Advances in Organic Synthesis: Volume 10 [10] 9781681087443

Table of contents :
Cover
Advances in Organic Synthesis: Volume 10
Copyright
End User License Agreement
Contents
Preface
List of Contributors
1. Organocatalytic α-hydroxylation or α-aminoxylation of Carbonyl Compounds
Abstract
Introduction
Functionalisation of Aldehydes and Ketones
α-Aminoxylation Reactions with Nitrosobenzene or Derivatives
First Publications: the “Classical Method”
Generalities
α-Aminoxylation Reactions in Aqueous Media
α-Aminoxylation Reactions in Ionic Liquids
α-Aminoxylation Reactions in Continuous Flow Systems
Oxidative α-C-H N,O-ketalization of Ketone
α-Oxybenzoylation Reactions
α-Aminoxylation Reactions with TEMPO
First Publications: the “Classical Method”
TEMPO α-aminoxylation Reactions Without Metal
Electrochemical Oxidation
Organophotocatalysis
Singlet Oxygen
Α-Functionalisation of 1,3-dicarbonyl Compounds
Conclusion
Consent for Publication
Conflict of Interest
Acknowledgements
References
2. Achmatowicz Rearrangement Derived Synthons, and their Relevant Bioinspired Chemistry
Abstract
Introduction
Natural Products Containing Six-Membered Oxygen Ring Substructures
Furyl Carbinols and Their Rearrangements
Achmatowicz Rearrangement; Reagents, Conditions, and Procedures
Some Synthetically Useful Transformations of Pyranosuloses Generated via AR
Applications of the Achmatowicz Rearrangement to Total Syntheses of Natural Products
MONOSACCHARIDES
Non-Carbohydrate Natural Products
AR-Derived Pyranosuloses as Versatile Glycosylation and Glycoconjugation Synthons
Conclusion
Consent for Publication
Conflict of Interest
Acknowledgements
Abbreviations
References
3. Recent Advances in the Synthesis of N-Glycosyl Compounds
Abstract
Introduction
Free Glycosylamines and their N-alkyl and N-aryl Glycosyl Compounds
N-Glycosylhydroxylamines and Alkoxyamines
N-Glycosylamino Acids
N-Glycosylamides
N-Glycosylsulfonamides, -sulfamides and -sulfinamides
N-Glycosylhydrazines
N-Glycosylphosphoramidates and -phosphonamidates
N-Glycosylimines and -imides
Concluding Remarks
Consent for Publication
Conflict of Interest
Acknowledgements
References
4. Acidic and Basic Functionalized Ionic Liquid Systems for Advanced Synthesis of Five and Six Membered Nitrogenates Heterocycles
Abstract
Introduction on Ionic Liquid Systems
Different Classification of Ionic Liquids
1. Based on Number of Cation
2. Based on Type of Anion
3. Based on Acidity
4. Based on Physical Properties
Sustainable Organic Synthesis and Functionalized Ionic Liquids
Advantages of One-Pot Protocol in Organic Reactions
Use of Functionalized Ionic Liquids in One-Pot Synthesis of Five Membered N- Heterocycles
Pyrroles
Pyrazoles
Imidazoles
Use of Functionalized Ionic Liquids in One-Pot Synthesis of Six Membered N-Heterocycles
Pyridines
Quinolines
Acridines
Pyrimidines
Conclusion and Future Scopes
Consent for Publication
Conflict of Interest
Acknowledgements
References
5. Mesoporous SBA-15: A Superior Heterogeneous Catalytic Support for Multicomponent Organic Synthesis
Abstract
Introduction
Surface Modifications of Mesoporous Silica Materials
Grafting Methods
Grafting with Passive Surface Groups
Grafting with Reactive Surface Groups
Site-selective Grafting
Co-condensation Reactions
Mesoporous SBA-15 as Support or Host
Encapsulation of Nanoparticles on Mesoporous SBA-15 Support for Catalytic Application
Immobilization of Transition Metal Complexes/Salts and Organic Species on Functionalized Mesoporous SBA-15 Support for Catalytic Application
Immobilization of Heteropolyacids on Functionalized Mesoporous SBA-15 Support for Catalytic Application
Multicomponent Reactions
Three Component Coupling
A3 Coupling Reaction
Biginelli Reaction
Mannich Reaction
Some Other Three Component Coupling Reactions
Four Component Reaction/Pseudo Four Component Reaction
Conclusion
Conflict of Interest
Conflict of Interest
Acknowledgements
References
Subject Index
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