Fungicides, Biocides And Preservative For Industrial And Agricultural Applications [1st edition] 9780815511250, 0815511256

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FUNGICIDES, BIOCIDES AND PRESERVATIVES FOR INDUSTRIAL AND AGRICULTURAL APPLICATIONS

by

Ernest W. Flick

NOYES PUBLICATIONS Pa* Ridge, New Jersey, U.S.A.

Copyright 0 1 9 8 7 b y Ernest W. Flick No part o f this book may be reproduced in any f o r m without permission in writing f r o m the Publisher. Library o f Congress Catalog Card Number: 87-13742 ISBN: 0-8155-1125-6 Printed in the United States Published in the United States of America b y Noyes Publications Mill Road, Park Ridge, New Jersey 07656 109876 5 4 3 2 1

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Library o f Congress Cataloging-inPublication Data Flick, Ernest W. Fungicides, biocides, and preservatives for industrial and agricuttural applications.

Includes index. 1. Fungicides. 2. Chemical preservatives. I . Title. TP248.F79F57 1987 668'.652 87-13742 ISBN 08155-1125-6

Copyright 0 1 9 8 7 b y Ernest W. Flick No part o f this book may be reproduced in any f o r m without permission in writing f r o m the Publisher. Library o f Congress Catalog Card Number: 87-13742 ISBN: 0-8155-1125-6 Printed in the United States Published in the United States of America b y Noyes Publications Mill Road, Park Ridge, New Jersey 07656

To the Late Dr. and Mrs. Clinton H. Bagenstose 109876 5 4 3 2 1

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Library o f Congress Cataloging-inPublication Data Flick, Ernest W. Fungicides, biocides, and preservatives for industrial and agricuttural applications.

Includes index. 1. Fungicides. 2. Chemical preservatives. I . Title. TP248.F79F57 1987 668'.652 87-13742 ISBN 08155-1125-6

Preface

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This volume describes approximately 350 fungicides, biocides and preservatives which are currently available for industrial and agricultural usage. The book will be of value to industrial and agricultural, technical and managerial personnel involved in the specification and use of these products. It has been compiled from information received from numerous industria! companies and other organizations. The data included represent selections from manufacturers' descriptions made a t no cost to, nor influence from, the makers or distributors of these materials. All products have U.S. Environmental Protection Agency registration numbers, indicating the EPA has approved product labeling, without which the product may not be sold, legally, in the United States. It should be noted that all products cannot necessarily be sold in every state in the U.S. Some states have certain restrictions on formulations permitted for use. It is the responsibility of the user to check with the manufacturer as to whether any of these restrictions applies in a particular geographic location. Only the most recent information has been included. It i s believed that all of the products listed here are currently available, which will be of utmost interest to readers concerned with product discontinuances.

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Products are presented by company, and the companies are listed alphabetically. The table of contents i s organized in such a way as to serve as a subject index to the book. Also included are a Trade Name Index and a Chemical Name Index, for easy and rapid location of products by the reader. In addition, another section, which will be useful, contains the Suppliers' Addresses. It can be found immediately following the Product Information section.

viii

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The book lists the following product information, as available, in the manufacturer's own words:

(1) Company name and product category. (2) Trade name and product numbers.

(3) Product Description: a description of the product, as presented by the supplier.

(4) EPA registration number. This book should prove to be valuable as a guide for the industrial and agricuIturaI communities. My fullest appreciation is expressed t o the companies and organizations who supplied the data included in this book. Newburyport, Massachusetts July 1987

Ernest W. Flick

NOTICE To the best of our knowledge the information in this publication i s accurate; however the Publisher does not assume any responsibility for the accuracy or completeness of, or consequences arising from, such information. This industrial guide does not purport to contain detailed user instructions, and by i t s range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher.

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Fungicide, biocide and preservative raw materials can be toxic, and therefore due caution should always be exercised in the use of these hazardous materials. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to a manufacturer's or supplier's current instructions for handling each material they use. The author and Publisher have used their best efforts to include only fungicides approved by the U.S. Environmental Protection Agency. However, prior to use of a specific fungicide, readers are cautioned to verify current approval status.

Contents

Preface ....................................................................................

vii

Notice ........................................................................................ viii Product Information Abbott - Buckman Laboratories ......

2

Abbott Laboratories ...............................................................................

2

AMICAL Flowable Preservative ................................................

2

AMICAL 48 Preservative ..........................................................

3

AMICAL 50 Preservative for Latex Paints ................................

4

Agtrol Chemical Products .....................................................................

5

Agricultural Fungicides .............................................................

5

CHAMPION Wettable Powder ..............................................

5

COPZIN Wettable Powder ....................................................

5

CHAMPION Flowable ...........................................................

5

Alco Chemical Corp. .............................................................................

6

AQUATREAT Microbiocides ....................................................

6

AQUATREAT DNM-30 ..........................................................

6

AQUATREAT DNM-360 ........................................................

6

AQUATREAT DNM-9 ............................................................

6

AQUATREAT SDM ...............................................................

6

AQUATREAT KM ..................................................................

6

American Cyanamid Company .............................................................

7

CYPREX 65-W Fruit Fungicide ................................................

7

Angus Chemical Company ...................................................................

8

BIOBAN CS-1135 Preservative ................................................

8

BIOBAN CT In-Can Paint Preservative ....................................

9

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ix

x Contents BIOBAN GK ............................................................................. 10 BIOBAN N-95 Preservative for Metal-Working Fluids ............... 11 BIOBAN P-1487 Broad-Spectrum Antimicrobial Agent ............. 12 BODOXIN ................................................................................ 13 FUELSAVER Antimicrobial Agent ............................................ 14 S.S.T. SUMP SAVER TABLETS .............................................. 15 TRIS NITRO ............................................................................ 16 Bedford Chemical Division .................................................................... 17 MICRO-CHEK Antimicrobials ................................................... 17 MICRO-CHEK 11 ..................................................................

17

MICRO-CHEK 11D ...............................................................

17

MICRO-CHEK 11 DIDP ........................................................

17

MICRO-CHEK 11 S-711 .......................................................

17

MICRO-CHEK 11 S-160 .......................................................

17

MICRO-CHEK 11 IPA ...........................................................

17

MICRO-CHEK 11 T ...............................................................

17

Beecham Home Improvement Products, Inc. ...................................... 18 Water Based WOODLIFE: 4-1 Concentrate & Ready-to-Use ... 18 WOODLIFE-F Water Repellent Preservative for Wood ............ 19 Betz Energy Chemicals, Inc. ................................................................. 20 BETZ ENCHEM Biocides ......................................................... 20 BETZ ENCHEM 41-J1 Biocide .............................................

20

BETZ ENCHEM 41-J2 Biocide .............................................

21

BETZ ENCHEM 41-J3 Biocide .............................................

22

BETZ ENCHEM 41-J4 Biocide .............................................

23

BETZ ENCHEM 41-J5 Biocide .............................................

24

BETZ ENCHEM 41-J6 Biocide .............................................

25

BETZ ENCHEM 41-J7 Biocide .............................................

26

Betz Laboratories, Inc. .......................................................................... 27 BETZ ENTEC 343 Slime Control Agent ................................... 27 This page has been reformatted by Knovel to provide easier navigation.

Contents xi BETZ Slimicides ...................................................................... 28 BETZ Slimicide C-31 .............................................................

28

BETZ Slimicide C-58P ..........................................................

29

BETZ Slimicide C-63P ..........................................................

30

BETZ Slimicide C-70 .............................................................

31

BETZ Slimicide J-12 .............................................................

32

BETZ Slimicide 508 ..............................................................

