Developments In Pressure-Sensitive Products, 2nd Edition 9781420027525, 1420027522

Table of contents :
Front cover
Preface to the Second Edition
Preface to the First Edition
Contributors
Table of Contents
1 Introduction
REFERENCES
2 Buildup and Classification of Pressure-Sensitive Products
CONTENTS
I. CONSTRUCTION OF PRESSURE-SENSITIVE PRODUCTS
A. GENERAL BUILDUP OF PRESSURE-SENSITIVE PRODUCTS
B. PARTICULAR BUILDUP OF PRESSURE-SENSITIVE PRODUCS
C. COMPONENTS OF PRESSURE-SENSITIVE PRODUCTS
II. CLASSES OF PSPs
A. LABELS
B. TAPES
C. PROTECTIVE FILMS
D. OTHER PRODUCTS
REFERENCES
3 Physical Basis of Pressure- Sensitive Products
CONTENTS
I. RHEOLOGY OF PSPs
A. RHEOLOGY OF CARRIER MATERIAL
B. RHEOLOGY OF ADHESIVES
C. RHEOLOGY OF ADHESIVE
D. PRODUCT RHEOLOGY
E. ADVANCES OF ADHESIVE RHEOLOGY
II. MECHANICAL PROPERTIES OF PSPs
A. RHEOLOGICAL BACKGROUND OF THE MECHANICAL PROPERTIES OF PSPs
B. MAIN MECHANICAL PERFORMANCES
C. REGULATING THE MECHANICAL PROPERTIES OF PSPs
D. THE INFLUENCE OF THE MECHANICAL PROPERTIES ON OTHER PERFORMANCE CHARACTERISTICS OF PSPs
III. OTHER PHYSICAL CHARACTERISTICS OF PSPs
A. ELECTRICAL CHARACTERISTICS OF PSPS
B. OPTICAL CHARACTERISTICS OF PSPS
REFERENCES
4 Molecular Fundamentals of Pressure-Sensitive Adhesion
CONTENTS
I. POLY(N-VINYL PYRROLIDONE) [PVP] — POLY(ETHYLENE GLYCOL) [PEG] BLENDS AS MODEL PSAs
II. PRESSURE-SENSITIVE ADHESION AS MATERIAL PROPERTY
A. INTERRELATIONSHIP BETWEEN ADHESION AND MECHANICAL PROPERTIES OF PSAs
B. TOWARD MOLECULAR NATURE OF PRESSURE-SENSITIVE ADHESION
C. PHYSICAL SIGNIFICANCE OF THE DALQHIST CRITERION OF TACK
D. PVP–PEG BLENDS VS. HYDROPHOBIC ADHESIVES
E. RELATION OF ADHESION TO PHASE STATE AND MOLECULAR STRUCTURE OF PVP-PEG COMPLEX
III. PRESSURE-SENSITIVE ADHESION AS A PROCESS
A. RHEOLOGICAL PROPERTIES OF PVP-PEG PSA UNDER CONDITIONS MODELING ADHESIVE BONDING
B. RELAXATION CRITERIA FOR PRESSURE-SENSITIVE ADHESION
C. BEHAVIOR OF PSA IN THE COURSE OF THE DEBONDING PROCESS
REFERENCES
5 Chemical Basis of Pressure- Sensitive Products
CONTENTS
I. MACROMOLECULAR BASIS AND CHEMICAL COMPOSITION OF CARRIER MATERIAL
A. GENERAL CONSIDERATIONS
B. NONADHESIVE CARRIER MATERIAL
C. CARRIER MATERIALS WITH ADHESIVITY
II. MACROMOLECULAR BASIS AND CHEMICAL COMPOSITION OF THE ADHESIVE
A. ELASTOMERIC COMPONENTS
B. VISCOELASTIC COMPONENTS
C. VISCOUS COMPONENTS
D. PLASTOMERS
E. OTHER COMPONENTS
III. MACROMOLECULAR BASIS AND CHEMICAL COMPOSITION OF THE ABHESIVE
A. COATED ADHESIVE COMPONENTS
B. BUILT-IN ABHESIVE COMPONENTS
REFERENCES
6 Developments in Crosslinking of Solvent-Based Acrylics
CONTENTS
I. CONVENTIONAL CROSSLINKING OF SOLVENT-BASED ACRYLIC PSAs
A. CROSSLINKING OF ACRYLIC PSAs BY CROSSLINKING MONOMERS
B. CROSSLINKING AGENTS
II. PHOTOCROSSLINKING OF SOLVENT-BASED ACRYLIC PSAs
A. UV-LIGHT
B. PHOTOINITIATORS
C. UV-INITIATED CROSSLINKING OF SOLVENT-BORNE ACRYLIC PSA USING UV EXCIMER LASER
III. THE INFLUENCE OF SELECTED CROSSLINKING AGENTS AND PHOTOINITIATORS ON SOLVENT-BASED ACRYLIC PSAs SHRINKAGE AFTER CROSSLINKING
CONCLUSIONS
REFERENCES
7 Adhesive Properties of Pressure-Sensitive Products
CONTENTS
I. DEFINITION AND CHARACTERIZATION OF ADHESIVE PROPERTIES
