..….213 G. Vorobets

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Part VI. Multifunctional applications of nanosystems VI.I. Moletronics Nano-bio electronic devices based on DNA bases and proteins.................………….225 R. Rinaldi, G. Maruccio, A. Bramanti, P. Visconti, A. Biasco, V. Arima , S.D’amico, R. Cingolani DNA, DNA/metal nanoparticles, DNA/nanocarbon and macrocyclic metal complex/ fullerene molecular building blocks for nanosystems: electronics and sensing...………..................................................................................251 E. Buzaneva, A. Gorchinskiy, P. Scharff, K. Risch, A. Nassiopoulou, C. Tsamis, Yu. Prilutskyy, O. Ivanyuta, A. Zhugayevych, D. Kolomiyets, A. Veligura, I. Lysko, O. Vysokolyan, O. Lysko, D. Zherebetskyy, A. Khomenko, I. Sporysh VI.II. Electronics and photonics Silicon nanocrystals in SiO² for memory devices........….................................…..…..277 A.G. Nassiopoulou, V.Ioannou-Sougleridis, A. Travlos On the route towards a monolithically integrated silicon photonics……………...…..287 N. Daldosso, L. Pavesi Photoluminescent nanosilicon systems.............................................……….………...299 Vladimir Makara Optical characterisation of opal photonic hetero-crystals .....................……........…...309 Sergei G. Romanov VI.III. Spintronics and magneto-optoelectronics Magnetism in polymerized fullerenes.….............................................................….....331 T. Makarova Application of the electronic properties of carbon nanotubes: computation of the magnetic properties and the 13C NMR shifts.......…………...........343 S. Latil, J.-C. Charlier, A. Rubio, C. Goze-Bac Nanotube spintronics: magnetic systems based on carbon nanotubes...............….…...359 G. M. Schneider, R. Kozhuharova, S. Groudeva-Zotova, B. Zhao, T. Mühl, I. Mönch, H. Vinzelberg, M. Ritschel, A. Leonhardt, J. Fink Spin coherence and manipulation in Si/SiGe quantum wells.....................……….......379 W. Jantsch, Z. Wilamowski Fundamental properties of ferromagnetic micro- and nanostructured films for application in optoelectronics................................................…..……………...……...391 V.P. Sohatsky

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VI.IV. Sensor nanosystems Porous silicon for chemical sensors…………………………………………...............399 C. Tsamis, A. Nassiopoulou Silicon micromachined sensors for gas detection...……………………………….......409 C. Moldovan, G. Vasile, M. Modreanu Microporous zeolite membranes - a useful tool for gas sensing systems.....……….....423 D. Nipprasch, T. Kaufmann, S. Kloeher, K. Risch Genomagnetic electrochemical biosensors…………………………...............….........431 J. Wang, A. Erdem Nanocapsules – a novel tool for medicine and science..........................................…...439 S. Krol, A. Diaspro, O. Cavalleri, D. Cavanna, P. Ballario, B. Grimaldi, P. Filetici, P. Ornaghi, A. Gliozzi Biological molecule conformations probed and enhanced by metal and carbon nanostructures: SEIRA, AFM and SPR data ………………………………………....447 G.I. Dovbeshko, O.P Paschuk, O.M. Fesenko, V.I. Chegel, Yu.M, Shirshov, A.A. Nazarova, D. Kosenkov Concerning signaling in in vitro neural arrays using porous silicon………………….467 S.C. Bayliss, I. Ashraf, A. V. Sapelkin

Subject index ...............................................................................................…....…....473 List of Participants....................................................................................….…….…475

Photographs of the participants to the NATO ARW in Imenau (July 2003)

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