33

Buckman Laboratories .......................................................................... 34 BUSAN 40 ............................................................................... 34 BUSAN 90 ............................................................................... 35

Product Information Calgon Corp. - Dupont ..................... 36 Calgon Corp. ......................................................................................... 36 Microbiocides ........................................................................... 36 H-130 Microbiocide ...............................................................

36

H-204 Microbiocide ...............................................................

37

H-212 Microbiocide ...............................................................

38

H-300 Microbiocide ...............................................................

39

H-380 Microbiocide ...............................................................

40

H-430 Microbiocide ...............................................................

41

H-450 Microbiocide ...............................................................

42

H-510 Microbiocide ...............................................................

43

H-900 Microbiocide ...............................................................

44

H-900G Microbiocide ............................................................

45

BIOCHEK 240 .......................................................................... 46 MERBAC-35 ............................................................................ 47 METASOL D3T ........................................................................ 48 METASOL D3T-A .................................................................... 49 TEKTAMER 38 ........................................................................ 50 TEKTAMER 38 A.D. ................................................................ 51 TEKTAMER 38 LV ................................................................... 52 This page has been reformatted by Knovel to provide easier navigation.

xii Contents TK-100

................................................................................... 53

TK-100 DISPERSION W .......................................................... 54 California Products Corporation ........................................................... 55 Wood Preservatives ................................................................. 55 STORM STAIN Linseed Oil Stain & Wood Preservative .......

55

STORM STAIN Penetrating Wood Preservative ...................

56

STORM STAIN Underground Wood Preservative ................

56

Chapman Chemical Co. ........................................................................ 57 CUNAPSOL-5 Water-Borne Copper Naphthenate ................... 57 MITROL G-ST Antimicrobial Agent .......................................... 58 MITROL PQ-8 for Control of Sapstain and Mold on Wood ....... 59 MITROL PQ-15 RTU ................................................................ 60 MITROL PO-56 Antimicrobial-Preservative .............................. 61 MITROL PQ-57 ........................................................................ 62 WOODGUARD ........................................................................ 63 W.A. Cleary Chemical Corp. ................................................................. 64 Fungicides ............................................................................... 64 3336 (TM) Turf and Ornamental Fungicide ...........................

64

3336-F Systemic Turf and Ornamental Fungicide ................

65

BROMOSAN .........................................................................

66

BROMOSAN-F ......................................................................

67

CADDY .................................................................................

68

CLEARY'S CAD-TRETE GRANULAR TURF FUNGICIDE ...

69

CLEARY'S GRANULAR TURF FUNGICIDE ........................

70

PMAS

..................................................................................

71

SPOTRETE-F .......................................................................

72

SPOTRETE 75W ..................................................................

73

Cosan Chemical Corporation ............................................................... 74 COSAN 91 ............................................................................... 74 COSAN 101 ............................................................................. 75 This page has been reformatted by Knovel to provide easier navigation.

Contents xiii COSAN 145 ............................................................................. 76 COSAN 158 ............................................................................. 77 COSAN 265 ............................................................................. 78 COSAN 635-W ......................................................................... 79 COSAN JTA-20 ........................................................................ 80 COSAN JTA-46 ........................................................................ 81 COSAN P ................................................................................. 82 COSAN PCMC ......................................................................... 83 COSAN PMA-30 ...................................................................... 84 COSAN PMA-100 .................................................................... 85 COSAN PMO-30 ...................................................................... 86 COSAN S ................................................................................. 87 COTIN 234 ............................................................................... 88 COTIN 300 ............................................................................... 89 Dexol Industries .................................................................................... 90 DEXOL ACTI-DIONE PM Rose Fungicide ............................... 90 DEXOL BENOMYL Systemic Fungicide ................................... 91 DEXOL Bordeaux Mixture ........................................................ 92 DEXOL Maneb Garden Fungicide ............................................ 93 DEXOL THIRAM PLUS Lawn Fungicide Contains ACTIDIONE ............................................................................. 94 DEXOL ZINEB Garden Fungicide ............................................ 95 Diamond Shamrock Chemicals Co. ..................................................... 96 NOPCOCIDE Fungicides ......................................................... 96 NOPCOCIDE N-40-D ............................................................

96

NOPCOCIDE N-96 ...............................................................

96

NOPCOCIDE N-96-S ............................................................

97

Dow Chemical U.S.A. ........................................................................... 98 DBNPA 2,2-Dibromo-3-Nitrilopropionamide ............................. 98 DOW Antimicrobial 7287 .......................................................

98

DOW Antimicrobial 8536 .......................................................

98

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xiv Contents DOWICIDE 1 Antimicrobial ...................................................

99

DOWICIDE A Antimicrobial ................................................... 100 DOWICIL 75 Preservative ..................................................... 101 Dupont ................................................................................................... 102 Agricultural Products ................................................................ 102 BENLATE Fungicide Wettable Powder ................................. 102 BENLATE PNW Fungicide Wettable Powder ....................... 102 MANZATE 200 Fungicide Wettable Powder ......................... 102 MANZATE 200 Flowable Fungicide Liquid Suspension ........ 103 TERSAN 1991 Fungicide Wettable Powder .......................... 103 TERSAN LSR Fungicide Wettable Powder ........................... 103

Product Information Eastern Company - Koppers Co. ..... 104 Eastern Color & Chemical Company .................................................... 104 ECCO MP-170-CONC400 ........................................................ 104 ECCO MP-400 ......................................................................... 105 ECCO MP-2004 ....................................................................... 106 ECCOCIDE CW CONC ............................................................ 107 FMC Corporation .................................................................................. 108 FUNGINEX 1.6 EC Fungicide .................................................. 108 Great Lakes Chemical Corp. ................................................................ 109 BROMICIDE Microbiocide ........................................................ 109 Griffin Corp. ........................................................................................... 110 Fungicides ............................................................................... 110 BASICOP .............................................................................. 110 CAPTEC 4L .......................................................................... 111 DU-TER Flowable ................................................................. 112 K-COP ................................................................................... 113 KOCIDE 20/20 ...................................................................... 114 KOCIDE 101 ......................................................................... 115 KOCIDE 404S ....................................................................... 116 This page has been reformatted by Knovel to provide easier navigation.

Contents xv KOCIDE 606 ......................................................................... 117 KOCIDE SD .......................................................................... 118 MANEX ................................................................................. 119 PRO-TEX .............................................................................. 120 SUPER SIX ........................................................................... 121 SUPER TIN 4L ...................................................................... 122 Gustafson, Inc. ...................................................................................... 123 Grain and Seed Treating Chemicals ........................................ 123 GUSTAFSON APRON-FL Seed Treatment Fungicide ......... 123 GUSTAFSON APRON 25W .................................................. 123 GUSTAFSON BOTRAN-30C ................................................ 124 GUSTAFSON Captan-DCNA 60-20 ...................................... 124 GUSTAFSON Captan 400 .................................................... 125 GUSTAFSON Captan 400-D ................................................ 125 GUSTAFSON Captan Methoxychlor 75-5 ............................. 125 GUSTAFSON Captan 75% ................................................... 126 GUSTAFSON Captan 300 .................................................... 126 GUSTAFSON Captan 30-DD ................................................ 126 KE Chloroneb 65W Fungicide ............................................... 127 GUSTAFSON EVERSHIELD C ............................................ 127 GUSTAFSON EVERSHIELD II ............................................. 127 GUSTAFSON FLO-PRO D Seed Protectant ........................ 128 GUSTAFSON FLO-PRO-IMZ ............................................... 128 GUSTAFSON 4-Way ............................................................ 128 GUSTAFSON Flowable Lindane 40% .................................. 129 GUSTAFSON Lindane 30C Flowable ................................... 129 GUSTAFSON LORSBAN 30 Flowable ................................. 129 Flowable (Water Dispersible Suspension) MERTECT LSP Fungicide Wheat Seed Treatment ............................. 129 GUSTAFSON Methoxychlor 300 .......................................... 130 GUSTAFSON PRO-GRO ...................................................... 130 This page has been reformatted by Knovel to provide easier navigation.

