Modern Aspects of Electrochemistry №18 [1 ed.] 9780306423123, 0-306-42312-X
241 93 119KB
English Pages 374 Year 1986
Table of contents :
FM......Page 2
Preface......Page 4
Contents......Page 5
I. INTRODUCTION......Page 11
II. ELECTRONIC ENERGY LEVELS OF SEMICONDOCTOR AND ELECTROLYTE......Page 12
III. POTENTIAL DISTRIBUTION AT SEMICONDUCTOR / ELECTROLYTE INTERFACE......Page 23
IV. DISTRIBUTION OF ENERGY STATES FOR IONS OF REDOX SYSTEM IN SOLUTION......Page 33
V. RATE EXPRESSIONS FOR ELECTRON TRANSFER AT ILLUMINATED INTERFACE......Page 47
VI. CONCLUDING REMARKS......Page 64
REFERENCES......Page 65
Ch 2. Photoelectrochemical Devices for Solar Energy Conversion......Page 71
I. SEMICONDUCTOR ELECTRODES......Page 72
II. MATHEMATICAL DESCRIPTION......Page 79
III. PHOTOELECTROCHEMICAL CELL DESIGN......Page 94
IV. CONCLUSIONS......Page 108
NOTATION......Page 109
REFERENCES......Page 111
I. INTRODUCTION......Page 123
II. MODELING NONENZYMATIC SYSTEMS OF ELECTRON TRANSFER......Page 125
III. POTENTIAL GENERATION ON BILAYER MEMBRANES CONTAINING CHLOROPHYLL......Page 147
IV. POSSIBLE MECHANISMS OF THE MOTION OF ELECTRONS AND PROTONS IN THE MEMBRANE......Page 154
V. CONCLUSIONS......Page 171
REFERENCES......Page 173
I. INTRODUCTION......Page 179
II. FORMATION OF HYDROUS OXIDES......Page 181
III. ACID-BASE PROPERTIES OF OXIDES......Page 183
IV. STRUCTURAL ASPECTS OF HYDROUS OXIDES......Page 189
V. TRANSPORT PROCESSES IN V. TRANSPORT PROCESSES IN......Page 192
VI. THEORETICAL MODELS OF THE VI. THEORETICAL MODELS OF THE......Page 198
VII. PLATINUM......Page 201
VIII. PALLADIUM......Page 215
IX. GOLD......Page 218
X. IRIDIUM......Page 223
XI. RHODIUM......Page 234
XII. RUTHENIUM......Page 237
XIII. SOME NONNOBLE METALS......Page 240
XIV. CONCLUSION......Page 249
ADDENDUM......Page 251
REFERENCES......Page 253
I. INTRODUCTION......Page 259
II. CHEMICAL AND ELECTROCHEMICAL PRINCIPLES......Page 260
III. MANUFACTURING PROCESSES......Page 263
IV. ELECTRODE MATERIALS AND IV. ELECTRODE MATERIALS AND......Page 273
V. ENGINEERING ASPECTS IN V. ENGINEERING ASPECTS IN......Page 280
VI. ION-EXCHANGE MEMBRANES AND VI. ION-EXCHANGE MEMBRANES AND......Page 297
NOTATION......Page 307
REFERENCES......Page 308
I. INTRODUCTION......Page 313
II. NUCLEATION, GROWTH, AND DETACHMENT OF BUBBLES......Page 314
III. ELECTRICAL EFFECTS OF GAS EVOLUTION......Page 328
IV. MASS TRANSFER AT GAS-EVOLVING ELECTRODES......Page 352
V. SUMMARY......Page 358
NOTATION......Page 359
REFERENCES......Page 362
Index......Page 365
FM......Page 2
Preface......Page 4
Contents......Page 5
I. INTRODUCTION......Page 11
II. ELECTRONIC ENERGY LEVELS OF SEMICONDOCTOR AND ELECTROLYTE......Page 12
III. POTENTIAL DISTRIBUTION AT SEMICONDUCTOR / ELECTROLYTE INTERFACE......Page 23
IV. DISTRIBUTION OF ENERGY STATES FOR IONS OF REDOX SYSTEM IN SOLUTION......Page 33
V. RATE EXPRESSIONS FOR ELECTRON TRANSFER AT ILLUMINATED INTERFACE......Page 47
VI. CONCLUDING REMARKS......Page 64
REFERENCES......Page 65
Ch 2. Photoelectrochemical Devices for Solar Energy Conversion......Page 71
I. SEMICONDUCTOR ELECTRODES......Page 72
II. MATHEMATICAL DESCRIPTION......Page 79
III. PHOTOELECTROCHEMICAL CELL DESIGN......Page 94
IV. CONCLUSIONS......Page 108
NOTATION......Page 109
REFERENCES......Page 111
I. INTRODUCTION......Page 123
II. MODELING NONENZYMATIC SYSTEMS OF ELECTRON TRANSFER......Page 125
III. POTENTIAL GENERATION ON BILAYER MEMBRANES CONTAINING CHLOROPHYLL......Page 147
IV. POSSIBLE MECHANISMS OF THE MOTION OF ELECTRONS AND PROTONS IN THE MEMBRANE......Page 154
V. CONCLUSIONS......Page 171
REFERENCES......Page 173
I. INTRODUCTION......Page 179
II. FORMATION OF HYDROUS OXIDES......Page 181
III. ACID-BASE PROPERTIES OF OXIDES......Page 183
IV. STRUCTURAL ASPECTS OF HYDROUS OXIDES......Page 189
V. TRANSPORT PROCESSES IN V. TRANSPORT PROCESSES IN......Page 192
VI. THEORETICAL MODELS OF THE VI. THEORETICAL MODELS OF THE......Page 198
VII. PLATINUM......Page 201
VIII. PALLADIUM......Page 215
IX. GOLD......Page 218
X. IRIDIUM......Page 223
XI. RHODIUM......Page 234
XII. RUTHENIUM......Page 237
XIII. SOME NONNOBLE METALS......Page 240
XIV. CONCLUSION......Page 249
ADDENDUM......Page 251
REFERENCES......Page 253
I. INTRODUCTION......Page 259
II. CHEMICAL AND ELECTROCHEMICAL PRINCIPLES......Page 260
III. MANUFACTURING PROCESSES......Page 263
IV. ELECTRODE MATERIALS AND IV. ELECTRODE MATERIALS AND......Page 273
V. ENGINEERING ASPECTS IN V. ENGINEERING ASPECTS IN......Page 280
VI. ION-EXCHANGE MEMBRANES AND VI. ION-EXCHANGE MEMBRANES AND......Page 297
NOTATION......Page 307
REFERENCES......Page 308
I. INTRODUCTION......Page 313
II. NUCLEATION, GROWTH, AND DETACHMENT OF BUBBLES......Page 314
III. ELECTRICAL EFFECTS OF GAS EVOLUTION......Page 328
IV. MASS TRANSFER AT GAS-EVOLVING ELECTRODES......Page 352
V. SUMMARY......Page 358
NOTATION......Page 359
REFERENCES......Page 362
Index......Page 365
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