Applications of hydrogen peroxide and derivatives [1 ed.] 0854045368, 9780854045365
Simple, but beautifully versatile
218 86 481KB
English Pages 286 Year 1999
Table of contents :
Front Matter......Page 1
Preface......Page 3
Table of Contents......Page 6
2. Industrial Manufacture of Hydrogen Peroxide......Page 9
3. Physical Properties of Hydrogen Peroxide......Page 22
4. Considerations for the Safe Use of Hydrogen Peroxide......Page 29
5. Toxicology and Occupational Health Aspects of Hydrogen Peroxide......Page 40
6. Conclusion......Page 41
References......Page 42
2. Basic Chemistry of Hydrogen Peroxide......Page 44
3. Activation of Hydrogen Peroxide in the Presence of Inorganic and Organometallic Species......Page 47
4. Activation of Hydrogen Peroxide in the Presence of Organic Compounds......Page 68
5. Stabilization of Aqueous Hydrogen Peroxide......Page 79
6. Conclusion......Page 80
References......Page 81
1. Introduction......Page 85
2. Epoxidation of Alkenes......Page 86
3. Hydroxylation of Olefins......Page 104
4. Oxidative Cleavage of Olefins......Page 109
5. Oxidation of Alcohols......Page 114
6.1 Oxidation of Aldehydes......Page 120
6.2 Oxidation of Ketones......Page 125
7. Oxidation of Aromatic Side-chains......Page 134
8. Oxidation of Organo-nitrogen Compounds......Page 145
9. Oxidation of Organo-sulfur Compounds......Page 152
10. Halogenation......Page 162
11. Reactions at Aromatic Nuclei......Page 168
References......Page 173
1. Introduction......Page 184
2. Redox Zeolites......Page 185
3. Non-crystalline Heterogeneous Catalysts......Page 200
4. Conclusion......Page 207
References......Page 208
1. Introduction......Page 211
2. Advanced Oxidation Processes......Page 213
3. Fenton's Treatment......Page 217
4. Cyanide and NOX Control......Page 221
5. Control of Reduced Sulfur Species......Page 223
6. Contaminated Site Remediation......Page 226
7. Waste Water Treatment......Page 228
8. Conclusion......Page 232
References......Page 233
2. Chemical Purification......Page 235
3. Pulp and Paper......Page 244
4. Hydrometallurgy and Metal Finishing......Page 249
References......Page 255
A......Page 261
B......Page 264
C......Page 265
D......Page 268
F......Page 269
H......Page 270
K......Page 273
M......Page 274
N......Page 276
O......Page 277
P......Page 278
Q......Page 280
S......Page 281
T......Page 283
U......Page 284
W......Page 285
Z......Page 286
Front Matter......Page 1
Preface......Page 3
Table of Contents......Page 6
2. Industrial Manufacture of Hydrogen Peroxide......Page 9
3. Physical Properties of Hydrogen Peroxide......Page 22
4. Considerations for the Safe Use of Hydrogen Peroxide......Page 29
5. Toxicology and Occupational Health Aspects of Hydrogen Peroxide......Page 40
6. Conclusion......Page 41
References......Page 42
2. Basic Chemistry of Hydrogen Peroxide......Page 44
3. Activation of Hydrogen Peroxide in the Presence of Inorganic and Organometallic Species......Page 47
4. Activation of Hydrogen Peroxide in the Presence of Organic Compounds......Page 68
5. Stabilization of Aqueous Hydrogen Peroxide......Page 79
6. Conclusion......Page 80
References......Page 81
1. Introduction......Page 85
2. Epoxidation of Alkenes......Page 86
3. Hydroxylation of Olefins......Page 104
4. Oxidative Cleavage of Olefins......Page 109
5. Oxidation of Alcohols......Page 114
6.1 Oxidation of Aldehydes......Page 120
6.2 Oxidation of Ketones......Page 125
7. Oxidation of Aromatic Side-chains......Page 134
8. Oxidation of Organo-nitrogen Compounds......Page 145
9. Oxidation of Organo-sulfur Compounds......Page 152
10. Halogenation......Page 162
11. Reactions at Aromatic Nuclei......Page 168
References......Page 173
1. Introduction......Page 184
2. Redox Zeolites......Page 185
3. Non-crystalline Heterogeneous Catalysts......Page 200
4. Conclusion......Page 207
References......Page 208
1. Introduction......Page 211
2. Advanced Oxidation Processes......Page 213
3. Fenton's Treatment......Page 217
4. Cyanide and NOX Control......Page 221
5. Control of Reduced Sulfur Species......Page 223
6. Contaminated Site Remediation......Page 226
7. Waste Water Treatment......Page 228
8. Conclusion......Page 232
References......Page 233
2. Chemical Purification......Page 235
3. Pulp and Paper......Page 244
4. Hydrometallurgy and Metal Finishing......Page 249
References......Page 255
A......Page 261
B......Page 264
C......Page 265
D......Page 268
F......Page 269
H......Page 270
K......Page 273
M......Page 274
N......Page 276
O......Page 277
P......Page 278
Q......Page 280
S......Page 281
T......Page 283
U......Page 284
W......Page 285
Z......Page 286
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