xvi Contents GUSTAFSON RTU-PCNB .................................................... 130 GUSTAFSON RTU-PCNB/LINDANE .................................... 131 GUSTAFSON TERRA-COAT L-21N ..................................... 131 GUSTAFSON TERRA-COAT L-205N ................................... 131 GUSTAFSON TERRA-COAT LT-2N .................................... 132 GUSTAFSON TERRACLOR SUPER-X 20-5 Dust with Graphite .................................................................... 132 GUSTAFSON TERRACLOR SUPER-X with MOLY ............. 132 GUSTAFSON Thiram-30 Fungicide ...................................... 133 GUSTAFSON Thiram 50WP Dyed ....................................... 133 GUSTAFSON 42-S ............................................................... 133 GUSTAFSON TOPS-2.5D .................................................... 133 VITAVAX Fungicide .............................................................. 134 GUSTAFSON VITAVAX CAPTAN 20-20 Seed Protectant ... 134 GUSTAFSON VITAVAX-HB POUR-ON Flowable Fungicide ................................................................... 134 GUSTAFSON VITAVAX-Maneb-Lindane ............................. 135 GUSTAFSON VITAVAX-PCNB ............................................ 135 GUSTAFSON VITAVAX-34 .................................................. 135 VITAVAX-30C Concentrate .................................................. 136 VITAVAX-200 ........................................................................ 136 Hopkins Agricultural Chemical Co. ....................................................... 137 DICHLONE Wettable Powder Fungicide .................................. 137 Kincaid Enterprises, Inc. ....................................................................... 138 CHLORONEB Fungicide .......................................................... 138 Fungicides ............................................................................... 139 TERRANEB SP Turf Fungicide ............................................. 139 CHLORONEB 65W Fungicide .............................................. 139 Koppers Co., Inc. .................................................................................. 140 COPPER TREAT 110 Ready-to-Use Wood Preservative ......... 140 COPPER TREAT 120 Ready-to-Use Wood Preservative ......... 141 This page has been reformatted by Knovel to provide easier navigation.

Contents xvii Sapstein Control Chemical NP-1 .............................................. 142 TIMBERTREAT 625 Insecticide ............................................... 143 TRIBUCIDE P-75 Concentrate Water Repellent Wood Preservative .................................................................... 144 TRIBUCIDE P-75 Ready to Use Water Repellent Wood Preservative .................................................................... 145 WOLMAN Treat OO Ready-to-Use Wood Preservative for Field Treatment ............................................................... 146 WOODTREAT C81 Ready to Use Water Repellent Fungicide ......................................................................... 147 WOODTREAT MB Ready-to-Use Water Repellent Wood Preservative .................................................................... 148 WOODTREAT WB Concentrate Water Repellent Wood Preservative .................................................................... 149

Product Information Leffingwell - Nuodex, Inc. ................ 150 Leffingwell ............................................................................................. 150 NUTRA-SPRAY COPPER Fungicides ..................................... 150 NUTRA-SPRAY COPPER BORDEAUX 22 .......................... 150 NUTRA-SPRAY BASIC COPPER CARBONATE ................. 150 M&T Chemicals, Inc. ............................................................................. 151 BIOMET TBTF (Tributyltin Fluoride) Anti-Foulant for Marine Paints .............................................................................. 151 BIOMET TBTO Antifoulant Bis (tributyltin) Oxide for Shipbottom Paints ........................................................... 152 BIOMET 14 Antimicrobial Compound for Protection of PVC Systems .......................................................................... 153 BIOMET 430/45 Antifoulant for Marine Paints .......................... 154 MAAG Agrochemicals, Inc. ................................................................... 155 NYTEK 10 ................................................................................ 155 NYTEK 10WP .......................................................................... 156 NYTEK 645 Penetrant Sealer .................................................. 157 This page has been reformatted by Knovel to provide easier navigation.

xviii Contents NYTEK WD .............................................................................. 158 Mallinckrodt, Inc. ................................................................................... 159 Products for Horticulture .......................................................... 159 BANROT ............................................................................... 159 MILBAN Brand Mildew Fungicide ......................................... 160 ORNALIN Contact Fungicide 50% Wettable Powder ............ 161 TRUBAN 5-G Fungicide ........................................................ 162 TRUBAN Flowable ................................................................ 163 TRUBAN Fungicide 25% Emulsifiable Concentrate .............. 164 TRUBAN Fungicide 30% Wettable Powder .......................... 165 ZYBAN .................................................................................. 166 Turf Products ........................................................................... 167 CADMINATE ......................................................................... 167 CALO-CLOR ......................................................................... 168 CALO-GRAN ......................................................................... 169 DUOSAN ............................................................................... 170 FUNGO 50 ............................................................................ 171 KOBAN 1.3G ......................................................................... 172 KOBAN 30 ............................................................................ 173 KOBAN Flowable .................................................................. 174 KROMAD .............................................................................. 175 THIRAMAD ........................................................................... 176 VORLAN ............................................................................... 177 Miller Chemical & Fertilizer Corp. ......................................................... 178 Fungicides ............................................................................... 178 BENOMYL 50W Systemic Fungicide .................................... 178 Lime Sulfur Solution .............................................................. 178 MANEB Garden Fungicide .................................................... 178 Mobay Chemical Corp. ......................................................................... 179 BAYLETON Fungicide ............................................................. 179 This page has been reformatted by Knovel to provide easier navigation.

Contents xix Mooney Chemicals, Inc. ....................................................................... 180 M-GARD Registered Wood Preservatives ................................ 180 M-GARD W110 ..................................................................... 180 M-GARD S120 ...................................................................... 180 M-GARD W150 ..................................................................... 180 M-GARD S150 ...................................................................... 180 M-GARD W550 ........................................................................ 181 Mooney M-GARD S520 ........................................................... 182 Registered Fungicides ............................................................. 183 8% COPPER NAP-ALL ......................................................... 183 6% COPPER NAP-ALL ......................................................... 183 8% ZINC NAP-ALL ............................................................... 183 Morton Thiokol, Inc. .............................................................................. 184 CUNILATE Fungicides ............................................................. 184 CUNILATE 2419 ................................................................... 184 CUNILATE 2174-NO ............................................................. 184 CUNILATE 2419-75 .............................................................. 184 CUNIPHEN Fungistatic Treatment for Textiles ......................... 185 CUNIPHEN 2713 .................................................................. 185 CUNIPHEN 2721 .................................................................. 185 CUNIPHEN 2721-C .............................................................. 185 CUNIPHEN 2762 .................................................................. 185 CUNIPHEN 2778-I ................................................................... 186 DUROTEX Antimicrobials ........................................................ 187 DUROTEX 7599 ................................................................... 187 DUROTEX 7603 ................................................................... 187 DUROTEX 7604 ................................................................... 187 DUOTEX GPM ...................................................................... 187 SOCCI Fungistatic Treatments ................................................ 188 SOCCI 3500 Fungistatic Treatment for Industrial Textiles Applications ............................................................... 188 This page has been reformatted by Knovel to provide easier navigation.

xx Contents SOCCI 3500-WP Fungistatic/Water Repellent Treatment for Industrial Textile Applications ............................... 188 SOCCI 30 Fungistatic Treatment for Rope and Cordage ..... 188 VINYZENE Antimicrobials ........................................................ 189 BP-5-2 .................................................................................. 189 BP-5-2DIDP .......................................................................... 189 BP-5-2DOP ........................................................................... 189 BP-5-2PG .............................................................................. 189 BP-5-2S-160 ......................................................................... 189 BP-5-2U ................................................................................ 189 VINYZENE Antimicrobials: Antimicrobial Additives for Plastics ............................................................................ 190 BP-5