A. GENERAL ADHESIVE PERFORMANCE
B. SPECIAL ADHESIVE PERFORMANCES
II. REGULATING THE ADHESIVE PROPERTIES
A. REGULATION OF THE ADHESIVE PROPERTIES WITH THE ADHESIVE
B. REGULATING THE ADHESIVE PROPERTIES WITH THE CARRIER
C. REGULATING ADHESIVE PROPERTIES WITH MANUFACTURING TECHNOLOGY
D. REGULATING THE ADHESIVE PROPERTIES WITH PRODUCT APPLICATION TECHNOLOGY
III. INTERDEPENDENCE ADHESIVE PROPERTIES AND OTHER PERFORMANCE CHARACTERISTICS
REFERENCES
8 Manufacture of Pressure- Sensitive Products
CONTENTS
I. MANUFACTURE OF COATING COMPONENTS
A. MANUFACTURE OF THE ADHESIVE COMPONENTS
B. MANUFACTURE OF THE ADHESIVE COMPONENTS
II. MANUFACTURE OF THE CARRIER MATERIAL FOR PSPs
A. CARRIER ON PAPER BASIS
B. SYNTHETIC FILMS AS CARRIER
C. OTHER CARRIER MATERIALS
D. MANUFACTURE OF THE RELEASE LINER
III. MANUFACTURE OF THE FINISHED PRODUCT
A. MANUFACTURE OF THE FINISHED PRODUCT BY EXTRUSION
B. MANUFACTURE OF THE FINISHED PRODUCT BY CARRIER COATING
REFERENCES
9 Molecular Design of Hydrophilic Pressure-Sensitive Adhesives for Medical Applications
CONTENTS
I. PERFORMANCE PROPERTIES OF PRESSURE-SENSITIVE ADHESIVES FOR MEDICAL APPLICATION
II. KEY FACTORS UNDERLYING THE DESIGN OF HYDROPHILIC PRESSURE-SENSITIVE ADHESIVES
III. HYDROPHILIC ADHESIVES: HYDROGEN BONDS VS. COVALENT CROSSLINKING
IV. PRINCIPLES OF FORMULATING THE ADHESIVE HYDROPHILIC POLYMER BLENDS
V. HYDROPHILIC ADHESIVES PRODUCED BY COMBINATION OF LADDER-LIKE AND CARCASS-LIKE TYPES OF NONCOVALENT CROSSLINKING
A. PHASE STATE AND MECHANISM OF INTERACTION
B. MECHANICAL PROPERTIES
C. EFFECT OF SWELLING IN WATER ON ADHESION
D. CONCENTRATION OF THE LADDER-LINE CROSSLINKING AS A FACTOR ACCOUNTING FOR ADHESIVE PERFORMANCE
E. IMPACT OF IONIZATION OF LADDER-LINE CROSSLINKING UPON ADHESION
F. SWELLING AND DISSOLUTION PROPERTIES
VI. AMPHIPHILIC ADHESIVES PRODUCED BY LADDER-LIKE CROSSLINKING AND PLASTICIZATION OF FILM-FORMING POLYMERS
A. PHASE STATE AND MECHANISM OF INTERACTION
B. EFFECT OF LADDER-LIKE CROSSLINKING ON TENSILE PROPERTIES
C. ADHESIVE BEHAVIOR
D. SWELLING AND DISSOLUTION
VII. CORPLEX ADHESIVES COMPARED WITH CONVENTIONAL PRESSURE-SENSITIVE ADHESIVES AND BIOADHESIVES
VIII. PHARMACEUTICAL APPLICATION OF THE CORPLEX ADHESIVES
REFERENCES
10 Converting Properties of Pressure-Sensitive Products
CONTENTS
I. COATING PROPERTIES OF PRESSURE-SENSITIVE PRODUCTS
A. ADHESIVE COATING
B. ABHESIVE COATING
C. PRINTING
II. CONFECTIONING PROPERTIES
A. CUTTING
B. DIE-CUTTING
C. PERFORATING, EMBOSSING, AND FOLDING
D. WINDING PROPERTIES
III. DISPENSING AND LABELING
REFERENCES
11 End-Uses of Pressure- Sensitive Products
CONTENTS
I. GENERAL CONSIDERATIONS
II. LABELS AND THEIR APPLICATION
A. APPLICATION CONDITIONS
B. APPLICATION METHOD OF LABELS
C. POSTMODIFICATION OF LABELS
D. MAIN TYPES OF LABELS
III. TAPES AND THEIR APPLICATION
A. APPLICATION CONDITIONS
B. APPLICATION METHOD
C. MAIN TAPES
IV. PROTECTIVE FILMS
A. APPLICATION CONDITIONS
B. MAIN PROTECTIVE FILMS
V. FORMS
VI. PLOTTER FILMS
VII. OTHER PSPs
REFERENCES
Abbreviations and Acronyms
I. COMPOUNDS
II. TERMS
Index
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