.................................................................................. 190

BP-5 DIDP ............................................................................ 190 BP-5 DOP ............................................................................. 190 BP-5 RG ................................................................................ 190 BP-5 S-160 ........................................................................... 190 BP-5-2 MEK .......................................................................... 191 BP-5-2 MS ............................................................................ 191 VINYZENE Antimicrobials: Bacteriostatic and Fungistatic Additives for Plastic Compounds ..................................... 192 BP-505 .................................................................................. 192 BP-505 DIDP ........................................................................ 192 BP-505 DOP ......................................................................... 192 BP-505 PG ............................................................................ 192 BP-505 S160 ......................................................................... 192 VINYZENE BP-5SIL3 Antimicrobial Additive for Plastics .......... 193 VINYZENE SB-1 Antimicrobial Additive for Plastics ................. 194 VINYZENE SB-1 EAA Antimicrobial Additive for Plastics ......... 195 VINYZENE SB-1 ELV Antimicrobial Additive for Plastics ......... 196 VINYZENE SB-1 NY Antimicrobial Additive for Plastics ........... 197 This page has been reformatted by Knovel to provide easier navigation.

Contents xxi VINYZENE SB-1 PR Antimicrobial Additive for Plastics ........... 198 VINYZENE SB-1 PS Antimicrobial Additive for Plastics ........... 199 Nuodex, Inc. .......................................................................................... 200 Antimicrobials .......................................................................... 200 FUNGITROL 11 .................................................................... 200 FUNGITROL 11-50 Dispersion ............................................. 201 FUNGITROL TINOX ............................................................. 202 FUNGITROL Zinc 8% Fungicide ........................................... 203 FUNGITROL Zinc 8% W.D. Fungicide .................................. 204 NUOCIDE 404-D ................................................................... 205 NUOCIDE 960 ...................................................................... 206 NUODEX 84 .......................................................................... 207 NUODEX 100 V.T. Microbiocide ........................................... 208 NUODEX Copper 8% ............................................................ 209 NUODEX PMA 18 ................................................................. 210 NUOPHENE .......................................................................... 211 NUOSEPT 65 Preservative ................................................... 212 NUOSEPT 95 Preservative ................................................... 213 PMA 60 ................................................................................. 214 QUINDEX .............................................................................. 215 QUINDEX Emulsion Base ..................................................... 216 QUINDEX N-10 GDP Fungicide ........................................... 217 QUINDEX N-10 PS Fungicide .............................................. 218 QUINDEX N-10 SS Fungicide .............................................. 219 QUINDEX N-10 WR Fungicide ............................................. 220 SUPER AD-IT Fungicide ....................................................... 221

Product Information O'Brien - Vineland Chemical ........... 222 O'Brien Industries, Inc. .......................................................................... 222 O'B ALGE 670 ......................................................................... 222 Olin Chemicals ...................................................................................... 223 This page has been reformatted by Knovel to provide easier navigation.

xxii Contents SODIUM OMADINE 40% Aqueous Solution Industrial Microbiostat for Industrial and Formulating Use Only ...... 223 ZINC OMADINE 48% Aqueous Dispersion, Industrial Grade ... 224 ZINC OMADINE Powder Industrial Microbiostat for Industrial and Formulating Use Only ............................................... 225 TRIADINE 10 Antimicrobial Agent ............................................ 226 Pennwalt Corporation ........................................................................... 227 Fungicides ............................................................................... 227 MANEB ................................................................................. 227 PENNCOZEB ........................................................................ 227 TOPSIN M 4.5F .................................................................... 228 TOPSIN M ............................................................................. 228 ZIRAM ................................................................................... 229 ZIRAM F-4 ............................................................................ 229 Rhone-Poulenc, Inc. ............................................................................. 230 Fungicides ............................................................................... 230 ALIETTE Fungicide ............................................................... 230 ROVRAL Fungicide ............................................................... 230 Rohm and Haas .................................................................................... 231 KATHON Preservatives ........................................................... 231 KATHON LX .......................................................................... 231 KATHON LX 1.5% ................................................................ 231 KATHON MWX ..................................................................... 232 KATHON WT ........................................................................ 233 KATHON WT 1.5% ............................................................... 233 KATHON 886 MW ................................................................. 234 KATHON 886 MW 1.5% ....................................................... 234 The O.M. Scott & Sons Co. .................................................................. 235 SCOTTS PROTURF ................................................................ 235 14-3-3

.................................................................................. 235

23-3-3

.................................................................................. 235

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Contents xxiii 24-5-3

.................................................................................. 235

28-0-12 .................................................................................. 236 Broad Spectrum Fungicide ................................................... 236 Fluid Fungicide ...................................................................... 236 Fluid Fungicide II ................................................................... 237 Fungicide II ........................................................................... 237 Fungicide VI .......................................................................... 237 Fungicide 7 ........................................................................... 238 Pythium Control .................................................................... 238 Systemic Fungicide ............................................................... 238 Standard Tar Products Co., Inc. ........................................................... 239 ORGANICLEAR Wood Preservatives ...................................... 239 ORGANICLEAR TM-2 .......................................................... 239 ORGANICLEAR WR-2 .......................................................... 239 ORGANICLEAR TM-5 .......................................................... 239 ORGANICLEAR WR-5 .......................................................... 239 ORGANICLEAR .................................................................... 239 Stauffer Chemical Company ................................................................. 240 FOLPET (PHALTAN) 50-WP ................................................... 240 Tennessee Chemical Company ........................................................... 241 TENN-COP 5E ......................................................................... 241 Tri-Basic Copper Sulfate .......................................................... 242 Troy Chemical Corp. ............................................................................. 243 TROYSAN AMO (Troysan Anti-Mildew O) ............................... 243 TROYSAN CMP (TROYSAN CMP ACETATE) ........................ 244 TROYSAN PMA-10-SEP .......................................................... 245 TROYSAN PMA-30 .................................................................. 246 TROYSAN PMDS-10 ............................................................... 247 TROYSAN POLYPHASE AF1 .................................................. 248 TROYSAN POLYPHASE P100 ................................................ 249 This page has been reformatted by Knovel to provide easier navigation.

xxiv Contents TROYSAN 142 ......................................................................... 250 TROYSAN 174 ......................................................................... 251 TROYSAN 192 ......................................................................... 252 Union Carbide Corp. ............................................................................. 253 AQUCAR Water Treatment Microbiocides ............................... 253 AQUCAR 515 ........................................................................ 253 AQUCAR 545 ........................................................................ 253 UCARCIDE Antimicrobials ....................................................... 254 UCARCIDE 225 Antimicrobial ............................................... 254 UCARCIDE 250 Antimicrobial ............................................... 254 UCARCIDE 150 Antimicrobial ............................................... 255 UCARCIDE Antimicrobial 750 for Pigment and Filler Slurries ...................................................................... 256 UCONEX Antimicrobial 345 for Metalworking Fluids ................ 257 Uniroyal Chemical Co., Inc. .................................................................. 258 Fungicides ............................................................................... 258 PLANTVAX-75W ................................................................... 258 TERRACLOR 2 Lb. Emulsifiable Soil Fungicide ................... 258 TERRACLOR 10% Granular Soil Fungicide ......................... 258 TERRACLOR 75% Wettable Powder Soil Fungicide ............ 259 TURFCIDE 10% Granular Turf & Ornamental Fungicide ...... 259 TURFCIDE 2 Lb. Emulsifiable Turf & Ornamental Fungicides ................................................................. 259 TERRACLOR Super X Granular Soil Fungicide with Thimet Systemic Insecticide .................................................. 260 TERRAZOLE 5% Granular Fungicide ................................... 260 TERRAZOLE 25% Emulsifiable Turf & Ornamental Fungicide ................................................................... 260 TERRACLOR SUPER X Emulsifiable Soil Fungicide ........... 261 TERRACLOR SUPER X Granular Soil Fungicide for Cotton ........................................................................ 261 This page has been reformatted by Knovel to provide easier navigation.

Contents xxv TERRACLOR SUPER X Granular Soil Fungicide with Disyston Systemic Insecticide ................................... 261 TERRAZOLE 35% Granular Turf & Ornamental Fungicide .. 262 TERRAZOLE 4 Lb . Emulsifiable Fungicide .......................... 262 U.S. Professional Laboratories ............................................................. 263 GROTAN Broad Spectrum Bactericide and Fungicide ............. 263 R.T. Vanderbilt Co., Inc. ........................................................................ 264 Preservatives ........................................................................... 264 VANCIDE 51 ......................................................................... 264 VANCIDE 51Z ....................................................................... 265 VANCIDE 51Z Dispersion ..................................................... 266 VANCIDE MZ-96 ................................................................... 267 VANCIDE TH ........................................................................ 268 VANCIDE 89 ......................................................................... 269 Vikon Chemical Co., Inc. ...................................................................... 270 VIKOL #AF-25 ......................................................................... 270 VIKOL RQ ................................................................................ 271 Vineland Chemical Co. ......................................................................... 272 Microbiocides ........................................................................... 272 SLIMICIDE V-10 ................................................................... 272 VINELAND MBT 10% ........................................................... 272

Suppliers' Addresses ............................................................ 274 Chemical Name Index ........................................................... 277 Trade Name Index .................................................................. 284

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2

zyxwvut zyxwv Fungicides, Biocides and Preservatives

Product Information

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ABBOTT LABORATORIES: AMICAL Flowable Preservative: EPA Reg. No. 275-72

Organic Chemical Antimicrobial Agent AMICAL Flowable is a water based liquid formulation of AMICAL (diiodomethyl-p-tolyl sulfone) As such, AMICAL Flowable provides the same mildew and algacidal protection of polymeric systems as AMICAL 48 and AMICAL 50 with superior dispersing characteristics when used in an aqueous system. AMICAL Flowable contains 40% active ingredient by weight and efficacy testing indicates enhanced mildewcidal protection when compared to AMICAL 48, and water is used as the carrier.

.

Physical Properties AMICAL Flowable is one of a series of AMICAL formulations offered exclusively by Abbott Laboratories. Chemically, AMICAL Flowable is diiodomethyl-p-tolylsulfone. AMICAL Flowable is stable through a pH range of 3.0 to 10.5. Appearance: Boiling Point: Freezing Point: pH : Viscosity : Specific Gravity: Weight per Gallon: Assay*

Light gray finely divided suspension l0OC

oc

7.0-8.5

-

1000 cps @ 25C 1.32 -1.33 11.05 lbs. Min 40% 600

* Active ingredient Microbiological Properties AMICAL Flowable provides a broad spectrum of antimicrobial activity. AMICAL Flowable is especially effective against major mildew-causing organisms. AMICAL Protects Latex Paints Against Mildew Better Than Any Mercurials Tested Fungicidal Activity in Chrome-Tanned Cattle Hides AMICAL is an established antifungal agent for use in protecting chrome or vegetable tanned 1eather.from mold and mildew during in-tannery wet processing and for protecting wet-blue during long storage and long transportation times, as encountered in the exportation of wet-blue.

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ABBOTT LABORATORIES: AMICAL 4 8 Preservative: EPA Reg. No. 275-21

Organic Chemical Antimicrobial Agent AMICAL 48 is a tan powder consisting of not less than 95% diiodomethyl-p-tolyl sulfone. AMICAL 48 provides mildew and algicidal protection of polymeric systems.

Physical Properties AMICAL 48 is one of a series of AMICAL formulations offered exclusively by Abbott Laboratories. AMICAL 48 is diiodomethylp-tolylsulfone. AMICAL 48 is stable through a pH range of 3.0 to 10.5. Appearance: Melting Point: pH : Assay :

Tannish finely divided powder 157 C 7.0-8.5 Min 95%

Microbiological Properties AMICAL 48 provides a broad spectrum of antimicrobial activity. AMICAL 48 is especially effective against major mildewcausing organisms. AMICAL Protects Latex Paints Against Mildew Better Than Any Mercurials Tested Wood Preservation

4

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Fungicides, Biocides and Preservatives

ABBOTT LABORATORIES: AMICAL 5 0 Preservative for Latex Paints: EPA Reg. No. 2 7 5 - 2 7

New Organic Chemical Antimicrobial Agent Does Not Tend to Cause Yellowing

AMICAL 50 is one of a series of new highly effective organic chemical antimicrobial agents. It provides mildewcide activity superior to that of organomercurials, and also provides package preservative action when used at higher mildewcide levels. AMICAL 50 contains the same active ingredients as AMICAL 4 0 . However, AMICAL 50 also contains effective color suppressants. AMICAL 4 8 has been reported to cause a transient yellow color in some paint systems. AMICAL 50 contains not less than 7 5 % diiodomethyl p-tolyl sulfone plus 20 percent color suppressants. The color suppressants have no harmful effects on paint stability in the can nor on the applied coating. They function only to inhibit the development of discoloration of the paint film. Comparative laboratory and field exposure testing show the following advantages for AMICAL 50 preservative. - AMICAL 5 0 mildewcide activity is superior to mercurials in latex paint systems. AMICAL 5 0 mildew protection is comparable or superior to that of competitive organic chemical mildewcides. AMICAL 50 also acts as a package preservative. - AMICAL 5 0 is effective with or without zinc oxide. AMICAL 50 does not tend to cause yellowing. - AMICAL 5 0 is easy to handle.

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Physical Properties AMICAL 5 0 is one of a series of newly developed organic chemicals offered exclusively by Abbott Laboratories. The active ingredient in AMICAL 50 is diiodomethyl p-tolyl sulfone. Color suppressants are also present. Appearance Specific Gravity Assay Active Ingredient Inert Ingredients

Fine Tan Powder 1.96 g/cc Min. 7 5 % Max. 2 5 %

Microbiological Properties AMICAL 50 provides a broad spectrum of antimicrobial activity, and is especially effective against major paint mildewcausing organisms.

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AGTROL CHEMICAL PRODUCTS: Agricultural Fungicides: Product Name : --

CHAMPION Wettable Powder

Active Ingredient Cupric Hydroxide Inert Ingredients Total (Metallic Copper Equivalent

....50%)

7 7% 23% 100%

EPA Reg. No. 55146-1 EPA Est. No. 35896-SC-1 COPZIN Wettable Powder Agricultural Fungicide with Nutritional Zinc Active Ingredient: Basic Copper Sulfate (24% Metallic Copper) Inert Ingredients (Including 24% Elemental Zinc) Total

45.2% 54.8% 100.0%

EPA Reg. NO. 55146-14 EPA Est. No. CHAMPION FLOWABLE Active Ingredient Cupric Hydroxide Inert Ingredients Total Contains 4.5 Lbs. Cupric Hydroxide per Gal. (Metallic Copper Equivalent 24.4%)

....

EPA Reg. No. 55146-2 EPA Est. No.

37.5% 62.5% 100.0%

6

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Fungicides, Biocides and Pfesef vatives

ALCO CHEMICAL CORP.: AQUATREAT Microbiocides:

-

-

are very safe for operators and in the environment. They contain "0 halogens 5 aldehydes and degrade quickly for discharge. offer very cost-effective control of a wide range of anaerobic and aerobic bacteria, fungi and algae. have excellent storage stabilitE and in application are non-foaming and non-corrosive. are compatible with most other treatment chemicals, including oxygen scavengers, and are effective in a reducing atmosDhere. are approved for use in California. are available in winterized formulations.

Registered Microbiocides Standard Formulations Since the introduction of AQUATREAT DNM-30, ALCO has developed and registered several microbiocides in addition to DNM-30 (30% active). AQUATREAT DNM-360 (36% active) and AQUATREAT DNM-9 (9% active) have been made available for the convenience of the formulator. Additionally, ALCO has registered other single dithiocarbamate microbiocides where their specific activities are needed. AQUATREAT DNM-30

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AQUATREAT DNM-360 AQUATREAT DNM-9 AQUATREAT SDM AQUATREAT KM

3 0 per cent mixed NABAM/DIBAM equal

portions 36 per cent mixed NABAM/DIBAM equal portions 9 per cent mixed NABAM/DIBAM equal portions 40 per cent mixed Sodium Dimethyldithiocarbamate 5 0 per cent Potassium Dimethyldithiocarbamate

Registrations Water Treatment Paper Sugar Petroleum AQUATREAT AQUATREAT AQUATREAT AQUATREAT AQUATREAT AQUATREAT

DNM-30: DNM-30: DNM-9: DNM-360. SDM: KM:

EPA EPA EPA EPA EPA EPA

Reg. Reg. Reg. Reg. Reg. Reg.

No.: No.: No.: No.: No.: No.:

31910-1 31910-2 31910-11 31910-12 31910-6 31910-5

American

AMERICAN

CYANAMID

COMPANY:

CYPREX

Active Ingredient: Dodine (n-dodecylguanidine Inert Ingredients EPA Reg. For

control peaches,

No.

65-W

Fruit

Cyanamid

Company

Fungicide:

acetate)

65.0% 35.0%

241-51-AA of certain pears, and

fungus pecans.

diseases

of

apples,

cherries,

7

8

Fungicides, Biocides and Preservatives

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ANGUS CHEMICAL COMPANY: BIOBAN CS-1135 Preservative: EPA Reg. No. 48301-8

BIOBAN CS-1135 perservative is an aqueous solution containing the following minimum concentrations of active ingredients: 4,4,-dimethyloxazolidine 3,4,4-trimethyloxazolidine

74.7% by wt 2.5% by wt

It contains no metallic compounds nor any organic derivatives of sulfur, boron, phosphorus, or halogens. The advantages of using BIOBAN CS-1135 are: Antimicrobial activity against a broad spectrum of microorganisms. Effective over a wide pH range including both alkaline and acid pH values. Alkaline buffering capability to prevent pH drift. Aids in maintaining optimum viscosity of emulsion formulations. Minimal discoloration of most formulations. Low freezing point. Excellent thermal stability.

-

In addition to its antimicrobial activity, the amine functionality in BIOBAN CS-1135 provides: Corrosion inhibition in many systems. Emulsifying capability when used with a fatty acid.

-

Physical Properties of BIOBAN CS-1135 Neutral equivalent as a base Color, APHA Flash point, Tag closed cup Freezing point Specific gravity at 25/25C Viscosity at 25C PH Weight per U.S. gallon

128-133.5 100 (max.) 120F below -2OC 0.98-0.99

-

7.5 cp 10.5-11.5 8 . 2 lb

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Angus Chemical Company

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ANGUS CHEMICAL COMPANY: BIOBAN CT In-Can Paint Preservative: EPA Reg. No. 48301-11 BIOBAN CT is an economical preservative for the prevention of spoilage of latex paints due to microbial contamination during production. Another important benefit is the complete lack of objectionable odor of BIOBAN CT.

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Typical Physical Properties Crystallization point (approx.) Specific gravity at 25/25C Specifications

2-Hydroxymethyl-2-nitro-l,3

Free formaldehyde, % by wt. pH, as is Color, Gardner

propanediol,

55F 1.222 %

by wt.

50 (min.) 1 (max.) 2.0-4.5 5.0 (max.)

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Fungicides, Biocides and Preservatives

ANGUS CHEMICAL COMPANY: BIOBAN GK:

Brand of hexahydro-1,3,5-tris(2-hydroxyethyl)-s-triazine EPA Reg. No.: 48301-14

BIOBAN GK is a 78.5% solution of hexahydro-1,3,5-tris(2hydroxyethy1)-s-triazine in water. It is widely used as an antimicrobial agent in metalworking fluids and in the preservation of latex paints and emulsions. BIOBAN GK is effective against both Gram-positive and Gramnegative bacteria. At higher concentrations, it is also effective against yeast and molds. Its activity is not affected by either the hardness of the water or the presence of nonionic surfactants in the fluid. Typical Properties Vapor Pressure, at 20C at 40C Flash Point, Pensky Martens Freezing point Specific gravity 25/25C Pounds per gallon at 71F Viscosity, Brookfield pH, as supplied

3 . 3 mmHg 13.4 mmHg 167F -lOF 1.16 9.65 300 cp

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Uses Metalworking Fluid Preservation Latex Emulsion Preservation

10.0-11.0

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11

ANGUS CHEMICAL COMPANY: BIOBAN N-95 Preservative for MetalWorking Fluids: EPA Reg. No. 1100-82-48301

BIOBAN N-95 Preservative is a 5 0 % aqueous solution of nonmetallic organic compounds which is effective for the prevention of deterioration and spoilage of metalworking fluids. Composition Active Ingredients % by wt. 5-Hydroxymethoxymethyl-l-aza-3,7-dioxabicyclo(3.3.O) octane 24.5 5-Hydroxymethyl-l-aza-3,7-dioxabicyclo(3.3.O)octane 17.7 5-Hydroxypoly[methyleneoxy(74% C2, 21% C3, 4% C4, 1% C5)] methyl-l-aza-3,7-dioxabicyclo(3.3.O)octane 7.8 Total Active Ingredients 50.0 Inert Ingredients Water Typical Physical Properties Appearance Odor Color (APHA) Viscosity (25C) Specific gravity (25/25C) Weight per gallon Refractive index (25C) PH Flash point (Tag Closed Cup,F)

50.0

Clear, pale yellow liquid Mild, characteristic 250 maximum 3.6 centistokes 1.137 9.5 lb 1.404 5-7.5

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12 Fungicides, Biocides and Preservatives

ANGUS CHEMICAL COMPANY: BIOBAN P-1487 Broad-Spectrum Antimicrobial Agent:

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EPA Reg. No. 48301-7

BIOBAN P-1487 is a potent agent to inhibit bacterial growth. It is recommended for those situations requiring oil solubility, yet it also is effective in aqueous systems. BIOBAN P-1487 consists of a mixture of two active chemicals: ( I ) 4-(2-nitrobutyl)morpholine

CAS Registry Number 2224-44-4

(11) 4,4'-(2-ethyl-2-nitrotrimethylene)

dimorpholine

CAS Registry Number 1854-23-5 Compound I is normally a liquid; pure compound I 1 is a solid melting above ambient temperature. The ratio of the two components is chosen so that BIOBAN P-1487 will normally remain a liquid at temperatures above OC. BIOBAN P-1487 is only moderately soluble in water; the saturated solution is slightly alkaline. BIOBAN P-1487 is soluble in most organic solvents, including aliphatic hydrocarbons. Active Ingredients 4-(2-Nitrobutyl)morpholine 4,4'-(2-Ethyl-2-nitrotrimethylene)dimorpholine

Inert Ingredients Total EPA Reg. No. 48301-7AA EPA Est. No. 48301-WG-1

70% by wt 20% by wt 10% by wt 100%

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ANGUS CHEMICAL COMPANY: BODOXIN:

(E.P.A. Reg. No. 48301-16)

-

Metalworking fluids. Powerful antibacterial and antifungal activity. Useable in concentrates and tankside. Long lasting. Years of proven experience.

Physical State: liquid Specific Gravity (25/25C): 1.24 Flash Point (closed cup) : 140F pH: -7.0 (as supplied)

13

14

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Fungicides, Biocides and Preservatives

ANGUS CHEMICAL COMPANY: FUELSAVER Antimicrobial Agent: Fuel Preservation Performance

FUELSAVER Antimicrobial Agent (EPA Reg. No. 4 8 3 0 1 - 7 ) is an excellent preservative for the prevention of microbial growth in hydrocarbons. studies have shown that at recommended levels it is:

-

effective against those bacteria, fungi, and yeasts found in contaminated fuels. fully soluble in fuels and hydrocarbons. active even in the presence of large quantities of water.

Also, when tested at levels of up to 1000 ppm in No. 2 diesel fuel, no deleterious effects on engine performance or emissions were noted. That is, engine rpms, power output, and torque remained unchanged, and no increase in the amount of pollutants emitted were observed. Conclusions: FUELSAVER will control microbial growth effectively at levels as low as 250 ppm in the fuel. This ability to provide control is unaffected by the presence of water in the system. In fact FUELSAVER is highly effective for hydrocarbons intentionally stored over water. Protection can be obtained by addition of FUELSAVER to the fuel or by direct addition to the water phase.

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FUELSAVER is a potent agent to inhibit microbial growth. It is recommended for those situations requiring oil solubility, yet it also is effective in aqueous systems. FUELSAVER consists of a mixture of two-active chemicals. Compound I, 4-(2-nitrobutyl)morpholine (CAS Registry Number 2224-44-4), is normally a liquid; pure compound 11, 4 , 4 ' - ( 2 ethyl-2-nitrotrimethy1ene)dimorpholine (CAS Registry Number 1854-23-5), is a solid, melting above ambient temperature. The ratio of the two components is chosen so that FUELSAVER will normally remain a liquid at temperatures above OC. FUELSAVER is only moderatel$ soluble in water; the saturated Solution is slightly alkaline. FUELSAVER is soluble in most organic solvents, including aliphatic hydrocarbons. Active Ingredients: 4-(2-Nitrobutyl)morpholine 4,4'-(2-Ethyl-2-nitromethylene)dimorpholine Inert Ingredients: Total EPA Reg. No. 48301-7AA

7 0 % by wt

20% by wt 10% by wt 100%

z zyx zyxwvu Angus Chemical Company

ANGUS CHEMICAL COMPANY: S.S.T.

15

SUMP SAVER TABLETS:

Bacteriostat for Water-Soluble Metalworking Fluids EPA Registry No. 48301-10AA

S.S.T. Sump Saver Tablets are a convenient method for extending the useful life of metalworking fluids. They contain as active ingredient the well-known antimicrobial agent T R I S NITRO brand of tris(hydroxymethy1)-nitromethane* formulated into a compact wafer form for ease of handling. Each S.S.T. Sump Saver Tablet weighs one ounce, sufficient for one week's treatment of 25 gallons of normal metalworking fluid. For extremely fouled systems, use two tablets weekly per 25 gallons of fluid. The use of S.S.T. Sump Saver Tablets results in a significant savings in time and money because fluid life can be greatly extended. Not only does this save the cost of replacement fluid but also provides significant savings in terms of less machine downtime and lower cost of spent fluid disposal. Additionally, a cleaner fluid means improved machine productivity and extended tool life. The CAS Registry No. is 126-11-4.

16

zyxwvut zyxw zyxwvu Fungicides, Biocides and Preservatives

ANGUS CHEMICAL COMPANY: TRIS NITRO:

Brand of 50% Aqueous Tris(Hydroxymethyl)nitromethane* (EPA Reg. No. 48301-11)

TRIS NITRO is an anti-microbial agent particularly suited for the control of bacteria and slimes in industrial applications. It is available as a 50% aqueous solution of tris(hydroxymethy1)nitromethane. Purified TRIS NITRO is a white crystalline solid which is quite stable when dry. At its melting point crystalline TRIS NITRO decomposes slowly, but there is no tendency for this decomposition to become self-sustaining because the reaction is endothermic. TRIS NITRO is highly soluble in water and is quite stable in neutral or weakly acidic solution. However, in slightly alkaline solution TRIS NITRO slowly decomposes to release formaldehyde. Formaldehyde is released more rapidly as pH is increased. This release can be easily controlled by pH adjustment and/or temperature so that the working life of TRIS NITRO can be varied from a few minutes to several months according to conditions of use.

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Typical Physical Properties of the 50% Aqueous Solution Crystal lization point (approx.) 55F Specific gravity at 25/25C 1.222 Specifications of the 50% Aqueous Solution TRIS NITRO, % by wt Free formaldehyde, % by wt pH, as is Color, Gardner

* CAS Registry No. 126-11-4

50 (min.) 1 (max.) 2.0-4.5 5.0 (max.)

Bedford Chemical Division

17

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BEDFORD CHEMICAL DIVISION: MICRO-CHEK Antimicrobials:

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MICRO-CHEK is an EPA registered industrial mildewcide for PVC, polyurethane and other polymer compositions susceptible to attack by microrganisms. With proper use, MICRO-CHEK will help prevent microbiological attack on the product surface that can cause the loss of aesthetic appearance, mildew odors, embrittlement and premature product failure. MICRO-CHEK is a 4.0% solution of the active ingredient of 2-n-octyl-4-isothiazolin-3-one carried in several different plasticizers. The isothiazolone is low migrating which enables MICRO-CHEK to effectively provide protection in the most stressful of environments in such applications a s roofing membranes, automotive trim, awnings, pond liners, marine upholstery, shower curtains and outdoor furniture. MICRO-CHEK can also provide superior performance in less severe interior applications such a s wall coverings, shelf liners, and refrigerator door gasketing. Product Name:

MICRO-CHEK 11 Carrier: Epoxidized soybean oil Density (lb/gal): 8.30 EPA Number: 1486-19

MICRO-CHEK 11D Carrier: Di(2-ethyl hexyl) phthalate Density (lb/gal): 8.21 EPA Number: 1486-19 MICRO-CHEK 11 DIDP Carrier: Diisodecyl phthalate Density (lb/gal): 8.10 EPA Number: 1486-19 MICRO-CHEK 11 S-711 Carrier: Mixed dialkyl phthalates Density (lb/gal): 8.20 EPA Number: 1486-19 MICRO-CHEK 11 S-160 Carrier: Butyl Benzyl Phthalate Density (lb/gal): 9.00 EPA Number: 1486-19 MICRO-CHEK 11 IPA Carrier: Isopropyl Alcohol Density (lb/gal): 6.70 EPA Number: 1486-19 MICRO-CHEK 11 T Carrier: Toluene Density (lb/gal): 7.25 EPA Number: 1486-19

18

Fungicides, Biocides and Preservatives

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BEECHAM HOME IMPROVEMENT PRODUCTS, I N C . : 4 - 1 C o n c e n t r a t e E, Ready-To-Use:

Water Based WOODLIFE:

Description: Water Based WOODLIFE i s a w a t e r b o r n e , p e n e t r a t i n g , p a i n t a b l e w a t e r - r e p e l l e n t p r e s e r v a t i v e f o r wood a n d wood-based p r o d u c t s . The p r e s e r v a t i v e , 3-lodo-2 p r o p y n l b u t y l c a r b a m a t e , g i v e s e f f e c t i v e p r o t e c t i o n a g a i n s t mold, mildew, s t a i n i n g a n d d e c a y f u n g i . The water r e p e l l e n c y p r o v i d e s d i m e n s i o n a l s t a b i l i t y t o m i n i m i z e c h e c k i n g and w a r p i n g o f wood a n d wood p r o ducts. The p r e s e r v a t i v e , 3-iOd0-2 p r o p y n y l b u t y l c a r b a m a t e ( P o l y p h a s e ) , i s a f u n g i c i d e w i t h l o w t o x i c i t y and s p i l l s are n o t c o n s i d e r e d a h a z a r d o u s waste. Water Based WOODLIFE i s n o n - f i l m f o r m i n g a n d i s n o t a s e a l e r b u t p e n e t r a t e s d e e p l y i n t o t h e wood. I t w i l l n o t p e e l o r c h i p l i k e c o n v e n t i o n a l f i n i s h e s and w i l l f u n c t i o n a s a n e x c e l l e n t b a s e f o r most p a i n t s and f i n i s h e s . Water Based WOODLIFE i s w a t e r - b a s e d and t h e r e f o r e non-flamm a b l e . T h i s makes i t e a s y t o c l e a n up w i t h w a t e r . Water Based WOODLIFE i s a v a i l a b l e a s a r e a d y - t o - u s e (RTU) or 4 : l C o n c e n t r a t e .

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Specifications: Conforms t o I n d u s t r i a l S t a n d a r d 1 S 4-81 a n d i s a p p r o v e d by N.W.W.D.A. Meets a l l c u r r e n t and p r o p o s e d g o v e r n m e n t e n v i r o n mental s t a n d a r d s . Uses :

W a t e r Based WOODLIFE i s d e s i g n e d f o r wood p r o d u c t s t h a t w i l l be u s e d above ground l i n e l e v e l . W a t e r Based WOODLIFE p r o v i d e s w a t e r - r e p e l l e n t p r e s e r v a t i v e p r o t e c t i o n f o r m i l l w o r k items, s t r u c t u r a l l u m b e r , s i d i n g , t r u s s e s , f l o o r i n g , s u b - f l o o r i n g , o u t s i d e s i g n s , t r u c k and f a r m e q u i p ment b o d i e s , f e n c i n g , p a t i o s , plywood, a n d r e c o n s t i t u t e d wood. Water Based WOODLIFE c a n b e u s e d a s a c l e a r , n a t u r a l f i n i s h f o r e x t e r i o r woods. Water Based WOODLIFE, when d r y , i s a n e x c e l l e n t b a s e f o r p a i n t s , a n d p r i m e r s , b o t h s o l v e n t and l a t e x t y p e s , a n d v a r n i s h . P h y s i c a l P r o p e r t i e s (Ready-To-Use): Active Ingredients: 0.5% 3-iOd0-2 p r o p y n l b u t y l c a r b a m a t e (IPBC) RTU Color: Opaque, creamy c o l o r Viscosity: 25-50 CPS B r o o k f i e l d Model RVT, #1 s p i n d l e @ 50 rpm Flashpoint: None Odor : Mild i n s o l u t i o n , o d o r f r e e when dry WeightIGal l o n : 8.0-9.0 l b . EPA R e g i s t e r e d

(#1409-50, c o n c e n t r a t e ) (#1409-51, r e a d y - t o - u s e )

Beecham Home Improvement Products, Inc.

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BEECHAM HOME IMPROVEMENT PRODUCTS, INC.: WOODLIFE-F Water Repellent Preservative for Wood: Description: WOODLIFE-F is a clear, penetrating, paintable water-repellent preservative for wood and wood-based products. The preservative, 3-iOd0-2 propynl butyl carbamate, provides effective protection against mold, mildew, staining and decay fungi. The water repellency feature provides dimensional stability to minimize checking, splitting, and warping of wood and wood products. WOODLIFE-F is non-film forming and is not a sealer but penetrates deeply into wood. It will not peel or chip like conventional finishes and will function as an excellent base for most paints and finishes.

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Specifications: Conforms to Industrial Standard I S 4-81 and is approved by N.W.W.D.A. Meets all current proposed government environmental standards. Uses : WOODLIFE-F is designed for wood products that will be used above ground line level. WOODLIFE-F provides water-repellent preservative protection for millwork items, structural lumber, siding, trusses, floortng, subflooring, outside signs, truck and farm equipment bodies, fencing, patios, plywood, and reconstituted wood. WOODLIFE-F can be used as a clear, natural finish for exterior woods. WOODLIFE-F, when dry, is an excellent base for paints, and primers, both solvent and latex types, and varnish. Physical Properties: Active Ingredients: Color: Viscosity: Flashpoint: Odor: Weight/Gallon: Carrier (Solvent): EPA Reg. No. 1409-63

0.5% 3-lodo-2 propynyl butyl carbamate (Polyphase) Clear very light straw Less than water, A-4 Gardener Bubble 105F (40C) Tag Closed Cup Petroleum distillate 6.65 lb./Gal. Mineral spirits

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Fungicides, Biocides and Preservatives

BETZ ENERGY CHEMICALS, INC.: BET2 EnChem Biocides: Product Name:

BETZ EnChem 41-51 Biocide

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Combination corrosion inhibitor and bactericide for sweet or sour systems Effective on sulfate-reducing bacteria and slime-forming bacteria Exhibits strong film forming tendencies

Description and Use 41-51 is a combination bactericide and corrosion inhibitor for use in oil field water systems. It is particularly effective for the control of sulfate-reducing and slime-forming bacteria. It also exhibits strong film forming properties for the control of corrosion caused by hydrogen sulfide, carbon dioxide, acids and salts.

Typical Applications 41-51 can be fed at any point where microbiological growth is a problem. The product is a combination bactericide and corrosion inhibitor for use in treating water in surface equipment, injection wells, packer fluids and drilling muds. 41-51 can be fed intermittently or continuously depending upon the location, extent, and other circumstances surrounding the problem. The product should be fed neat.

General Properties n-Alkyl*-1,3-Propylene Diamines Isopropyl Alcohol *4% C8, 5% C10, 42% C12, 15% C14, 8% C16, 26% Environmental Protection Agency Registration No. Appearance Density (70F) Flash Point (closed cup) Freeze Point pH (undiluted) pH (5% solution) Pour Point (ASTM) Specific Gravity (70F) Viscosity (70F)

41.7% 58.3% C18 8928-2-48525

clear amber liquid 6.8 lbs/gal. 59F 10F 12.3 11.0 15F 0.819 8 cps

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BETZ ENERGY CHEMICALS, INC.: BETZ EnChem Biocides(Continued): Product Name: BET2 EnChem 41-52 Biocide

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Specially formulated liquid biocide effective on a variety of common oil field organisms EPA Registered biocide May be fed continuously or intermittently depending on severity of problem

Description and Use BET2 EnChem 41-J2 is a specially formulated liquid biocide for the control of slime forming bacteria, fungi, algae and sulfate reducers in oil field water systems. Typical Applications 41-J2 is a highly effective biocide for oil field water systems. The product can be fed to source wells, at free water knockouts, before or after flotation cells and filters, or after the injection pumps. 41-J2 is also used in packer fluids and drilling muds. General Properties Dodecylguanidine Hydrochloride Methylenebis (Thiocyanate) Inert Ingredients (including solubilizing and dispersing agents) EPA Registration Number Appearance Density (70F) Flash Point (closed cup) (Setaflash) Freeze Point pH (undiluted) pH (5% solution) Pour Point (ASTM) Specific Gravity (70P) Viscosity (70F)

10% 5%

85% 3876-122 yellow liquid 9.12 lbs/gal. 120F